城市污水处理厂动态模拟研究

利用活性污泥1号模型。对采用A/O工艺的上海某城市污水处理厂的碳化、硝化、反硝化过程进行计算机动态模拟，结果表明，出水中的TCOD、TN与污水处理厂的出水基本吻合，说明利用活性污泥1号模型对城市污水处理厂进行模拟是可行的。并根据模拟结果建议该厂运行过程中应降低A段的溶解氧。     

Prenatal diagnosis of carbamoyl-phosphate synthetase deficiency by fetal liver biopsy

In a pregnancy at risk for carbamoyl-phosphate synthetase (CPS) deficiency, prenatal diagnosis was attempted by fetal liver biopsy, performed at 18 weeks of gestation. CPS activity was absent and the diagnosis was confirmed after termination of the pregnancy. The technique employed for fetal liver biopsy is described together with an evaluation of its possible role in prenatal diagnosis.     

N-苯基-2-萘胺和N-苯基-1-萘胺籍分离的大鼠肝细胞的代谢

具有致癌性的抗氧化剂N—苯基—2-萘胺(P2NA)和N—苯基—1-萘胺(PINA)在体外籍新鲜分离的大鼠肝细胞进行生物转化.肝细胞培育后的产物经TLC和HPLC分析表明,二者主要代谢产物为酚类.P2NA生成二个酚类化合物,经与标准样品作平行层析证实为6-羟基P2NA和4＇-羟基—P2NA,而P1NA仅生成一个酚类化合物.P2NA经去苯基反应的代谢产物2-萘胺未被检出.     

Study of control strategy and simulation in anoxic-oxic nitrogen removal process

The control strategy and simulation of external carbon addition were specially studied in an anoxic-oxic(A/O) process with low carbon: nitrogen(C/N) domestic wastewater. The control strategy aimed to adjust the flow rate of external carbon dosage to the anoxic zone, thus the concentration of nitrate plus nitrite(NOx^- -N) in the anoxic zone was kept closed to the set point. The relationship was studied between the NOx^- -N concentration in the anoxic zone(SNo) and the dosage of external carbon, and the results showed that the removal efficiency of the total nitrogen(TN) could not be largely improved by double dosage of carbon source when SNO reached about 2 mg/L. Through keeping SNO at the level of about 2 mg/L, the demand of effluent quality could be met and the carbon dosage could be optimized. Based on the Activated Sludge Model No. 1 (ASM No. 1), a simplified mathematical model of external carbon dosage was developed, Simulation results showed that PI controller and feed-forward PI controller both had good dynamic response and steady precision. And feed-forward PI controller had better control effects due to its consideration of influent disturbances.     

两种假单孢菌中二氯酚降解酶活性及其定域研究

对两种有降解二氯酚能力的假单孢菌Ｐｓｅｕｄｏｍｏｎａｓ ｓｐ．ＤＣＰ－１和Ｐｓｅｕｄｏｍｏｎａｓ ｓｐ．ＤＣＰ－２中二氯酚降解酶活性及定域进行了测定，结果表明该酶的活力与菌种、培养等因素有关，与诱导物的关系不显；酶主要定域在膜周及膜内；酶的活力在两种菌中的水平相当；酶的比活力在ＤＣＰ－１的膜周处表现出相当高的水平。     

单甲脒等农药的土壤薄层层析行为

用土壤薄层层析法研究单甲脒，单甲脒盐酸盐、灭幼脲和涕灭威等农药在不同土壤中的迁移行为，分别获得了这几种化合物的Ｒｆ值，它们分别为０．１４、０．１７，０．０８，０．７６，研究表明，单脒，单甲脒盐酸盐和灭幼脲不会污染地下水，而涕灭威则会对地下水污染构成严重的威胁。     

PV_1、B.fp在不同水样及温度条件下的灭活动力学

研究了脊髓灰质炎病毒 (Poliovirus1,PV1)、脆弱拟杆菌噬菌体 (bacteriophageinfectingBacteroidesfragilis,B .fp)在不同水样 (自来水、超纯水、闽江水、生活污水和滤膜过滤除菌生活污水 ) ,不同温度 (4℃、2 0℃、35℃ )条件下的灭活动力学 .结果显示 :温度是导致病毒灭活的重要因素 ,温度升高 ,病毒灭活速率加快 .同时 ,某些水质因子也明显影响病毒的灭活 .实验结果还表明 ,在任一灭活实验条件下 ,B .fp的灭活速率都比PV1低 ,表明B .fp是一个更合适的用于指示水体病毒污染程度与灭活效率的指示生物 .图 4表 2参 2 1     

尿中1-羟基芘的同步荧光测定法

本文报告1-羟基芘的荧光光谱在碱性溶液中的红移现象,研究了在1mol/l NaOH溶液中的同步荧光光谱,得出最适△λ为35nm.以此为基础建立了尿中1-羟基芘的同步荧光测定法,回收率80%,精密度8.0%,检测下限0.05ng/ml.     

应用灰色系统理论预测土壤酸化趋势

本文以各组分组成的土壤酸中和容量动态变化作为指标,用灰色系统控制理论对酸雨引起南方土壤的酸化趋势进行定量的预测分析。     

Large outdoor chamber experiments and computer simulations: (I) Secondary organic aerosol formation from the oxidation of a mixture of d-limonene and α-pinene

This work merges kinetic models for α-pinene and d-limonene which were individually developed to predict secondary organic aerosol (SOA) formation from these compounds. Three major changes in the d-limonene and α-pinene combined mechanism were made. First, radical–radical reactions were integrated so that radicals formed from both individual mechanisms all reacted with each other. Second, all SOA model species from both compounds were used to calculate semi-volatile partitioning for new semi-volatiles formed in the gas phase. Third particle phase reactions for particle phase α-pinene and d-limonene aldehydes, carboxylic acids, etc. were integrated. Experiments with mixtures of α-pinene and d-limonene, nitric oxide (NO), nitrogen dioxide (NO₂), and diurnal natural sunlight were carried out in a dual 270 m³ outdoor Teflon film chamber located in Pittsboro, NC. The model closely simulated the behavior and timing for α-pinene, d-limonene, NO, NO₂, O₃ and SOA. Model sensitivities were tested with respect to effects of d-limonene/α-pinene ratios, initial hydrocarbon to NO_x (HC₀/NO_x) ratios, temperature, and light intensity. The results showed that SOA yield (Y_SOA) was very sensitive to initial d-limonene/α-pinene ratio and temperature. The model was also used to simulate remote atmospheric SOA conditions that hypothetically could result from diurnal emissions of α-pinene, d-limonene and NO_x. We observed that the volatility of the simulated SOA material on the aging aerosol decreased with time, and this was consistent with chamber observations. Of additional importance was that our simulation did not show a loss of SOA during the daytime and this was consistent with observed measurements.