抑制薇甘菊生长的日本菟丝子化感物质研究

采用制备型高效液相色谱、重结晶等方法从有害植物日本菟丝子（Cuscuta japonica Choisy）的水浸液有机萃取物中分离出能显著抑制薇甘菊（Mikania micrantha H.B.K.）种子萌发的化感物质,并采用核磁共振（1HNMR、13CNMR）法、质谱（MS）法等对其结构进行分析和鉴定。结果表明：能显著抑制薇甘菊种子萌发的日本菟丝子化感物质为桂皮酸（cinnamicacid）和3-苯基丙酸（3-phenylpropanoic acid）。这2种化合物在菟丝子属的植物中属首次分离鉴定。这2种化感物质具有开发为生物源农药（如除草剂）的潜力。研究结果为入侵植物薇甘菊的防治提供了参考依据,也为日本菟丝子的开发利用开辟了一条新途径。     

土壤环境中具有Keggin结构的Al13草酸盐胶体合成及其表征

采用XRD,FTIR和MAS27 Al NMR方法表征从Al13溶液中合成的草酸盐胶体.结果表明:胶体具有明显的XRD衍射峰,有别于常见的Al系及其草酸盐沉淀;位于810cm-1处络合物中Al-O伸缩振动证明胶体是由Al13和草酸根直接络合形成;红外光谱中位于725cm-1处的(Al-O)Td键和固体核磁共振波谱中位于约61ppm处的Al(O)4特征峰共同证明胶体具有特殊的Keggin结构,高pH(=7.8)环境下Al13草酸盐胶体仍能保持Keggin结构;经过化学分析,该草酸盐胶体化学式为AlO4Al12(OH)24(H2O)12(C2O4)7/2.     

我国《国民经济和社会发展第十三个五年规划纲要》 对安全生产战略影响量化分析

安全生产与经济社会发展密切相关,历年国家五年规划纲要所明确的一系列经济社会发展体制机制改革和政策措施实施,都直接或间接影响着安全发展进程与成效。在对我国《“十三五”规划纲要》中283项相关事项梳理的基础上,坚持政策评估和风险评价相结合的原则,采用定性和定量相结合的方法,邀请专家学者从机遇、挑战、积极影响、消极影响4个维度,分重大、较大、一般3个层级对相关事项进行逐项量化评估。根据评估结果和量化计算模型,就《“十三五”规划纲要》对安全生产可能产生的整体战略影响进行了深入分析,并与《“十二五”规划纲要》影响进行比对,给出了有关宏观决策建议。     

Soil organic matter chemistry. Part 1. Characterization of several humic preparations by proton and carbon‐13 nuclear magnetic resonance spectroscopy

Both laboratory and commercial preparations of humic substances (HSs) such as fulvic acids and humic acids along with HC1‐HF preparation of Manitoba peat soil organic matter were characterized using Fourier Transformation (FT) proton (¹H) and carbon‐13 (¹³C) nuclear magnetic resonance (NMR) spectroscopy. All the samples were dissolved in a solution of 0.4 N NaOD in D₂O. In the case of ‘H‐NMR spectroscopy, all the investigated humic samples displayed resonance absorption peaks in the region of 1–4 ppm indicating the likely presence of aliphatic protons in the preparations. However, with the exception of one fulvic acid preparation (extracted from Manitoba Carrol clay‐loam soil with 0.5 N NaOH), ¹H‐NMR spectra of all other samples provided evidence for strong aromatic character. The aliphatic and aromatic characteristics of such samples of HSs were further confirmed with the aid of ¹³C‐NMR spectra.     

聚合氯化铝Al13模型化合物的量子化学计算

采用MNDO方法对聚合氯化铝(PAC)中的Al13模型化合物进行了量子化学计算.结果表明:作为电子给体化学反应的活性点主要是羟基氧原子或羟基桥键氧原子,作为电子受体化学反应的活性点主要是六配位的Al.羟铝比(OH/Al)大的模型物, 铝氧四面体中Al所带正电荷明显减少,表明OH/Al比大时将有更多的电子流向Al(Ⅲ).与此同时,羟桥Al-O的键级会逐渐减小,有利于PAC的水解.水解过程实际上是通过OH-的HOMO和被水解形态组分的LUMO相互作用使Al-O(H2O)键断裂形成Al-O(OH)键的过程.     

Al(Ⅲ) speciation distribution and transformation in high concentration PACl solutions

Effects of Al(Ⅲ) concentration and pH on the speciation of Al(Ⅲ) in polyaluminum chloride (PACl) solutions especially on the Al13 fraction were investigated. A series of PACl samples were prepared over the range of Al(Ⅲ) concentration from 0.01 to 2.0 mol/L with the B (OH/Al ratio) value from 1.0 to 2.5 by forced hydrolysis of AlCl3. The samples were characterized by ferron assay,pH and 27Al NMR. It was shown that the Al(Ⅲ) concentration had a dramatic effect on the hydrolysis processes and the species distribution of PACl was in relate to the decrease of pH. The fraction of Al species, Alb (or Al13) decreased and Alc increased with increase of total Al(Ⅲ) concentration. Under the condition of Al(Ⅲ) 2.0 mol/L, B = 2.5, the pH value was 2.73 and no Al13 could be detected. During diluting and aging, the species distribution evolved. The Al13 could then be detected again and the amounts increased with time. If the diluted samples were concentrated by freeze dry at -35℃ or heating at 80℃, the pH value and Al13 content would decrease with the increased concentration. It demonstrated that the key factor for formation of Al13 in concentrated PACl was pH value.     

Isotopic Composition as a Tool for Assessment of Origin and Dynamic of Organic Matter in Tropical Freshwater

The isotopic composition (¹³C and ¹⁵N) and C:N ratio of sediment and particulate were investigated to assess the origin and dynamic of the organic matter in two river basins located in the Parana State, Brazil. The main sources of organic matter, plants, litter and soil, were analyzed in the study. This study was carried out during the dry and wet seasons. Although organic matter contribution for the particulate material has been mixed, the main contribution in the two seasons for both rivers was autochthonous characterized by δ¹³C and C:N ratio values ranging from −31.0 to −21.8‰ and from 5.1 to 11.4, respectively. The soil with δ¹³C values ranging from −25.9 to −20.6‰, and C:N ratio from 10.2 to 15.8, was the main carbon source for the river sediment for the two tributaries in the wet and dry seasons. The sediment δ¹⁵N values for both the rivers in the wet season showed an ¹⁵N enrichment trend in most of studied sites when compared to the dry season values, suggesting major input of nutrients as dissolved organic nitrogen and sewage nitrate. In the dry season, ¹⁴N enriched compounds, could have been used by phytoplankton, causing ¹⁵N enrichment. The isotope and C:N ratio data clearly showed that the agricultural activity has been influencing the origin and dynamic of organic matter in the two rivers, with potential biochemical consequences for the lower basin of the major Tibagi river.     

Interaction of PACls with sulfate

IntroductionPolyaluminumchloride (PACl)asamainkindofinorganicpolymerflocculantsisanewhighereffectivewaterandwastewatertreatmentreagent.Basedonthetraditionallow molecularaluminum ,ithasbeendevelopedworldwidesincethe 196 0s(Tang,1994 ;1990 ;1987) .PAClistheintermediateproductofthehydrolysis polymerization ageingprocessofAl(III)undersuitableconditions.Atpresent,itisgenerallyknownthattherearemanypossiblespeciesexistintheAl(III)solution ,suchasmonomers,oligomers,Al13 [AlO4Al12 (OH) 2 4(H2 …     

“十三五”中国城镇化六大转型与健康发展

新型城镇化是中国最大的潜在内需,是深化供给侧结构性改革的突破口,是引领"十三五"时期经济发展的引擎。本文在对中国城镇化深入分析的基础上,发现当前中国城镇化面临着以人为本不够、城镇化效率不高、绿色发展不够、城镇规模结构不平衡、市场化不足、协调发展不够六大问题。结合"十三五"规划纲要提出的"创新、协调、绿色、开放、共享"的新发展理念,文章认为"十三五"期间城镇化要实现健康发展,需要推动六大转型:(1)通过采取差别化落户政策和居住证制度并行的市民化二维路径,实现从以地为中心的城镇化转向以人为本的城镇化;(2)通过土地价格市场化、提升人力资本、避免重复投资和过度投资来提高土地、劳动、资本的使用效率,实现从低效利用要素的城镇化转向高效率和高质量的城镇化;(3)通过转变经济发展方式和提升城市管理水平,实现从"高耗能、高排放、高污染"的城镇化转向人口、资源、环境可持续发展的绿色城镇化;(4)通过依托城市群这一平台,实现从规模结构不合理、大中小城市不协调的城镇化转向城市群一体化高效发展、大中小城市协调发展、规模效应和集聚效应充分发挥的城镇化;(5)通过转变政府职能,发挥市场机制在资源配置中的决定性作用,实现从"政府主导"的城镇化转向"市场主导、政府引导"、民间资本作用充分发挥的城镇化;(6)通过推动信息化和工业化深度融合、工业化和城镇化良性互动、城镇化和农业现代化相互协调,实现从城镇化与工业化、信息化、农业现代化发展不协调、产城脱节转向"四化同步"、产城融合的发展方式。     

从《“十三五”生态环境保护规划》看环境监管的转变

"十三五"时期是以环境质量为核心的生态文明建设的重要时期,完善环境监管制度转变是推进生态文明制度体系建设的重要内容。本文研究提出了加快实现环境监管的三个重要转变:环境管理向环境治理的转变,环境监管能力向环境治理能力现代化的转变和环境监管方式向环境综合监管的转变。另外,本文还对三个转变如何落地提出了建议。