氟苯胺同系物降解性能对比实验研究

利用驯化污泥研究了邻氟苯胺、对氟苯胺、2,4-二氟苯胺的好氧生物降解性能.结果表明,3种氟苯胺的好氧生物降解性能从高到低依次为,对氟苯胺、邻氟苯胺和2,4-二氟苯胺.降解动力学分析表明,在初始浓度在8～50 mg·L^-1范围内,除2,4-二氟苯胺在实验浓度8.56 mg/L时为一级反应,其他为零级反应.且它们的降解规律都符合Monod方程.污染物化学结构特性与其生物降解性能相关性研究表明,热力学参数与氟苯胺好氧生物降解性能相关性最好,空间参数次之,而电性参数最差.并研究了共代谢条件下葡萄糖和苯胺对2,4-二氟苯胺的好氧降解的影响,葡萄糖的引入有促进作用,而苯胺只在一定浓度范围内有促进作用.因而,氟苯胺的生产废水与生活污水合并处理以及多种组分混合废水处理是可行的.     

AF反应器对芳香族化合物反硝化降解特性研究

以苯、联苯和萘为模型化合物,研究了厌氧滤池（AF）反应器在反硝化及连续运行条件下对含这几种芳香族化合物模拟废水的处理效果,并以葡萄糖为补充碳源,考察了不同C/N对有机物反硝化降解特性的影响.结果表明,在长期连续流运行及反硝化条件下,AF反应器对废水中几种典型芳香族化合物具有良好地去除效果,当进水COD浓度约为1?000mg/L,苯、联苯和萘总浓度为60mg/L时,出水COD去除率可达到90％,芳香族化合物的去除率可达到84％.苯比萘和联苯更易于反硝化降解.C/N在5～30范围内,苯的降解率均达到90%,C/N对苯的降解没有明显影响;COD、萘和联苯去除率受C/N影响较大,C/N为15时,COD、萘和联苯去除率最大,分别为90%、78%和82%.     

土地渗滤处理系统中微生物数量变化的初步研究

本文分析了北方寒冷地区城市污水在土地渗滤系统处理中细菌总数和粪大肠菌群数变化情况,并探讨了处理效果。     

中国煤矿安全事故损失计算模型研究

分析了煤矿安全事故处理过程中可能发生的各项经济损失,根据它们的特征和性质将其划分为直接价值因素损失、间接价值因素损失和非价值性因素损失3大类.引入伤害分级比例系数法进行事故人员伤亡价值损失的估算,有利于对伤亡矿工赔付额的界定.建立了煤矿事故损失计算模型,同时给出了各项费用的计算公式,并将该模型应用于我国辽宁孙家湾"2.14"煤矿事故的损失计算,对计算结果进行了分析,并进行经济损失程度分级.结果显示,模型计算得到损失大小和损失组成特点符合实际.     

河南省雷暴日数时空分布的非均一性特征

利用河南省气候中心编制的97个台站1961-2000年雷暴日数的资料,对该省境内雷暴发生的时空分布非均一性进行了分析.结果表明:全省平均雷暴日数有明显下降的趋势;雷暴日数站间偏度系数具有明显的年际变化特征,80%的年代表现为正偏;而其峰度系数则60%的年份为负值,且具有明显的年际变化特征.年平均雷暴日数及其均方差空间分布型态比较一致.豫北、豫西和豫东南分别出现3个雷暴高发区,其中豫东南强度最大,豫西强度与其相当,豫北相对较小.历年雷暴日数以正偏为主;峰度系数则以负值为主.河南省除信阳地区外,各站雷暴日数在0.05置信水平上服从正态分布.     

运动鞋鞋底防滑性能的研究进展

本文论述了国内外在鞋底防滑性能方面的研究现状,对其发展趋势做了预测,有助于进一步研究鞋底的防滑性能,以提高运动鞋的质量,对着穿者在运动中的保护起到更好的作用,有助于运动质量的提高。     

雇员安全意识培养的心理学研究维度

HSE是一个系统和复杂的过程,在目前体系相对完善的情况下,如何提高雇员的安全意识,积极主动执行体系各项规定是人们关注的问题。该文从心理学角度探讨了影响雇员安全意识培养的三个方面,通过雇员社会认同性的实现,儿童趣味性与社会竞争性的结合以及人类认识能力巩固的周期性三个心理学研究维度进行了充分的论述,通过提高认识,将有助于增强雇员的安全意识,从而推进HSE管理。     

Aerobic degradation of methyl tert-butyl ether by a Proteobacteria strain in a closed culture system

The contamination of methyl ten-butyl ether （MTBE） in underground waters has become a widely concerned problem all over the world. In this study, a novel dosed culture system with oxygen supplied by H2O2 was introduced for MTBE aerobic biodegradation. After 7 d, almost all MTBE was degraded by a pure culture, a member of β-Proteobacteria named as PMI, in a closed system with oxygen supply, while only 40% MTBE was degraded in one without oxygen supply. Dissolved oxygen （DO） levels of the broth in closed systems respectively with and without H2O2 were about 5-6 and 4 mg/L. Higher DO may improve the activity of monooxygemase, which is the key enzyme of metabolic pathway from MTBE to tert-butyl alcohol and finally to CO2, and may result in the increase of the degrading activity of PM1 cell. The purge and trap GC-MS result of the broth in closed systems showed that tea-butyl alcohol, isopronol and acetone were the main intermediate products.     

Effect of sulfate on the methanogenic activity of a bacterial culture from a brewery wastewater during glucose degradation

The maximum specific methanogenic activity （SMA） of a sludge originating from a brewery wastewater treatment plant on the degradation of glucose was investigated at various levels of sulfate on a specific loading basis. Batch experiments were conducted in serum bottles at pH 7 and 35℃. A comparison of the values indicates that the SMA of this mixed culture was increased and reached its highest level of 0.128 g CH4 gas COD/（g VSS.d） when biomass was in contact with sulfate at a ratio of 1：0.114 by weight.     

Imazaquin degradation and metabolism in a sandy loam soil amended with farm litters

Irnazaquin applied in legume crops has a long residual time in soil, which often impacts safety of the susceptible crops. To increase safety of imazaquin application, two composted litters, bovine manure （BM） and chicken manure （CM）, were used to determine their effects on imazaquin environmental behavior by incorporating each kind of manure into the tested sandy loam soil at 10% （w/w）. The degradation of imazaquin in BM- and CM-amended soil was about 2.4 and 1.5 times, respectively, faster than that in unamended soil. The half-lives of imazaquin in BM-amended soil varied between 6.7 and 15.4 d over the temperature range of 20 to 40℃, and the degradation rate constant （k） increased by a factor of about 1.5 for every 10℃ change. Higher mix ratio did not significantly increase the degradation, and the optimal active degradation of imazaquin was observed approximately at the mix ratio of 10：1 of soil to BM. The different moisture levels had negligible effect on imazaquin degradation. In both unamended and BM-amended treatments, two metabolites were observed at 5, 10 and 30 d after treatment. One metabolite at retention time （RT） of 8.4 rain was identified as 2-（4- hydroxyl-5-oxo-2-imidazolin-2-yl） quinoline acid, originating from the loss of isopropyl group and hydroxylation at the 4-position of imidazolinone ring. The other at RT of 12.9 rain was identified as quinoline-2,3-dicarboxylic anhydride, resulting from detachment of imidazolinone ring and the forming of dicarboxylic anhydride. This finding suggested that the addition of farm litters into soil might be a good management option since it can not only increase soil fertility but also contribute to increase safety of imazaquin application to the following susceptible crops.