全文获取类型
收费全文 | 1831篇 |
免费 | 423篇 |
国内免费 | 322篇 |
专业分类
安全科学 | 173篇 |
废物处理 | 135篇 |
环保管理 | 171篇 |
综合类 | 790篇 |
基础理论 | 941篇 |
污染及防治 | 246篇 |
评价与监测 | 88篇 |
社会与环境 | 13篇 |
灾害及防治 | 19篇 |
出版年
2024年 | 1篇 |
2023年 | 12篇 |
2022年 | 30篇 |
2021年 | 33篇 |
2020年 | 30篇 |
2019年 | 63篇 |
2018年 | 127篇 |
2017年 | 113篇 |
2016年 | 91篇 |
2015年 | 100篇 |
2014年 | 255篇 |
2013年 | 240篇 |
2012年 | 280篇 |
2011年 | 242篇 |
2010年 | 213篇 |
2009年 | 164篇 |
2008年 | 118篇 |
2007年 | 56篇 |
2006年 | 47篇 |
2005年 | 43篇 |
2004年 | 42篇 |
2003年 | 33篇 |
2002年 | 25篇 |
2001年 | 25篇 |
2000年 | 22篇 |
1999年 | 20篇 |
1998年 | 17篇 |
1997年 | 15篇 |
1996年 | 20篇 |
1995年 | 18篇 |
1994年 | 13篇 |
1993年 | 13篇 |
1992年 | 15篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1989年 | 6篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有2576条查询结果,搜索用时 62 毫秒
101.
Process of rice straw degradation and dynamic trend of pH by the microbial community MC1 总被引:7,自引:1,他引:6
LIU Jian-bin WANG Wei-dong YANG Hong-yan WANG Xiao-fen GAO Li-juan CUI Zong-jun 《环境科学学报(英文版)》2006,18(6):1142-1146
The process of the rice straw degradation in the fermentor with aeration at 290 ml/h was studied. The results of dissolved oxygen (DO) indicated that the optimum DO during cellulose degradation by microbial community MC1 ranged from 0.01 to 0.12 mg/L. The change model ofpH values was as follows: irrespective of the initial pH of the medium, pH values decreased rapidly to approximate 6.0 after being inoculated within 48 h when cellulose was strongly degraded, and then increased slowly to 8.0--9.0 until cellulose was degraded completely. During the degradation process, 15 kinds of organic compounds were checked out by GC-MS. Most of them were organic acids. Quantity analysis was carried out, and the maximum content compound was ethyl acetate which reached 13.56 g/L on the day 4. The cellulose degradation quantity and ratio analyses showed that less quantity (under batch fermentation conditions) and longer interval (under semi-fermentation conditions) of rice straw added to fermentation system were contributed to matching the change model of pH, and increasing the quantity and ratio of rice straw degradation during cellulose degrading process. The highest degradation ratio was observed under the condition office straw added one time every five days (under semi-fermentation conditions). 相似文献
102.
张慧杰 《中国安全生产科学技术》2020,16(5):51-56
针对时间因素对钻屑瓦斯解吸指标K1测定结果的影响,采用恒温瓦斯放散试验深入分析钻屑瓦斯解吸指标K1测定理论的准确性,总结因时间因素导致K1值测定误差所带来的现场问题。研究结果表明:K1值的测定误差与时间关系密切,测定启动时间越晚,误差越大;测定启动时间由第1 min延后至第2 min,绝对误差和相对误差最大值分别增加0.081 cm3/(g·min1/2)和2.20%;高瓦斯压力条件矿井或煤层的局部高瓦斯压力区域、构造煤发育区的钻屑瓦斯解吸指标K1值测定结果偏低,测定误差偏大。研究结果可为煤与瓦斯突出预测水平的提升提供技术支撑。 相似文献
103.
Steroid estrogens such as estrone (E1), 17β-estradiol (E2), estriol (E3), and 17α-ethynylestradiol (EE2) have been suspected to be the main contaminants, which can affect the endocrine system of animals. Many authors have investigated these chemicals in the domestic wastewater treatment plants (WTP). However, wastewater from industries producing steroid contraceptives has not got ample attention. From the environmental point of view, the four steroids are very significant because even very low concentrations (ng/L) can cause reproductive disturbances in human, livestock and wildlife. The main purpose of the present investigation was to develop an analytical method for the determination of the four steroid estrogens present in WTP of a pharmacy factory, mainly producing contraceptive medicine in Beijing, China. Analysis was performed by solid-phase extraction (SPE) system and liquid chromatography combined with tandem mass spectrometry (LC/MS/MS). The average recoveries from effluent samples ranged from 88% to 103% and the precision of the method ranged from 9% to 4%. Based on 0.5-L wastewater samples, the limit of quantification (LOQ) was determined at 0.7 ng/L for E1, 0.8 for E2, 0.9 ng/L for E3, and 0.5 ng/L for EE2 in influent, and 1.0 ng/L for E2 and EE2, and 2.0 ng/L for E1 and E3 in effluent. In the influent samples, average concentrations of 80, 85, 73 and 155 ng/L were determined for E1, E2, E3 and EE2, respectively, showing that they were removed in this WTP to the extent of 79, 73, 85 and 67%, respectively. 相似文献
104.
105.
106.
The growth properties and biodegradation mechanism of a Gram-negative bacterium, Pseudomonas nitroreducens TX1 that was able to grow on branched octylphenol polyethoxylates (OPEO(n), average n=9.5) as the sole carbon source over a wide concentration range (1-100,000 mgl(-1)) were studied. Analysis of growth factors indicated the highest specific growth rate (micro) of 0.53 h(-1) was obtained at an initial concentration of 5,000 mgl(-1) OPEO(n). An optimal C/N ratio of 12 was obtained for (NH(4))(2)SO(4) as the nitrogen source in a cultivated medium at pH 7. The kinetic analysis demonstrated that bacterial growth and OPEO(n) degradation followed the Monod equation and were based on a substrate concentration inhibition model and pseudo-first-order reaction, respectively. The substrate inhibition coefficient was over 18,000 mgl(-1) and this indicates that the strain has an ability to sustain growth at high concentrations of OPEO(n) and use it as the sole carbon source under such a stress condition. Furthermore, LC-MS analysis showed that the biodegradation mechanism of dodecyl octaethoxylate (AEO8) by P. nitroreducens TX1 was the sequential cleavage of the ethoxylate chain. 相似文献
107.
采用共沉淀法合成了三元类水滑石Mg_3Mn_xAl_(1-x)CO_3,通过高温煅烧得到其衍生氧化物Mg_3Mn_xAl_(1-x)O_m,再经浸渍负载Pt或BaO后制得新型NO_x存储/再还原(NSR)催化剂。XRD及SEM表征结果显示,当Mn与Al的摩尔比(Mn/Al)大于1时所制备的Mg_3Mn_xAl_(1-x)O_m有杂晶相出现且发生团聚,结合NO_x存储性能评价结果,确定最优Mn/Al为1。BaO负载不利于NO_x的存储,而当Pt负载量为1%(w)时NO_x存储性能最优,250℃条件下的存储量由负载前的0.52 mmol/g提升至0.61 mmol/g。CO_2与NO_x之间存在较强的竞争吸附。负载1%Pt催化剂的NSR性能评价结果表明,8个稀燃-富燃循环后NO_x的去除率为68%,表明催化剂的还原性能仍需加强。 相似文献
108.
选用正十六烷模拟润滑油,通过振荡平衡实验,考察了两种含氮脂肪酸型生物降解促进剂(甲基二乙醇胺油酸酯(MDEAO)和油酸二乙醇酰胺(ODEA))对水土体系中正十六烷吸附行为的影响。实验结果表明:正十六烷在水土体系中的有机质标化分配系数与土壤种类无关,与生物降解促进剂种类有关;土壤对正十六烷的吸附过程更符合Freundlich等温吸附模型;MDEAO的临界胶束浓度为2.0 mg/L,对土壤吸附正十六烷有一定的促进作用,ODEA的临界胶束浓度为0.7 mg/L,形成的胶束对正十六烷的增溶效果明显,促进了正十六烷在土壤中的解吸。 相似文献
109.
利用废气中本身含有的CO催化还原烟气中的NOx,可以实现以废治废。采用TiO2纳米管负载CeO2,制备CeO2/TiO2纳米管催化剂,并对其进行了SEM表征及影响因素实验。实验结果表明:在n(Ce)∶n(Ti)=3∶7、焙烧温度500 ℃、焙烧时间3 h时制备的CeO2/TiO2纳米管催化剂形貌较好,表面颗粒分布相对均匀;反应温度400~600 ℃时NO脱除率达98%;该催化剂具有一定的抗氧性能;当n(SO2)∶n(NO)=(1∶2)~(2∶1)时,NO脱除率仍然在95%以上。 相似文献
110.
采用共沉淀法合成了不同Ce与Ti摩尔比的CePO4-TiO2复合材料,利用XRD、TEM、NH3-TPD和H2-TPR技术对其物理化学性质进行了表征,并对其NH3-SCR活性进行了评价。实验结果表明:随着CePO4含量的增加,催化剂的活性提高;当Ce与Ti的摩尔比为8:2时催化剂的活性最高,230 ℃的NO转化率达到100%,且具有更广的温度窗口,优于纯CePO4。表征结果显示,CePO4与TiO2形成固溶体后,颗粒尺寸较为均匀,强酸位的数量增多,氧化还原性能提升,从而提高了催化剂的SCR反应活性,同时改善了其抗水抗硫性能。 相似文献