ZCMR法从废物中制取活性炭及在含铬废水处理中应用

采用微波照射－ 氯化锌（ZCMR） 法从废物中制取锯末活性炭及烤胶废料活性炭,用所得的两种活性炭处理含铬废水,结果表明,ZCMR法制取的废物活性炭对电镀废水中铬的吸附容量是市售一级粉末活性炭的1.72 ～1.8 倍, 过滤速度是市售活性炭的1.6 ～1.7 倍, 极限吸附量达21.5 ～22.5mg/g．     

模拟日光照射下草酸协同黄铁矿对Cr(Ⅵ)的还原作用

研究了模拟日光照射下草酸协同黄铁矿对Cr(Ⅵ)的还原作用机理及其影响因素.结果表明,加入草酸后,反应体系中生成了光化学活性高的草酸铁(Ⅲ)配合物,同时还可能阻止了黄铁矿表面Fe(Ⅲ)水解产物Fe(OH)3和CrxFe1-x(OH)3的生成,从而使黄铁矿还原Cr(Ⅵ)的速率明显得到提高.增加溶液酸度、草酸浓度和黄铁矿质量浓度,有利于Cr(Ⅵ)的还原.     

防灾抗灾新发明

安全木屋 在最近举办的挪威＂卑尔根国际木节＂上,由荷兰建筑师马克斯·林克和西蒙·德容只用4天建起的安全木屋设计独特,十分引人注目。瘦长结构的安全屋全用外表被火燎烧过的5厘米×5厘米的松木梁建造,有助于防火,防腐和防虫,确保室内安全。它敞开屋顶,以便让自然光照射进来。通过旁边的一个小门可进入安全木屋,里面有一系列的活动平台,可根据社交、联络、工作或休闲等不同的用途配置。儿童和成年人可以在平台里进行读书或娱乐等活动,甚至睡大觉。     

避开来自阳光的紫外线

正六月阳光,热辣,闪亮。作物和花草承其德泽,生出灼灼光华。这繁茂的炽烈,闭着眼睛都有炫彩的亮,这就是夏日阳光的王者风范。六月阳光,带来了色彩浓郁到极致的旺盛,六月里诞生的我,感念这火辣阳光赋予的顽强生命力,但还是忍不住悄悄说一点阳光的坏,准确地说,是数落一下赤橙黄绿蓝靛紫的明媚光芒之外,     

安全小字典(26)

为什么有些气体钢瓶必须分开存放？ 答：某些气体会相互作用而发生危险。例如氧气与乙炔气相遇,一旦有火种即可发生剧烈燃烧。氢气与氯气相混,经光线照射即可发生爆炸。故所容气体性质相抵触的气瓶不得混装运输并应分开存放。     

Fabrication of Bi2O3/TiO2 nanocomposites and their applications to the degradation of pollutants in air and water under visible-light

A nanoheterojunction composite photocatalyst Bi2O3/TiO2working under visible-light(λ 420 nm) was prepared by combining two semiconductors Bi2O3 and TiO2 varying the Bi2O3/TiO2molar ratio. Maleic acid was employed as an organic binder to unite Bi2O3 and TiO2 nanoparticles. The SEM, TEM, XRD and diffuse reflectance spectra were utilized to characterize the prepared Bi2O3/TiO2nanoheterojunction. The nanocomposite exhibited unusual high photocatalytic activity in decomposing 2-propanol in gas phase and phenol in aqueous phase and, evolution of CO2 under visible light irradiation while the end members exhibited low photocatalytic activity. The composite was optimized to 5 mol% Bi2O3/TiO2. The remarkable high photocatalytic efficiency originates from the unique relative energy band position of Bi2O3 and TiO2 as well as the absorption of visible light by Bi2O3.     

A visible light-responsive iodine-doped titanium dioxide nanosphere

I-doped titanium dioxide nanospheres (I-TNSs) were synthesized via a two-step hydrothermal synthesis route, their potential for the e cient utilization of visible light was evaluated. The prepared anatase-phase I-TNSs had a bimodal porous size distribution with a Brunauer-Emmett-Teller surface area of 76 m2/g, a crystallite size of approximately 14 nm calculated from X-ray di raction data, and a remarkable absorption in the visible light region at wavelengths > 400 nm. The photocatalytic activity of the samples was evaluated by decoloration of Methyl Orange in aqueous solution under visible light irradiation in comparison to the iodine-doped TiO2 (I-TiO2). The I-TNSs showed higher photocatalytic e ciency compared with I-TiO2 after irradiation for 180 min even though the latter had a much greater surface area (115 m2/g). It was concluded that the surface area was not the predominant factor determining photocatalytic activity, and that the good crystallization and bimodal porous nanosphere structure were favourable for photocatalysis.     

Photocatalytic degradation of endocrine disruptor Bisphenol-A in the presence of prepared CexZn1-xO nanocomposites under irradiation of sunlight

Photocatalytic degradation of Bisphenol A （BPA）, a representative endocrine disruptor chemical, was carried out under irradiation of sunlight in the presence of CexZn1-xO nanophotocatalyst. Cerium （Ce） ions were successfully incorporated into the bulk lattice of ZnO by simple co-precipitation process. The CexZn1-xO composite nanostructures exhibited higher photocatalytic efficiency than pure ZnO in the degradation of BPA under sunlight irradiation and nearly complete mineralization of BPA was achieved. The degradation rate was strongly dependent on factors such as the size and structure of catalyst, doping material concentration, BPA concentration, catalyst load, irradiation time and pH levels. This work suggested that the CexZn1-xO assisted photocatalytic degradation is a versatile, economic, environmentally benign and efficient method for BPA removal in the aqueous environment.     

轮班制度对于地铁司机疲劳的影响

立足于轮班工作模式,阐述轮班制度对司机疲劳产生与积累的影响。介绍疲劳指数方法和池田公式的理论基础及模型构架,基于北京地铁13号线现行轮班表,分别应用上述两种研究方法进行地铁轮班司机疲劳程度的分析。两种方法的评估结果显著相关,均说明13号线现行轮班表的制定会导致司机疲劳的产生,存在安全运营风险。应用上述方法可实现对司机疲劳程度的非接触式测量,避免对司机驾驶作业的干扰,同时为地铁运营公司的安全管理人员制定合理的轮班方案,建立全面、量化的动态管理措施,提高行车安全保障提供了科学依据。     

关于不同海拔高度宇宙射线吸收剂量率测量方法的探讨

本文报道了使用FT—620型照射量率仪和高压电离室对四川省不同海拔高度宇宙射线电离成份所致空气吸收剂量率的测量结果。测量水面是四川省的三岔湖(海拨461米);邛海(海拔1510米);泸沽湖(海拔2690米)。根据测量结果经过换算,得出了在一定的地理纬度下,宇宙射线电离成份所致空气吸收剂量率随海拔高度的变化曲线。由此可评价不同海拨高度地区,宇宙射线电离成份所致居民受照剂量和计算陆地r辐射剂量率