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924.
以含钛高炉渣为原料采用加热法制备肥料,以提高其溶解性能,使其中的营养元素转化为易被植物吸收利用的形式,并通过栽培实验研究了肥料对大豆生长状况、性状、产量和营养成分的影响。结果表明:炉渣中Mg、Ti、Fe的溶出率分别为88%、84%和75%,肥料中可被植物有效利用的元素有氮、硅、硫、钙、镁、铁和钛。该肥料可以使大豆产量、百粒重和叶片叶绿素含量明显增加;生育期缩短2 d;籽粒的氮、磷和钾含量显著增加,蛋白质和淀粉含量增加。施用该固态复合肥并未导致钒和铬等重金属元素在大豆体内的富集。 相似文献
925.
为提高催化剂光催化降解煤矿瓦斯效率,运用溶胶-凝胶浸渍过程将具有优异吸附性能的活性炭颗粒引入催化剂,制备了新型复合催化剂Ga2O3/AC。采用XRD、SEM、N2吸附等方法对新型复合催化剂的结构形貌及比表面积进行理化表征,验证了复合催化剂制备方法的可行性。同时以真空紫外灯为光源,进行光催化氧化降解瓦斯的模拟实验,对比考察Ga2O3、活性炭颗粒及复合催化剂的光催化活性。结果表明,相比单一Ga2O3,复合催化剂光照时间为180 min后对甲烷的降解率提高了13%,达到100%去除率。 相似文献
926.
利用X射线晶格衍射(XRD)、N2吸附和X射线光电子能谱仪(XPS)等对铈和钛掺杂后的铁氧化物晶相、孔隙结构及表面活性组分的分散度等物性进行表征分析,得到了铈和钛掺杂对铁氧化物低温NH3-SCR脱硝性能的促进机理.结果表明:铈和钛掺杂会抑制铁氧化物中Fe2O3的结晶,细化其孔径,增大其比表面积和比孔容;铈掺杂会促使铁氧化物表面形成Ce4+/Ce3+氧化还原电子对;进一步掺杂钛会提高铁铈复合氧化物形成更多吸附氧,增强其表面低温催化氧化NO为NO2的性能;且铈和钛掺杂增强了铁氧化物表面的吸附性能,尤其提高了对NH3的低温吸附,从而促进了铁基氧化物催化剂的低温NH3-SCR脱硝性能. 相似文献
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Lei ZHU Xiaohong ZHOU Hanchang SHI 《Frontiers of Environmental Science & Engineering》2014,8(6):945-951
A potentiometric cobalt-based screen-pritning sensor was fabricated by electroplating cobalt on the surface of a screen-printing electrode as the sensitive layer for the determination of dihydrogenphosphate (H2PO4) in wastewater samples. The electrochemical performance of this sensor was fully examined to determine its detection calibration, detection limit, response time, selectivity, and interference with pH, various ions, and dissolved oxygen (DO). The cobalt-based phosphate sensor showed a phosphate-selective potential response in the range of 10 5mol·L^-1 to 10^-1 mol^-1, yielding a detection limit of 3.16 × 10μmol·L^l and a slope of -37.51 mV·decade' in an acidic solution (pH 4.0) of H2PO4-. DO and pH were found to interfere with sensor responses to phosphate. Ultimately, the performance of the sensor was validated for detecting wastewater samples from the Xiaojiahe Waste- water Treatment Plant against the standard speetrophotometric methods for HzPO4 analysis. The discrepancy between the two methods was generally +5% (relative standard deviation). Aside from its high selectivity, sensitivity, and stability, which are comparable with conventional bulk Co-wire sensors, the proposed phosphate sensor presents many other advantages, such as low price, compactness, ease of use, and the possibility of integration with other analytical devices, such as flow injectors. 相似文献
929.
Zongcheng Zhan Xiaojun Liu Dongzhu Ma Liyun Song Jinzhou Li Hong He Hongxing Dai 《Frontiers of Environmental Science & Engineering》2014,8(4):483-495
A novel Ultrasonic Assisted Membrane Reduction (UAMR)-hydrothermal method was used to prepare flower-like Pt/CeO2 catalysts. The texture, physical/chemical properties, and reducibility of the flower-like Pt/CeO2 catalysts were characterized by X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), N2 adsorption, and hydrogen temperature programmed reduction (HE-TPR) techniques. The catalytic performance of the catalysts for treating automobile emission was studied relative to samples prepared by the conventional wetness impregnation method. The Pt/CeO2 catalysts fabricated by this novel method showed high specific surface area and metal dispersion, excellent three-way catalytic activity, and good thermal stability. The strong interaction between the Pt nanoparticles and CeO2 improved the thermal stability. The Ce4+ ions were incorporated into the surfactant chains and the Pt nanoparticles were stabilized through an exchange reaction of the surface hydroxyl groups. The SEM results demonstrated that the Pt/CeO2 catalysts had a typical three-dimensional (3D) hierarchical porous struc- ture, which was favorable for surface reaction and enhanced the exposure degree of the Pt nanoparticles. In brief, the flower-like Pt/CeO2 catalysts prepared by UAMR-hydrothermal method exhibited a higher Pt metal dispersion, smaller particle size, better three-way catalytic activity, and improved thermal stability versus conven- tional materials. 相似文献
930.
Dawei LIANG Yanyan LIU Sikan PENG Fei LAN Shanfu LU Yan XIANG 《Frontiers of Environmental Science & Engineering》2014,8(4):624-630
A biocathode with microbial catalyst in place of a noble metal was successfully developed for hydrogen evolution in a microbial electrolysis cell (MEC). The strategy for fast biocathode cultivation was demonstrated. An exoelectrogenic reaction was initially extended with an H2-full atmosphere to enrich Ha-utilizing bacteria in a MEC bioanode. This bioanode was then inversely polarized with an applied voltage in a half-cell to enrich the hydrogen-evolving biocathode. The electrocatalytic hydrogen evolution reaction (HER) kinetics of the biocathode MEC could be enhanced by increasing the bicarbonate buffer concentration from 0.05 mol·L-1 to 0.5 mol· L-1 and/or by decreasing the cathode potential from -0.9 V to - 1.3 V vs. a saturated calomel electrode (SCE). Within the tested potential region in this study, the HER rate of the biocathode MEC was primarily influenced by the microbial catalytic capability. In addition, increasing bicarbonate concentration enhances the electric migration rate of proton carriers. As a consequence, more mass H+ can be released to accelerate the biocathode-catalyzed HER rate. A hydrogen production rate of 8.44 m3. m 3. d1 with a current density of 951.6 A. m-3 was obtained using the biocathode MEC under a cathode potential of - 1.3 V vs. SCE and 0.4 mol· L-1 bicarbonate. This study provided information on the optimization of hydrogen production in biocathode MEC and expanded the practical applications thereof. 相似文献