超临界水氧化技术研究进展

超临界水氧化技术是一种新兴的、高效的高级氧化技术具有广阔的应用前景。该方法具有独特的技术性和经济性。主要介绍超临界氧化技术的研究现状、应用领域,同时指出存在的问题和对策及发展前景分析。     

Molecular characterization and developmental expression patterns of thyroid hormone receptors (TRs) and their responsiveness to TR agonist and antagonist in Rana nigromaculata

Considering some advantages of Rana nigromaculata as an experimental species, we propose that this species, like Xenopus laevis, could be used to assay thyroid hormone（TH） signaling disrupting actions. To validate the utilizability of R. nigromaculata, we investigated the responsiveness of R. nigromaculata to a TH receptor（TR） agonist（T3） and antagonist（amiodarone） by analyzing expression, based on characterizing TR cDNA and developmental expression patterns. With high levels of identity with the corresponding genes in X. laevis, both TRα and TRβ in R. nigromaculata exhibited roughly similar developmental expression patterns to those of X. laevis, in spite of some species-specific differences. Both TRα and TRβ expression had greater changes in the liver and intestine than in the tail and brain during metamorphosis. T3 exposure for 2 days induced more dramatic increases of TRβ expression in stage 27 than in stage34 tadpoles but not in stage 42 tadpoles, showing that the responsiveness of R. nigromaculata to TH decreased with development and disappeared at the onset of metamorphic climax.Corresponding to greater changes of TRβ expression in the liver and intestine than in the tail and brain during metamorphosis, the liver and intestine had higher responsiveness to exogenous T3 than the tail and brain. Amiodarone inhibited T3-induced TRβ expression. Our results show that R. nigromaculata can be used as a model species for assaying TH signaling disrupting actions by analyzing TRβ expression, and intestine tissues at stage 27 are ideal test materials due to high responsiveness and easy accessibility.     

Two-step accelerated mineral carbonation and decomposition analysis for the reduction of CO2 emission in the eco-industrial parks

Carbon dioxide（CO2） emissions are a leading contributor to the negative effects of global warming. Globally, research has focused on effective means of reducing and mitigating CO2 emissions. In this study, we examined the efficacy of eco-industrial parks（EIPs） and accelerated mineral carbonation techniques in reducing CO2 emissions in South Korea.First, we used Logarithmic Mean Divisia Index（LMDI） analysis to determine the trends in carbon production and mitigation at the existing EIPs. We found that, although CO2 was generated as byproducts and wastes of production at these EIPs, improved energy intensity effects occurred at all EIPs, and we strongly believe that EIPs are a strong alternative to traditional industrial complexes for reducing net carbon emissions. We also examined the optimal conditions for using accelerated mineral carbonation to dispose of hazardous fly ash produced through the incineration of municipal solid wastes at these EIPs. We determined that this technique most efficiently sequestered CO2 when micro-bubbling, low flow rate inlet gas, and ammonia additives were employed.     

钴胁迫下红苋菜中钴积累分布及其生理特性的研究

采用模拟钴污染土壤的方法,研究不同程度的钴(0、20、40、60 mg/kg)胁迫对成熟期红苋菜生长及其体内钴积累分布和生理特性的影响。结果表明:(1)同一钴胁迫下,红苋菜株高差异性大,株高差值(最高与最矮的差值)范围为14~27 cm,远大于对照组的4 cm;(2)在不同程度的钴胁迫下,植株各部位钴含量分布规律不一致,且根部钴含量最高。当胁迫浓度为60 mg/kg,植株长势最差组的根、茎、叶部钴含量最高,分别为对照组的41、44和14倍,此时地上部和单株的钴积累量均最大,分别为1 103和1 275μg,且两者的积累量与MDA含量成极显著正相关;(3)钴胁迫使得叶片叶绿素含量、CAT和POD酶活性均出现不同程度的降低,SOD酶活性仅在低浓度的钴胁迫下上升,而MDA含量则上升;(4)钴胁迫下植株对钴的转运系数为0.20~0.64,地上富集系数为1.96~10.06,同一胁迫下,长势最差组的转运系数和地上富集系数最大。     

专利资讯

专利名称：从废锂电池中回收硫酸锂和氢氧化钴的方法 到目前全国手机用户已经超过2亿,其中使用锂电池的手机约占三分之二,如果按每个锂电池重为50g,按每部手机每年更换一次电池,每年就会产生666．7t／a电池垃圾,再加上其他电器的使用,全国所产生的废锂电池垃圾超过1000t／a,这些电池垃圾中含有碱、钴酸锂等物质。     

工业和信息化部发布第三批废钢铁加工行业准入企业名单

正2014年第57号根据《废钢铁加工行业准入条件》和《废钢铁加工行业准入公告管理暂行办法》,经企业申报,省级工业和信息化主管部门初核,专家复审,现场核实及网上公示等程序,并征得环境保护部同意,现将符合《废钢铁加工行业准入条件》企业名单(第三批)予以公告。附件:符合《废钢铁加工行业准入条件》企业名单(第三批)     

工信部发布第四批《再制造产品目录》

正中华人民共和国工业和信息化部公告2014年第50号为推动再制造产业健康有序发展,加强再制造行业管理,确保再制造产品质量,引导再制造产品消费,根据《再制造产品认定管理暂行办法》(工信部节[2010]303号)及《再制造产品认定实施指南》(工信厅节[2010]192号),经过现场审核、产品检验与综合技术评定,并经专家论证,天津光电久远科技有限公司、浙江金龙电机股份有限公司等7家企业3大类26种产品符合再制造产品认定相关要求,列入《再制造产品目录(第四批)》,现予公告。     

汞分析仪直接测定土壤中总汞的方法研究

建立了利用RP91C-RA915M汞分析仪直接测定土壤中总汞的方法。该方法直接固体进样,省去了常规方法加酸消解、赶酸、定容等繁琐的前处理步骤;利用标准土壤绘制工作曲线,无需反复稀释标准储备液配制标准溶液,测定了方法检出限、精密度及准确度。结果表明此方法准确、可靠,是一个比较理想的分析方法。本方法的检出限为0.25μg/kg,相对标准偏差为1.98%~4.92%,标准样品测定准确,加标回收率为92.8%~106%。     

气相色谱法测定水中的三氯乙醛

建立了一种用气相色谱法测定水体中三氯乙醛的方法。水样先以石油醚萃取,除去高沸点化合物,加入氯化钠破乳,然后再用石油醚—乙醚混合溶剂(V/V=2:1)萃取3次,萃取液经色谱柱分离,用电子捕获检测器检测。最低检出浓度可达0.008 mg/L,线性关系良好(相关系数γ=0.992~0.998),一般共存物质不干扰测定。     

便携式溶解氧仪法测定水中溶解氧相关问题探讨

分析总结了便携式溶解氧仪法测定水中溶解氧应注意的一些问题,提出了相应的解决措施,以确保水中溶解氧分析测定结果满足环境监测数据"五性"要求。