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Yuan Ma Shan Zhai Shi Yun Mao Shi Lei Sun Ying Wang Zhong Hua Liu 《Journal of environmental science and health. Part. B》2013,48(9):661-670
A new imidacloprid (IMI) degrading bacterium Z-9 (deposited number CGMCC 6648) was isolated and identified as Pseudoxanthomonas indica by 16S rRNA gene analysis. Two metabolites were identified as olefin and 5-hydroxy IMI by liquid chromatography-mass spectrometry and nuclear magnetic resonance analysis. P. indica CGMCC 6648 degraded 70.1% of IMI (1.22 mmol L?1) and formed 0.93 mmol L?1 5-hydroxy IMI and 0.05 mmol L?1 olefin IMI in 6 days and in the presence of 100 mmol L?1 glucose. The half-life of IMI degradation was 3.6 days. P. indica CGMCC 6648 transforms IMI via a co-metabolism mechanism and different carbohydrates have significant effects on 5-hydroxy IMI formation, whereas different organic acids have substantial effects on olefin IMI production. Lactose is the best co-substrate for IMI degradation and 5-hydroxy IMI formation with 0.77 mmol L?1 degraded and 0.67 mmol L?1 formed in 48 h, respectively. Pyruvate is the best co-substrate for olefin IMI formation with 0.17 mmol L?1 produced in 96 h for all carbon sources tested. Pyruvate significantly stimulates the conversion of 5-hydroxy IMI to olefin IMI, whereas glucose slightly inhibits this reaction. P. indica CGMCC 6648 rapidly degrades IMI and forms olefin IMI, which may enhance its potential for biodegradation of IMI and increase its insecticidal activity, which can decrease the IMI dosage required. 相似文献
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Prenatal diagnosis of 5p deletion syndrome, or cri du chat, following an abnormally low measurement of a screening of serum human chorionic gonadotrophin (hCG), is reported. Karyotyping following amniocentesis revealed a terminal deletion in the short arm of one chromosome 5. The pregnancy was electively terminated. 5p deletion syndrome has been described with abnormally high hCG levels and normal hCG levels. This is the first report of its association with abnormally low levels. The association between chromosomal abnormalities and hCG is discussed. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
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We present a case report on a fetus with multiple malformations, diagnosed by ultrasound at 20 weeks' gestation. From the combination of intrauterine growth retardation and limb abnormalities that were observed, the most likely diagnosis was considered to be Cornelia de Lange Syndrome (CdLS). Following counselling, the mother opted to terminate the pregnancy. Chromosome analysis of cultured amniotic fluid cells showed a karyotype of 46,XX,t(3;5)(q21;p13). Postmortem examination of the baby confirmed the presence of features consistent with a diagnosis of CdLS. This case provides a report of a definitive diagnosis of Cornelia de Lange Syndrome, suspected on the basis of ultrasound imaging and confirmed by amniocentesis findings. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
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由于能源化石类燃料中均包含不同含量的硫化物,随着人类对这些能源的不断利用,引发的环境污染等问题日趋严重。利用五羰基铁(Fe(CO)5)分解条件温和可控,产物无杂质,分解后的Fe0可以与硫原子原位键合等特点。文章尝试采用Fe(CO)5作为脱硫剂在温和条件下进行脱除正辛硫醇的研究。实验结果表明:随着压强(101~5 067 kPa)、Fe(CO)5加入量(50~250μL)、时间(1~6 h)和温度(0~180℃)的不同,Fe(CO)5脱硫效率具有明显差异,在此基础上得到最佳脱硫条件及最高脱除效率:常压、Fe(CO)5加入量200μL(1.4 mmol)、t=2h和T=140℃时,达到最高硫容3 450 mg/L。分别采用IR、XPS手段对脱硫反应机理进行了探索。IR结果表明:在1 084 cm-1处为硫氧峰,在797 cm-1归属为铁氧峰。XPS结果表明:167.8 eV处可能为S4+,711.6 eV处可能为Fe3+。因此,正辛硫醇脱除的可能机理为巯基断裂,并在空气中与氧结合,最终形成S4+,而Fe(CO)5的Fe经过脱硫之后,在空气中不稳定,最终被氧化成Fe3+。 相似文献