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Graphene-supported nanoscale zero-valent iron:Removal of phosphorus from aqueous solution and mechanistic study 总被引:1,自引:0,他引:1
Fenglin Liu JingHe Yang Jiane Zuo Ding M Lili Gan Bangmi Xie Pei Wang Bo Yang 《环境科学学报(英文版)》2014,26(8):1751-1762
Excess phosphorus from non-point pollution sources is one of the key factors causing eutrophication in many lakes in China,so finding a cost-effective method to remove phosphorus from non-point pollution sources is very important for the health of the aqueous environment. Graphene was selected to support nanoscale zero-valent iron(nZVI)for phosphorus removal from synthetic rainwater runoff in this article. Compared with nZVI supported on other porous materials,graphene-supported nZVI(G-nZVI) could remove phosphorus more efficiently. The amount of nZVI in G-nZVI was an important factor in the removal of phosphorus by G-nZVI,and G-nZVI with 20 wt.% nZVI(20% G-nZVI)could remove phosphorus most efficiently. The nZVI was very stable and could disperse very well on graphene,as characterized by transmission electron microscopy(TEM) and scanning electron microscopy(SEM). X-ray photoelectron spectroscopy(XPS),Fourier Transform infrared spectroscopy(FT-IR) and Raman spectroscopy were used to elucidate the reaction process,and the results indicated that Fe-O-P was formed after phosphorus was adsorbed by G-nZVI. The results obtained from X-ray diffraction(XRD) indicated that the reaction product between nZVI supported on graphene and phosphorus was Fe3(PO4)2·8H2O(Vivianite). It was confirmed that the specific reaction mechanism for the removal of phosphorus with nZVI or G-nZVI was mainly due to chemical reaction between nZVI and phosphorus. 相似文献
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胺 活性特点: 胺可以看作氨分子中的氢原子被烃基取代而生成的化合物.胺中氮原子的电子构型是1S22S22P3,氮在氨和胺分子中是不等性的SP3杂化状态,其中3个杂化轨道与氢原子或烃基的碳原子形成3个σ键,第4个杂化轨道中还有一对未共用的电子,即(RH2N:).由于氮原子上有一孤电子对能与质子结合,呈现出胺的碱性,而氨分子中的氢原子被烷基取代后,连接在氮原子上的烷基是供电子性基团,可使胺离子正电荷分散而稳定.铵正离子愈稳定说明胺的碱性愈强,所以脂肪胺的碱性比氨强,与酸接触会生成盐;而芳香胺的碱性比脂肪胺和氨都弱,这是由于芳胺中的氮原子上的孤电子对与苯环的π电子组成共轭体系,产生了电子的离域,使氮原子上的孤电子对向苯环离域,铵离子正电荷更加集中,这样氮原子上的电荷密度减少,接受质子的能力降低,因此碱性减弱.在芳香胺中,氮原子上连的苯环愈多,其孤电子对向苯环离域愈多,则碱性随之降低,只有在与强酸作用时生成盐,且生成的盐在水溶液中完全水解.三苯胺已接近中性,即使和强酸也不能生成盐. 相似文献
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用Ultra-2,320μm柱分离2,4-滴,2,4-二氯酚肽2,4,6-三氯酚,保证了检测结果有足够的精确度,用直接进水样技术而不必处理水样,使检测结果趋精确。 相似文献
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从水溶液中分离回收醋酸方法的评述 总被引:15,自引:0,他引:15
评述了从水溶液中分离回收醋酸的普通精馏法、共沸精馏法、酯化法和溶剂萃取法,具体分析了各种方法 特点及适用范围。建议在工业上对较高浓度的醋酸用低沸点溶剂萃取-共沸精馏联合法,对低浓度醋酸溶液采用有机胺溶剂萃取法进行分离。 相似文献
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The degradation of nonylphenol (NP) in aqueous solution with UV, H2O2/UV, and Fenton/photo-Fenton processes was studied. The efficacy of direct and hydrogen peroxide photolysis proved to be dependent on the pH value. The addition of H2O2 to UV treatment improved NP degradation. The application of UV photolysis and the H2O2/UV system at pH 7 resulted in low pseudo first-order rate constants at 10-4 sec-1. In the experiments at elevated pH values the pseudo-first order rate constants increased to 10-3 sec-1. The efficacy of the Fenton process was lower in comparison with UV and hydrogen peroxide photolysis. The addition of UV irradiation to the H2O2/Fe2+ system substantially improved NP degradation efficacy. In terms of performance, the photo-Fenton process was similar to the H2O2/UV process. The most favourable process for complete nonylphenol degradation considering both operational cost and treatment efficacy was H2O2/UV at pH 11 and 250 mol/L H2O2. 相似文献
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