催化剂生产技术产业化研究

简要叙述催化剂生产技术工程化，产业化和生产工艺全过程质量控制，确保产品的一致性和性能稳定性。     

应用故障树法分析γ-Al2O3涂层质量的影响因素

应用故障树分析法，找到导致γ-Al2O3涂层质量不好的18个基本因素。应用故障树分析原理，对这18个因素的结构重要度进行了详细的分析。根据分析结果，结合大量实验数据和事实系统讨论了这18个因素对γ-Al2O3涂层质量的影响程度。研究结果表明，焙烧温度、焙烧时间、造孔剂种类及用量对涂层质量影响最大；应用故障树法分析γ-Al2O3涂层质量的影响因素是可行的，能给实验研究提供一定的理论指导。     

CH-20加氢催化剂的器外再生与工业应用

介绍了中石化长岭分公司300kt/a加氢装置使用的CH-20加氢催化剂器外再生前后催化剂性质对比和再生剂的工业应用情况,说明CH-20加氢催化剂器外再生后,催化剂活性得到了很好的恢复,不仅带来了可观的经济效益和环保效益,而且保证了装置长周期运转.     

炭-催化剂性能对8#滤毒罐防毒性能的影响分析

8~#滤毒罐是专门防护硫化氢气体的防护器材,所装填的药层是炭—催化剂,因此,炭—催化剂性能的优劣决定着滤毒罐防毒时间的长短。也就是说,炭—催化剂性能好,所装填的8~#罐的防毒时间就长;炭—催化剂的性能差,8~#罐的防毒时间就短。 通常,8~#滤毒罐是靠化学吸着作用达到防毒的目的。化学吸着是由吸附质与吸附剂分子之间以类似化学链的力相吸发生的,吸附质与吸附剂形成表面化合物,吸附热较高,有选择性,通常不可逆,炭—催化剂借助于     

OH radicals generated by DC corona discharge for improving the pulsed discharge desulfuration efficiency

Positive DC corona discharge is formed with needle-plate electrode configuration, in which the water vapor is ejected though the needle points. The purpose is to increase the numbers of the water-based radicals, ionize the water molecule and improve the desulfuration efficiency of pulsed corona reactor. The water ions were determined by four stages molecular beam mass spectrometer and diagnose the water-based radicals by emission spectrograph. A conclusion on formation of ions and radicals with DC corona discharges can be drawn.     

Kinetics study on catalytic wet air oxidation of phenol by several metal oxide catalysts

Four metal oxide catalysts composed of copper (Cu), stannum (Sn), copper-stannum (Cu-Sn) and copper-cerium(Cu-Ce) respectively were prepared by the co-impregnation method, and γ-alumina(γ-Al2O3 ) is selected as support. A first-order kinetics model was established to study the catalytic wet air oxidation of phenol at different temperature when these catalysts were used. The model simulations are good agreement with present experimental data. Results showed that the reaction rate constants can be significantly increased when catalysts were used, and the catalyst of 6% Cu-10% Ce/γ-Al2 O3 showed the best catalytic activity. This is consistent witht he result of catalytic wet air oxidation of phenol and the COD removal can be arrived at 98.2% at temperature 210℃, oxygen partial pressure 3 MPa and reaction time 30 rain. The activation energies of each reaction with different catalysts are nearly equal, which is found to be about 42 kJ/mol and the reaction in this study is proved to be kinetics control.     

高效、多功能一氧化碳防护材料

本文介绍了一种高效、多功能的钯-炭型（Pd/C）一氧化碳（CO）常温催化剂。装罐试验表明：在该催化剂装药量为35～50g的条件下，对模拟呼吸量为30L/min、初始CO浓度为3125mg/m^3的CO净化率大于99.5%，防护时间可达数小时，同时对氢氧酸（HCN）、有机气体等具有很好的综合防护效果。与传统的霍加拉特剂相比，该催化剂具有防护效能高、抗温性和抗陈化性强的突出特点。     

聚/表型复合压裂液性能及其对煤样甲烷吸附解吸特性影响实验研究

为弥补常规压裂液破胶困难、残留多或黏度低、用量大等缺点,将疏水改性羟丙基瓜尔胶与双子表面活性剂进行交联复配,制得1种疏水聚合物/表面活性剂复合压裂液,从黏度、破胶性能以及对煤样甲烷吸附解吸能力影响等方面与常规压裂液进行对比分析。研究结果表明：在同等表面活性剂质量分数下,加入疏水改性羟丙基瓜尔胶的复合压裂液黏度是单组份表面活性剂压裂液的3倍,其破胶时间与表面活性剂压裂液几乎无差别,且仅为HPG压裂液的1/2;复合压裂液对煤样甲烷吸附解吸能力影响明显低于HPG压裂液,其吸附损伤因子虽高于表面活性剂压裂液,但比HPG压裂液低24%。研究结果可为矿用复合压裂液研制提供参考。     

“绿色”纤维增强水泥基复合材料的研究及发展

纤维增强材料对于改善水泥基材料的韧性和抗冲击性、大幅度提高混凝土的断裂能、防止混凝土发生脆性破坏具有重要意义;而"绿色"纤维在提高混凝土结构安全性的同时,具有环保、节能、利废、可降解再生等特性。本文介绍了"绿色"纤维的分类,分析了"绿色"纤维增强水泥基材料的特点,总结了"绿色"纤维在水泥基材料中应用、研究的进展。指出:"绿色"纤维与水泥基材料复合,适应循环经济和建材行业可持续发展的要求,是未来纤维增强水泥基复合材料发展的主要方向。