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151.
152.
Atsuyoshi Nakayama Norioki Kawasaki Ioannis Arvanitoyannis Seiichi Aiba Noboru Yamamoto 《Journal of Polymers and the Environment》1996,4(3):205-211
Biodegradable polyesters were synthesized by ring-opening copolymerization of -butyrolactone (BL) and its derivatives withl-lactide (LLA). Although tetraphenyl tin was the main catalyst used, other organometallic catalysts were used as well.1H and13C NMR spectra showed that poly(BL-co-LLA)s were statistical and that their number-average molecular weights were as high as 7×104. The maximum BL content obtained from copolymerization BL/LLA was around 17%. TheT
m andT
g values of the copolymers showed a gradual depression with an increase in BL content. NoT
m was obtained for the copolymers containing more than 13 mol% BL. The biodegradability of the copolyesters was evaluated by enzymatic hydrolysis and nonenzymatic hydrolysis tests. The enzymatic hydrolysis was carried out at 37°C for 24 h using lipases fromRhizopus arrhizus andR. delemar. Hydrolyses by both lipases showed that an increase in BL content of the copolymer resulted in enhanced biodegradability. Nonenzymatic accelerated hydrolysis of copolymers at 70°C was found to increase proportionally to their exposure time. The hydrolysis rate of these copolymers was considerably faster than that of PLLA. The higher hydrolyzability was recorded for the BL-rich copolymers. The copolymerization of -methyl--butyrolactone (MBL) or -ethyl--butyrolactone (EBL) with LLA resulted in relatively LA-rich copolymers. 相似文献
153.
154.
J. J. Jesudason R. H. Marchessault T. Saito 《Journal of Polymers and the Environment》1993,1(2):89-98
The synthetic analogue of a bacterially produced polyester, poly(-hydroxybutyrate) (PHB) was synthesized from racemic -butyrolactone using anin situ trimethyl aluminum-water catalyst. The polymer was fractionated into samples differing in molecular weight and isotactic diad content. The latter was closely related to degree of crystallinity. The biodegradation of these fractions were examined by monitoring mass loss over time in the presence of anAlcaligenes faecalis T1 extracellular bacterial poly(-hydroxybutyrate) depolymerase. The fraction with high isotactic diad tacticity content showed little or no degradation over a 50 hour incubation period, whereas the fraction of intermediate isotactic diad content degraded in a continuous steady fashion at a rate that was less than that for bacterial PHB. The low isotactic diad fraction underwent a rapid initial degradation, followed by no further mass loss. The presence of stereoblocks in the polymer structure of the various fractions was an influence on the degree of susceptibility towards degradation and is related to sample crystallinity. 相似文献
155.
儿童呼吸健康与颗粒物中元素浓度的关联分析 总被引:3,自引:0,他引:3
通过两步回归法研究了儿童呼吸健康与PM2.6和PM2.5-10中元素浓度的统计关联,发现了哮喘、支气管炎、气喘,慢性咳嗽和慢性咳痰与污染元素,土壤元素的某些关联性,比较了粗、细颗粒物中元素与呼吸健康反应之间的异同,提出了解释土壤元素与健康反应之间正向关联性的“土壤粒子团”假设。 相似文献
156.
Anne Ingeborg Myhr Terje Traavik 《Journal of Agricultural and Environmental Ethics》2003,16(3):227-247
Risk governance of GM plants and GMfood products is presently subject to heatedscientific and public controversies. Scientistsand representatives of the biotechnologyindustry have dominated debates concerningsafety issues. The public is suspicious withregard to the motives of scientists, companies,and political institutions involved. Thedilemmas posed are nested, embracing valuequestions, scientific uncertainty, andcontextual issues. The obvious lack of data andinsufficient information concerning ecologicaleffects call for application of thePrecautionary Principle (PP). There are,however, divergent opinions among scientistsabout the relevance of putative hazards,definition of potential ``adverse effects,' andwhether actions should be taken to preventharm. The reliance on the concept ofsubstantial equivalence in safety evaluation ofGM food is equally controversial. Consequently,value assumptions embedded in a scientificframework may be a barrier for employment ofthe PP. One of our major conclusions is thatprecautionary GMP usage requires riskassessment criteria yet undeveloped, as well asbroader and more long-term conceptions of risk,uncertainty, and ignorance. Conflicts ofinterest and public participation are otherissues that need to be taken intoconsideration. GMP governance regimes that arejustifiable from a precautionary and ethicalpoint of view must transcend traditionalscientific boundaries to include alternativescientific perspectives as well as publicinvolvement. 相似文献
157.
移动床生物膜反应器充氧能力的试验研究 总被引:5,自引:0,他引:5
对移动床生物膜反应器的充氧能力进行了试验研究,结果表明:反应器充氧能力在添加填料比无填料时大;在悬浮载体能够均匀流化的填充率范围内,反应器充氧能力随着填充率的增大而增大;当填充率大于可以均匀流化的最大填充率时,反应器的充氧能力略有下降。 相似文献
158.
Lakes caused by coal mining processes are characterized by low pH, low nutrient status, and high concentrations of Fe(II) and sulfate due to the oxidation of pyrite in the surrounding mine tailings. Fe(III) produced during Fe(II) oxidation precipitates to the anoxic acidic sediment, where the microbial reduction of Fe(III) is the dominant electron-accepting process for the oxidation of organic matter, apparently mediated by acidophilic Acidiphilium species. Those bacteria can reduce a great variety of Fe(III)-(hydr)oxides and reduce Fe(III) and oxygen simultaneously which might be due to the small differences in the redox potentials under low pH conditions. Due to the absence of sulfide, Fe(II) formed in the upper 6 cm of the sediment diffuses to oxic zones in the water layer where itcan be reoxidized by Acidithiobacillus species. Thus, acidic conditions are stabilized by the cycling of iron which inhibits fermentative and sulfate-reducing activities. With increasing sediment depth, the amount of reactive iron decrease, the pH increases above 5, and fermentative and as yet unknown Fe(III)-reducing bacteria are also involved in the reduction of Fe(III). Sulfate is reduced apparently by the activity of spore-forming sulfate reducers including new species of Desulfosporosinus that have their pH optimum similar to in situconditions and are not capable of growth at pH 7. However, generation of alkalinity via sulfate reduction is reduced by the anaerobic reoxidation of sulfide back to sulfate. Thus, the microbial cycling of iron at the oxic-anoxic interface and the anaerobic cycling of sulfur maintains environmental conditions appropriate for acidophilic Fe(III)-reducing and acid-tolerant sulfate-reducing microbial communities. 相似文献
159.
城市垃圾甲烷气体排放及减排对策 总被引:6,自引:0,他引:6
本文讲述了城市垃圾的现状以及影响垃圾甲烷排放的各种因素,并根据IPCCGuidelines(1995)提供的方法对1990~2010年江浙沪地区城市垃圾甲烷排放量的变化趋势进行了预测统计计算,1990年江浙沪地区城市垃圾甲烷排放量为7123万吨,2010年预测的甲烷排放量为26676万吨,本文就垃圾中甲烷的排放提出了切实可行的减排方案。 相似文献
160.
根据扁矩形消声通道二维消声理论替代一维理论导出的消声系数Φ(α),研究了障板消声结构的Φ(α)计算机程序和消声量与障板几何尺寸的关系 相似文献