用磷泥生产磷铜母合金的方法

该发明涉及一种用磷泥生产磷铜母合金的方法：向熔磷槽内投入磷泥，加热至高于黄磷熔点的温度下熔融；在蒸磷锅内加入相当于锅容积1／6～1／2的水，然后将熔融后的磷泥引入蒸磷锅内，加热至285～400℃产生磷蒸气；将磷蒸气通入气液吸收反应器与可溶性铜盐水溶液反廊；反应后含固液两相的混合物通过固液分离装置进行分离；固液分离所得崮体产物继续用水冲洗、过滤，直至滤液中无铜离子和元素磷检出；所得固体产物十燥至水的质量分数小于5％，即得磷铜母合金（P质量分数不低于14．5％，Cu质量分数不低于83．2％）。     

工业废水中盐酸,氯乙酸,醋酸共存时盐酸的测定

介绍了配水及工业废水中盐酸，氯乙酸，醋酸同时存在时，测定盐酸含量的方法。测定的相对标准偏为９．６９０％－０．９０３％，盐酸回收率为９３．４％－１０４．０％。     

A high activity of Ti/SnO2-Sb electrode in the electrochemical degradation of 2,4-dichlorophenol in aqueous solution

Electrochemical degradation of 2,4-dichlorophenol (2,4-DCP) in aqueous solution was investigated over Ti/SnO₂-Sb anode. The factors influencing the degradation rate, such as applied current density (2-40 mA/cm²), pH (3-11) and initial concentration (5-200 mg/L) were evaluated. The degradation of 2,4-DCP followed apparent pseudo first-order kinetics. The degradation ratio on Ti/SnO₂-Sb anode attained > 99.9% after 20 min of electrolysis at initial 5-200 mg/L concentrations at a constant current density of 30 mA/cm² with a 10 mmol/L sodium sulphate (Na2SO4) supporting electrolyte solution. The results showed that 2,4-DCP (100 mg/L) degradation and total organic carbon (TOC) removal ratio achieved 99.9% and 92.8%, respectively, at the optimal conditions after 30 min electrolysis. Under this condition, the degradation rate constant (k) and the degradation half-life (t_1/2) were 0.21 min^-1 and (2.8±0.2) min, respectively. Mainly carboxylic acids (propanoic acid, maleic acid, propanedioic acid, acetic acid and oxalic acid) were detected as intermediates. The energy efficiencies for 2,4-DCP degradation (5-200 mg/L) with Ti/SnO₂-Sb anode ranged from 0.672 to 1.602 g/kWh. The Ti/SnO₂-Sb anode with a high activity to rapid organic oxidation could be employed to degrade chlorophenols, particularly 2,4-DCP in wastewater.     

制取高浓度臭氧水的实验研究

采用介质阻挡强电离放电技术制取高浓度臭氧 ,使用射流器和气液溶解分离器溶解臭氧制取高浓度臭氧水。讨论了应用臭氧量、气液比、系统压力和气液溶解方式对臭氧水浓度和臭氧有效溶解效率的影响     

高浓度O3水研究

介绍了氧水溶液研究的进展及其广泛诱人的前景，同时阐叙了产生高深度氧、高效率溶解制取氧水溶液等方法。利用这些方法，臭氧水溶液的臭氧浓度达８ｇ／ｍ＾２，氧溶解率达９８％以上。     

用氟化钾水溶液从制药废液中回收异丙醇的工艺研究

采用普通精馏与加盐分相技术回收异丙醇。测定了异丙醇－水－氟化钾体系在恒温（40℃）时的液－液相平衡数据，并用Pitzer理论和Wilson方程对液－液相平衡数据进行了理论计算。结果表明：计算值与实验值符合良好；采用氟化钾水溶液回收异丙醇，当60.0%氟化钾浓溶液与50％异丙醇－50％水的物料的质量比为2.0时，有机相中异丙醇的纯度可达95.62%（质量百分数），水相中氟化钾稀溶液经蒸发回收后循环使用不影响分离性能。采用以上技术从制药废液中回收异丙醇，每年可获经济效益342万元。     

浅析液化石油气贮罐氢鼓泡现象

液化石油气贮罐在运行过程中,因受到介质中杂质的侵蚀,使其材质发生劣化、厚度减薄、强度下降,从而造成严重的隐患和事故。而杂质中的H2S则是最具破坏力的因素,钢材在含H2S的水溶液中发生应力腐蚀现象,产生氢鼓泡,最终产生裂纹,造成设备的损坏。     

Removal characteristics of CO2 using aqueous MEA/AMP solutions in the absorption and regeneration process

The carbon dioxide (CO2) removal efficiency, reaction rate, and CO2 loading into aqueous blended monoethanolamine (MEA) + 2-amino-2-methyl-1-propanol (AMP) solutions to enhance absorption characteristics of MEA and AMP were carried out by the absorption/regeneration process. As a result, compared to aqueous MEA and AMP solutions, aqueous blended MEA+AMP solutions have a higher CO2 loading than MEA and a higher reaction rate than AMP. The CO2 loading of rich amine of aqueous 18 wt.% MEA+12 wt.% AMP solution was 0.62 mol CO2/mol amine, which is 51.2% more than 30 wt.% MEA (0.41 mol CO2/mol amine). Consequently, blending MEA and AMP could be an effective way to design cousidering economical efficiency and used to operate absorber for a long time.     

二氯苯在盐水溶液中活度系数的研究

本文采用紫外分光光度法测定了２５．００±０．００１℃下间位和对位二氯苯在ＨＣＯＯＮａ,ＣＨ３ｃＯＯＮａ,（ＮＨ４）２ＳＯ４,ＭｇＳＯ４和Ｎａ２ＳＯ４水溶液中活度系数（ｆ）,它们的ｌｇｆ－Ｃ关系符合Ｓｅｔｓｃｈｎｏｗ盐效应公式。     

超声作用下羟丙基甲基纤维素抑尘剂的制备及应用

以羟丙基甲基纤维素、丙烯酸、丙烯酰胺等为原料,过硫酸铵为引发剂,二甲基二烯丙基氯化铵为交联剂,在超声作用下,通过水溶液聚合法合成出了一种羟丙基甲基纤维素抑尘剂,采用FT-IR,TGA,DSC,SEM等对产品进行了结构表征并对其抑尘性能进行了测试.结果表明,所合成的抑尘剂溶液稳定、成膜柔软、拉伸强度高.喷洒抑尘剂的煤样在...