全文获取类型
收费全文 | 1851篇 |
免费 | 191篇 |
国内免费 | 587篇 |
专业分类
安全科学 | 354篇 |
废物处理 | 121篇 |
环保管理 | 144篇 |
综合类 | 1209篇 |
基础理论 | 235篇 |
污染及防治 | 352篇 |
评价与监测 | 36篇 |
社会与环境 | 32篇 |
灾害及防治 | 146篇 |
出版年
2024年 | 17篇 |
2023年 | 63篇 |
2022年 | 81篇 |
2021年 | 86篇 |
2020年 | 63篇 |
2019年 | 82篇 |
2018年 | 66篇 |
2017年 | 58篇 |
2016年 | 81篇 |
2015年 | 85篇 |
2014年 | 167篇 |
2013年 | 110篇 |
2012年 | 127篇 |
2011年 | 135篇 |
2010年 | 120篇 |
2009年 | 114篇 |
2008年 | 156篇 |
2007年 | 157篇 |
2006年 | 143篇 |
2005年 | 135篇 |
2004年 | 115篇 |
2003年 | 92篇 |
2002年 | 58篇 |
2001年 | 49篇 |
2000年 | 44篇 |
1999年 | 45篇 |
1998年 | 38篇 |
1997年 | 26篇 |
1996年 | 33篇 |
1995年 | 27篇 |
1994年 | 13篇 |
1993年 | 15篇 |
1992年 | 10篇 |
1991年 | 4篇 |
1990年 | 6篇 |
1989年 | 7篇 |
1988年 | 1篇 |
排序方式: 共有2629条查询结果,搜索用时 15 毫秒
101.
102.
The catalyst of Fe-Mo/ZSM-5 has been found to be more active than Fe-ZSM-5 and Mo/ZSM-5 separately for selective catalytic reduction (SCR) of nitric oxide (NO) with NH3. The kinetics of the SCR reaction in the presence of O2 was studied in this work. The results show that the observed reaction orders were 0.74-0.99, 0.01-0.13, and 0 for NO, O2 and NH3, respectively, at 350-450℃. And the apparent activation energy of the SCR was 65 kJ/mol on the Fe-Mo/ZSM-5 catalyst. The SCR mechanism was also deduced. Adsorbed NO species can react directly with adsorbed ammonia species on the active sites to form N2 and H2O. Gaseous O2 might serve as a reoxidizing agent for the active sites that have undergone reduction in the SCR process. It is also important to note that a certain amount of NO was decomposed directly over the Fe-Mo/ZSM-5 catalyst in the absence of NH3. 相似文献
103.
104.
Soonchul Kwon Maohong Fan Herbert F. M. DaCost Armistead G. Russell 《环境科学学报(英文版)》2011,23(8):1233-1239
Olivine, one of the most abundant minerals existing in nature, is explored as a CO2 carbonation agent for direct carbonation of
CO2 in flue gas. Olivine based CO2 capture is thermodynamically favorable and can form a stable carbonate for long-term storage.
Experimental results have shown that water vapor plays an important role in improving CO2 carbonation rate and capacities. Other
operation conditions including reaction temperature, initial CO2 concentration, residence time corresponding to the flow rate of CO2
gas stream, and water vapor concentration also considerably affect the performance of the technology. 相似文献
105.
The competition between submersed plants has been recognized as an important factor influencing the structure of plant communities
in shallow lakes. The ability of different species to take up and store nutrients from the surrounding ambience varies, and hence plant
community structure might be expected to affect the cycling of nutrients in lake ecosystems. In this study, the uptake of phosphorus
by Hydrilla verticillata and Vallisneria natans was studied and compared in monoculture and competitive mixed-culture plantings.
Results showed that for both studied species the phosphorus concentrations of different tissues and of whole plants was unaffected by
competition. However, the quantity of phosphorus accumulated by whole plants of H. verticillata was significantly higher in mixture
culture than in monoculture, while that of V. natans was lower in the mixed culture. The results indicated that H. verticillata has a
competitive advantage over V. natans, when the two species are grown in competition, and is able to accumulate a greater quantity of
phosphorus. 相似文献
106.
Visible light responsive N-F-codoped TiO2 photocatalysts exhibit a higher catalytic activity than N-doped TiO2 for the degradation of 4-chlorophenol due to the synergistic effect of nonmetal elements. 相似文献
107.
在当前全球竞争的背景下,我国的尾气排放产业所面临的知识产权问题非常突出,国内的各个企业面临的知识产权问题各有不同,非常复杂,而大多数企业并不像发达国家的大型企业一样拥有负责专利管理、专利情报收集与分析、专利对策研究与发展战略研究的部门。 相似文献
108.
109.
110.
采用搅拌流动法研究了酸性水钠锰矿及水羟锰矿2种δ-MnO2矿物氧化As(Ⅲ)的动力学过程,构建了可用于多相体系的搅拌-流动氧化还原反应动力学模型.经过As吸附量的校正后,该模型对酸性水钠锰矿及水羟锰矿氧化As(Ⅲ)动力学数据拟合度分别为0.980和0.951,模型拟合得到pH 7时2种矿物单位比表面上氧化As(Ⅲ)的初始反应速率常数k分别为0.131,0.014min-1·m-2.相比而言,该速率常数明显高于批量法得到的表观速率常数kobs,0.021,0.001min-1?m-2更接近真实的化学动力学参数.搅拌流动法与批量法得到的不同矿物的速率常数大小趋势一致,即尽管酸性水钠锰矿对As(Ⅲ)的氧化率低于水羟锰矿,单位比表面上酸性水钠锰矿氧化As(Ⅲ)初始反应速率却远高于水羟锰矿.反应过程分析表明,反应初始阶段,As(Ⅲ)的吸附为主要限速步骤;而随着反应的进行,矿物表面反应位点逐渐钝化或减少,反应位点数量成为限速步骤. 相似文献