全文获取类型
收费全文 | 3002篇 |
免费 | 726篇 |
国内免费 | 1302篇 |
专业分类
安全科学 | 244篇 |
废物处理 | 128篇 |
环保管理 | 157篇 |
综合类 | 2247篇 |
基础理论 | 1503篇 |
污染及防治 | 539篇 |
评价与监测 | 144篇 |
社会与环境 | 31篇 |
灾害及防治 | 37篇 |
出版年
2024年 | 13篇 |
2023年 | 76篇 |
2022年 | 118篇 |
2021年 | 162篇 |
2020年 | 125篇 |
2019年 | 116篇 |
2018年 | 218篇 |
2017年 | 258篇 |
2016年 | 280篇 |
2015年 | 308篇 |
2014年 | 300篇 |
2013年 | 377篇 |
2012年 | 370篇 |
2011年 | 310篇 |
2010年 | 307篇 |
2009年 | 275篇 |
2008年 | 215篇 |
2007年 | 187篇 |
2006年 | 181篇 |
2005年 | 133篇 |
2004年 | 98篇 |
2003年 | 85篇 |
2002年 | 75篇 |
2001年 | 61篇 |
2000年 | 89篇 |
1999年 | 40篇 |
1998年 | 34篇 |
1997年 | 35篇 |
1996年 | 20篇 |
1995年 | 33篇 |
1994年 | 23篇 |
1993年 | 25篇 |
1992年 | 18篇 |
1991年 | 6篇 |
1990年 | 8篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1985年 | 10篇 |
1984年 | 8篇 |
1983年 | 8篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有5030条查询结果,搜索用时 843 毫秒
601.
Breakthrough curves, on a semi-log scale, from tests in porous media with block-input of viruses, bacteria, protozoa and colloidal particles often exhibit a typical skewness: a rather slowly rising limb and a smooth transition of a declining limb to a very long tail. One-site kinetic models fail to fit the rising and declining limbs together with the tail satisfactorily. Inclusion of an equilibrium adsorption site does not seem to improve simulation results. This was encountered in the simulation of breakthrough curves from a recent field study on the removal of bacteriophages MS2 and PRD1 by passage through dune sand. In the present study, results of laboratory experiments for the study of this issue are presented. Breakthrough curves of salt and bacteriophages MS2, PRDI, and phiX174 in 1 D column experiments have been measured. One- and two-site kinetic models have been applied to fit and predict breakthrough curves from column experiments. The two-site model fitted all breakthrough curves very satisfactorily, accounting for the skewness of the rising limb as well as for the smooth transition of the declining limb to the tail of the breakthrough curve. The one-site model does not follow the curvature of the breakthrough tail, leading to an overestimation of the inactivation rate coefficient for attached viruses. Interaction with kinetic site 1 is characterized by relatively fast attachment and slow detachment, whereas attachment to and detachment from kinetic site 2 is fast. Inactivation of viruses and interaction with kinetic site 2 provide only a minor contribution to removal. Virus removal is mainly determined by the attachment to site 1. Bacteriophage phiX174 attached more than MS2 and PRD1, which can be explained by the greater electrostatic repulsion that MS2 and PRD1 experience compared to the less negatively charged phiX174. 相似文献
602.
Takayuki Kameda Koji Inazu Yoshiharu Hisamatsu Norimichi Takenaka Hiroshi Bandow 《Atmospheric environment (Oxford, England : 1994)》2006,40(40):7742-7751
The formation of mutagenic nitro-polycyclic aromatic hydrocarbons (NPAHs) 1- and 2-nitrotriphenylene (1- and 2-NTP) via gas-phase OH or NO3 radical-initiated reactions of triphenylene was demonstrated for the first time using a flow reaction system. In contrast with the results of conventional electrophilic nitration, 2-NTP was formed in larger yield than 1-NTP, but this is consistent with the mechanism proposed for gas-phase radical-initiated nitration of PAH. In diesel exhaust particle (DEP) samples, both 1- and 2-NTP were identified and their concentrations determined, as well as 1-nitropyrene (1-NP), which is a representative combustion-derived NPAH: the mean concentrations of 1-NTP, 2-NTP, and 1-NP were 4.7, 1.9, and 32 pmol mgDEP–1, respectively. The mean 2-NTP/1-NTP, 1-NTP/1-NP, and 2-NTP/1-NP ratios in samples of airborne particles collected in a residential area in Osaka, Japan, were>1.55,<0.25, and 0.37, respectively; these values are much higher than those of the DEP samples. This finding indicates that there is another source for airborne NTPs, especially 2-NTP, apart from diesel exhaust. These results strongly suggest that airborne NTPs originate from atmospheric processes such as radical-initiated reactions of triphenylene, and this has a significant influence on the atmospheric occurrence of NTPs. 相似文献
603.
604.
新型复合球填料为沸石与悬浮球填料的有机组合体,密度约为0.92~0.97g/cm3,比表面积为711~1185m2/m3,表面粗糙,物化性能稳定.在曝气量为20∶1,停留时间为6 h时,装有新型复合球填料的反应柱挂膜容易,成膜时间短,膜不易脱落,且生物相丰富.膜成熟时对生活污水中的氨氮和COD都有很好的去除效果,出水氨氮浓度≤2 mg/L,去除率≥93%;出水COD浓度≤22 mg/L,去除率≥80%.新型复合球反应柱在稳定状态处理低浓度的二级出水时,出水氨氮浓度≤2 mg/L,去除率≥89%,出水COD浓度为10~36 mg/L,去除率为48%~81%.出水水质符合GB50335-2002标准. 相似文献
605.
应用由城市污水处理厂序批式间歇反应器(SBR)中筛选得到的4株特殊氨氧化菌,分别在SBR和有回流的生物膜与A/O工艺耦合体系培养中,考察其降解低碳高氨氮废水的功能。结果表明,自养硝化与异养氨氧化菌的混合菌群较单一自养硝化菌株降解氨氮速率快;在生物膜与A/O工艺耦合系统中,自养硝化与异养氨氧化菌协同代谢加速氨氮氧化脱除,氨氮脱除速率远比SBR系统快。对生物膜与A/O工艺耦合系统中氨氮脱除动力学进行了研究,模拟了NH4^+、NO2^-;质量浓度与氨氮脱除比速率之间的关系,模型得到了较好的验证。 相似文献
606.
607.
利用Ce-Fe/Al2O3为催化剂的非均相光Fenton体系降解阳离子红GTL模拟废水,考察了H2O2浓度、催化剂用量、初始pH值及不同工艺过程对降解效果的影响,通过紫外-可见漫反射光谱、红外光谱、XPS手段研究铁在反应中的价态变化。结果表明,在11 W低压汞灯照射下,非均相光Fenton体系能够有效地降解结构稳定的阳离子红GTL,在pH 6,反应温度20℃,时间90 min,Ce-Fe/Al2O3 2 g/L,H2O2浓度340 mg/L,含50 mg/L阳离子红GTL模拟废水TOC去除率为92.40%;光Fenton反应中Fe(Ⅲ)转化为Fe(Ⅱ)。 相似文献
608.
609.
The toxicity of seawater dispersions of a chemical dispersant to two marine crustaceans was investigated in the presence and absence of various quantities of a non-toxic mineral oil. From the results and a physical-chemical partitioning analysis, a limiting value of the oil-water partition coefficient of the toxic compounds is deduced suggesting that essentially all of the toxic compounds in the dispersant will partition into solution in water following dispersant application to an oil spill. This conclusion simplifies interpretation and prediction of the toxic effects of a dispersed oil spill.The combined bioassay-partitioning procedure may have applications to the study of the toxicity of other complex mixtures such as industrial effluents. 相似文献
610.