防雷接地技术在大型油库中的应用

对大型金属油罐库区接地网的等电位连接布局及其可靠性进行了探讨,以期完善设计、施工,使防雷、防静电工作水平提高,从而达到防火、防爆、安全运行的目的。     

流动电位法测定滤料表面的Zeta电位

滤料表面的ζ电位是评价滤料颗粒表面性质的重要指标之一,研究滤料表面的ζ电位对于提高过滤效率以及开发改性滤料是十分重要的.根据流动电位与ζ电位的关系自制了一套测定ζ电位的装置,经测定计算出了4种常用水处理滤料表面的ζ电位,结果表明:当滤料的粒径范围在0.45～0.9mm之间时,使用该装置测得的磁铁矿、无烟煤、核桃壳和陶粒表面ζ电位分别为-27.64mV、-6.54mV、-5.87mV、-2.30mV.电子能谱和红外光谱分析结果证明磁铁矿、无烟煤、核桃壳和陶粒滤料表面ζ电位的差异主要归因于其表面化学结构的不同.     

自动电位滴定仪测定氯化物的探讨

该实验就自动电位滴定仪测定氯化物的检出限、适用的水样pH范围及对其干扰物质的最大容忍浓度作了实验研究,对分析实际水样有一定的参考作用。     

大型浮顶储油罐雷击事故分析及防范对策

对几起典型的大型浮顶储油罐雷击事故进行了分析,总结了这些事故存在的共性问题。通过开展大型浮顶储油罐的直击雷及雷电感应模拟试验,找出大型浮顶储油罐导电片等现有防雷设施在设计和安装中存在的问题,提出了取消二次密封装置上的导电片、安装等电位连接装置等技术措施,以有效减少大型浮顶储油罐火灾事故的发生。     

样品保存方法对阳极溶出伏安法测定时的影响

对海水中Cu、Pb、Zn、Cd的日常监测分析方法进行了调查,结果表明在调查范围内阳极溶出伏安法使用数量最高。通过实验研究了不添加保存剂、加浓HNO3、加浓HClO4对阳极溶出伏安法测定海水Cu、Pb、Zn、Cd的影响。发现不添加保存剂时4种金属峰电位变化范围大、出现频次分散,分析方法灵敏度下降。不同类型酸对阳极溶出伏安法测定Pb、Zn、Cd时的峰电位变化影响不大,加浓HNO3时Cu的峰电位变化小于加浓HClO4。根据实验结果,推荐使用保存剂为浓HNO3。     

A potentiometric cobalt-based phosphate sensor based on screen-printing technology

A potentiometric cobalt-based screen-pritning sensor was fabricated by electroplating cobalt on the surface of a screen-printing electrode as the sensitive layer for the determination of dihydrogenphosphate （H2PO4） in wastewater samples. The electrochemical performance of this sensor was fully examined to determine its detection calibration, detection limit, response time, selectivity, and interference with pH, various ions, and dissolved oxygen （DO）. The cobalt-based phosphate sensor showed a phosphate-selective potential response in the range of 10 5mol·L^-1 to 10^-1 mol^-1, yielding a detection limit of 3.16 × 10μmol·L^l and a slope of -37.51 mV·decade＇ in an acidic solution （pH 4.0） of H2PO4-. DO and pH were found to interfere with sensor responses to phosphate. Ultimately, the performance of the sensor was validated for detecting wastewater samples from the Xiaojiahe Waste- water Treatment Plant against the standard speetrophotometric methods for HzPO4 analysis. The discrepancy between the two methods was generally ＋5% （relative standard deviation）. Aside from its high selectivity, sensitivity, and stability, which are comparable with conventional bulk Co-wire sensors, the proposed phosphate sensor presents many other advantages, such as low price, compactness, ease of use, and the possibility of integration with other analytical devices, such as flow injectors.     

Effects of bicarbonate and cathode potential on hydrogen production in a biocathode electrolysis cell

A biocathode with microbial catalyst in place of a noble metal was successfully developed for hydrogen evolution in a microbial electrolysis cell （MEC）. The strategy for fast biocathode cultivation was demonstrated. An exoelectrogenic reaction was initially extended with an H2-full atmosphere to enrich Ha-utilizing bacteria in a MEC bioanode. This bioanode was then inversely polarized with an applied voltage in a half-cell to enrich the hydrogen-evolving biocathode. The electrocatalytic hydrogen evolution reaction （HER） kinetics of the biocathode MEC could be enhanced by increasing the bicarbonate buffer concentration from 0.05 mol·L-1 to 0.5 mol· L-1 and/or by decreasing the cathode potential from -0.9 V to - 1.3 V vs. a saturated calomel electrode （SCE）. Within the tested potential region in this study, the HER rate of the biocathode MEC was primarily influenced by the microbial catalytic capability. In addition, increasing bicarbonate concentration enhances the electric migration rate of proton carriers. As a consequence, more mass H＋ can be released to accelerate the biocathode-catalyzed HER rate. A hydrogen production rate of 8.44 m3. m 3. d1 with a current density of 951.6 A. m-3 was obtained using the biocathode MEC under a cathode potential of - 1.3 V vs. SCE and 0.4 mol· L-1 bicarbonate. This study provided information on the optimization of hydrogen production in biocathode MEC and expanded the practical applications thereof.     

地震台站的雷电破坏与防护

像哨兵一样,日日夜夜,风雨无阻,密切监视着地球“脉搏”的地震台站,多数位于高山、丘陵和地质状况复杂的区域。其地理环境特征是周围没有高大建筑物,地下土壤电阻较高,是雷电频繁活动区域。而雷电的频频光顾,扰乱了地震台站的正常监测工作。随着“九五”成果在全国地震台站的普遍应用,“十五”项目的不断实施推进,数字化地震前兆台网已基本实现了     

杜绝挂接地线中常见的不正确行为

介绍在实际电气工作中,使用接地线时常出现的不正确行为,并依据接地线工作原理,对不正确行为进行剖析,提出纠正挂接地线错误行为的方法,以提高现场使用接地线的安全性.     

浅谈人体静电的产生与防范

有关资料表明,人体静电电位一般可达几千伏、上万伏,最高可达50kV,具有如此高静电电位的人体,一旦靠近或接触接地导体时,就不可避免地发生静电放电.人体静电导致的火花放电,瞬时功率有时高达几十瓦.因此,人体静电放电引燃引爆事故时有发生.