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191.
讨论了以FeSO4·7H2O和H2SO4为原料,以HNO3为催化剂通入空气氧化铁(Ⅱ)制备聚合硫酸铁的主要影响因素。实验表明:[SO42-]/[Fe]总=1.35~1.40为较合适的投料比例;HNO3的投料量约为原料FeSO4·7H2O投料的4%,反应温度为60~90℃,搅拌速度为400~600r/min,反应时间4h。反应后期pH基本不变;产品对活性大红溶液的净水处理结果较为满意,脱色率98.8%,COD的去除率为92%。 相似文献
192.
利用黄磷厂废渣作煅烧水泥熟料的矿化剂、水泥混合材和利用黄磷厂废渣生产胶凝材、白水泥是消除黄磷渣污染环境的有效途径;通过影响黄磷渣作水泥混合材和生产胶凝材因素的研究,推荐了提高黄磷渣作水泥混合材的掺量及生产优质胶凝材的工艺条件;黄磷渣的开发利用不仅可使企业获得显著的经济效益,而且可减少磷渣堆放占用耕地和消除磷渣对环境的污染,具有显著的经济效益、社会效益和环境效益。 相似文献
193.
硝酸及氯离子对高温硝酸铵水溶液热危险性的影响研究 总被引:3,自引:1,他引:3
国内外学者对硝酸铵的危险性进行了大量的研究,而对其水溶液的危险性至今开展不多。笔者采用差示扫描量热仪(DSC)及全自动反应量热仪(RC1e)对高温状态下的硝酸铵水溶液的热分解危险性、杂质离子对其稳定性的影响进行了研究。纯硝酸铵和90%硝酸铵水溶液的DSC实验表明,90%硝酸铵溶液和分析纯硝酸铵具有相似的热爆炸危险;90%硝酸铵水溶液在140~180℃之间的RC1e试验表明:硝酸或氯离子单独存在时,对硝酸铵分解都有不同程度的抑制作用,而同时存在时则大大降低体系的热稳定性。该结果对保障硝酸铵在生产、使用过程中的安全具有重要的参考价值。 相似文献
194.
"快速密闭催化消解法"因具有快速经济的优点而在日常监测中被广泛采用.但在标定稀硫酸亚铁铵溶液时,各站存在着使用不同标定方法的现象.本文通过实验讨论了稀硫酸亚铁铵溶液标定对水样COD分析的影响. 相似文献
195.
196.
The sludge, which was collected from a biological coke wastewater treatment plant, was used as a low-cost adsorbent in the removal of reactive dyes (methylene blue (MB) and reactive red 4 (RR4)) from aqueous solution. The pH of dye solution played an important role on the dye uptake. As the solution pH increase, the MB uptake increased, while the RR4 uptake decreased. The maximum uptake of RR4 by protonated sludge was 73.7 mg/g at pH 1, and the maximum uptake of MB by sludge was 235.3 mg/g at pH 9. Three functional groups, including carboxyl, phosphonate, and amine group, were identified by potentiometric titration, fourier transform infrared (FT-IR) spectrometry, and X-ray photoelectron spectroscopy (XPS). The anionic functional groups, phosphonate and carboxyl group, were identified as the binding sites for the cationic MB. Amine groups were identified to bind RR4. The main mechanism of the reactive dyestuffs adsorption is electrostatic interaction. 相似文献
197.
热爆炸理论在硝酸铵水溶液热安全性研究中的应用 总被引:1,自引:0,他引:1
本文概述了均温系统热爆炸非稳定理论,将其应用于含不同量杂质的硝酸铵水溶液体系中,并将临界爆炸温度和爆炸延滞期的试验值与计算值进行比较,结果表明应用热爆炸理论预先估算硝酸铵水溶液体系中达到任意升温的时间和预先计算达到预先选择的对应于爆炸的升温所需要的时间是可行的。 相似文献
198.
Solubilization of perchloroethylene (PCE) in a nonionic (Triton X-100) and a cationic (cetyltrimethylammonium bromide (CTAB))
surfactant solutions and the degradation of surfactant solubilized PCE using fine to nanosize Fe and bi-metallic Fe-Ni particles were
investigated. Micelle partition coefficients (Km) and molar solubility ratio (MSR) for PCE in 10 g/L of surfactant solutions have been
quantified and the solubility of PCE (100 mg/L in water) in the surfactant solutions increased by about ten fold. Of the two surfactants
studied, Triton X-100 solubilized the higher amount of PCE per gram of surfactant. To degrade solubilized PCE, both iron and bimetallic
Fe-Ni particles were used in continuously stirred batch reactors. The iron and bi-metallic particles were synthesized using the
solution method and the particles were characterized using the SEM, EDS, TEM and XRD. The PCE solubilized up to 500 mg/L in
both surfactant solutions were totally degraded at various rates by 200 g/L of bi-metallic Fe-Ni particles in less than 20 hr, which is the
highest concentration of PCE degraded in the shortest time compared to data in the literature. The degradations of PCE solubilized in
surfactant solutions were represented by nonlinear kinetic relationships which depended on the type of surfactant used for solubilizing
the PCE. 相似文献
199.
200.
Degradation of 4-CP in an internal electrolysis system 总被引:1,自引:0,他引:1
The characteristic and mechanism of parachlorophenol (4-CP) degradation in an internal electrolysis system were investigated. The degradation rate of 4-CP was higher in acid solution than that of in neutral or alkaline solution. Addition of activated carbon could make 4-CP easier be degraded by the surface contact catalysis. The dissolved oxygen in solution could take part in the electrode reaction and intensify the degradation of 4-CP. By the analysis of intermediates of degradation of 4-CP, it could be conferred that 4-CP was broken through the bond beside hydroxy firstly, then the bond beside chloride was broken and the chloride was dechlorinated simultaneously. Most intermediate products were glycerine, ethane diacid and acetic acid, while very few 1, 4-butanedial and alcohols were found. 相似文献