唐山市空气中SO2与TSP污染状况分析

分析了唐山市从1988年至1992年大气中SO2和TSP的污染状况和变化规律，取得对该市环境管理的科学依据。     

Application of CFD Methods for Modelling in Air Pollution Problems: Possibilities and Gaps

Different urban air pollution problems deal with complex structure of air flows and turbulence. For such problems the Computer Fluid Dynamics (CFD) methods become widely used. However, this approach despite a number of advantages has some problems. Experience of use of CFD tools for development of models and suggestions of their applications for a local scale air pollution over a complex terrain and stable stratification are discussed in this paper, including: Topography and complex geometry: choose of the co-ordinate system and computer grid; Turbulence closure for air pollution modelling: modified k- model for stable stratified ABL; Boundary conditions for vertical profiles of velocity for stable-stratified atmosphere; Effects of the radiation and thermal budget of inclined surfaces to dispersion of pollutants; Artificial sources of air dynamics and circulation.Some examples of CFD applications for air pollution modelling for a flat terrain, mountainous area, mining open cast and indoor ventilation are discussed. Modified k- model for stably-stratified ABL is suggested. Due to the isotropic character of the k- model a combination of it in vertical with the sub-grid turbulence closure in horizontal can be more suitable for ABL. An effective scheme of boundary conditions for velocity profiles, based on the developed similarity theory for stable-stratified ABL, is suggested. Alongside with the common studies of atmospheric dispersion, the CFD methods have also demonstrated a good potential for studying anthropogenic and artificial-ventilation sources of air dynamic and circulation in local-scale processes of air pollution.     

Geostatistical Uncertainty Modelling for the Environmental Hazard Assessment During Single Erosive Rainstorm Events

This paper presents an environmental hazard assessment to account the impacts of single rainstorm variability on river-torrential landscape identified as potentially vulnerable mainly to erosional soil degradation processes. An algorithm for the characterisation of this impact, called Erosive Hazard Index (EHI), is developed with a less expensive methodology. In EHI modelling, we assume that the river-torrential system has adapted to the natural hydrological regime, and a sudden fluctuation in this regime, especially those exceeding thresholds for an acceptable range of flexibility, may have disastrous consequences for the mountain environment. The hazard analysis links key rainstorm energy variables expressed as a single-storm erosion index (EI_sto), with impact thresholds identified using an intensity pattern model. Afterwards, the conditional probabilities of exceeding these thresholds are spatially assessed using non-parametric geostatistical techinques, known as indicator kriging. The approach was applied to a test site in river-torrential landscape of the Southern Italy (Benevento province) for 13 November 1997 rainstorm event.     

基于N，N─二甲基苯胺与NO_2~－─对氨基苯磺酸重氮盐的偶联反应示波极谱法测定NO_2~－

报道了利用Ｎ，Ｎ─二甲基苯胺为偶联试剂的Ｃｒｉｅｓｓ反应以示波极谱法测定ＮＯ_２~－的测试方法。在拟定的实验条件下，ＮＯ_２~－在４．０×１０~－３～４．８×１０~－１μｇ／ｍｌ范围内与极谱波波高呈良好的线性关系。环境水测定的相对标准偏差小于ｌ％，回收率在９７％～１０１％之间。     

我国内陆流域各类水体中天然放射性核素浓度

1985年～1989年由新疆、甘肃、青海、西藏、内蒙古、陕西、宁夏等省、自治区环境监测站(研究所)对内陆流域各类水体中U、Th、~(226)Ra、~(40)K浓度进行调查,由调查的29条内陆河、23个湖泊、15座水库、55处井泉和34个自来水的统计结果表明,流域内各水体中U和~(40)K浓度的平均值与同期调查的黄河水系同类水体的浓度相近,明显高于长江水系,与全国同类水体相比亦属偏高。Th和~(226)Ra的平均浓度与全国同类水体的浓度相近,甘、新内陆区浓度较低。调查发现,一些咸水湖、井水和自来水中U、~(226)Ra,或~(40)K浓度异常偏高。     

Fractionation of Cu, Pb and Zn in certified reference soils SRM 2710 and SRM 2711 using the optimized BCR sequential extraction procedure

Sequential extraction of metals from solid media is a common analytical tool used in environmental and exploration geochemistry. A number of procedures exist, but without harmonization and standardization, meaningful comparisons are tenuous without baseline data. A newly developed, standardized sequential extraction procedure (optimized BCR) was applied to two contaminated certified reference soils from Montana, US (SRM 2710 and SRM 2711) for Cu, Pb and Zn. Four operationally defined fractions were isolated, acid extractable, reducible, oxidizable, and residual (by aqua regia). Fraction-specific concentrations, percentages and recoveries for Cu, Pb and Zn were used to explore differences between the optimized BCR procedure and three other sequential extraction schemes with published data for SRM 2710 and 2711 (i.e. Tessier scheme, Geological Survey of Canada scheme and the original BCR scheme). Results indicate significant differences between the four schemes, even for schemes that are closely associated (i.e. the original and optimized BCR schemes). Order-of-magnitude fraction-specific concentration differences were observed, especially for Pb in the reducible fraction. Differences between schemes are worrisome because trends varied between metals, between fractions and between reference soils. These data reinforce the need for increased adoption of standardized sequential extraction procedures and further examination of different solid media.     

上海地区二氧化硫浓度和风速的统计关系

应用上海市1986年6月至1987年5月间5个自动监测站的全年每日逐时SO_2浓度平均值和同步的风速平均值资料,按季进行比较、归纳,得到风速—SO_2浓度的诊断判据,并利用1984年全年的相应资料进行验证,准确率达85％;得到了各季浓度—风速的回归方程,和浓度—风速、温差的二元回归方程、复相关系数。     

Kinetics of photoelectrocatalytic degradation of humic acid using B_2O_3·TiO_2/Ti photoelectrode

IntroductionEightypercentoforganicsubstancesinthesourcewaterisfromcrudehumicacidthatisacrudeorganiccompoundcreatedbyrottinganddecomposinginnaturalcycle ,thehighercontentofhumicacidis ,theworsequalityofthewateris,notonlycanitcausechrominance,offensiveodor,…     

分光光度法测定雨水中微量过氧化氢的研究

本文提出了以钛（ＩＶ） 过氧化氢 ２ （３，５ 二溴 ２ 吡啶偶氮） ５ 二乙氨基苯酚（３，５ ｄｉＢｒ ＰＡＤＡＰ）三元配合物体系光度测定雨水中微量过氧化氢的方法，该方法简便，灵敏度和选择性较高，所得结果令人满意     

多环芳烃的几种理化参数与LC_(50)的相关性研究

对多环芳烃(PAHS)4种理化参数(K;W、Sw。X Vv。)与 LCO的相关关系进行了研究,建立了 4种一元线性回归方程。结果表明,4种参数的相关系数分别为:0.刀66、08083、09488、0.9570,经r检验,后两种属高度显著相关.用所建立的一元线性回归方程对7种PAHS的LC。进行估算,估算值与实测值相比,平均相对误差分别为58.84％、32.23％、1761％、198％,用l和V＊.H对LClj进行估算的估算精度也较高。经比较,提出用(。估算P＊比对麦穗鱼＊CO的新方法。