HP-5毛细管柱气相色谱法分离水中滴滴涕色谱条件研究

本试验利用HP-5毛细管柱,气相色谱法对水中滴滴涕几种衍生体的分离条件进行了研究和优化,找到了最佳仪器条件,为水中滴滴涕的检测提供了一定的试验参考。     

差压法测定水样中的BOD5

差压法（压力感测法）是测定BOD5的一种简单可靠的方法,OxiTop即是基于这一原理的BOD测量系统,经试验验证分析,该方法操作简单、结果准确,是目前测定BOD5较好的一种方法。     

Isolation of marine benzo[a]pyrene-degrading Ochrobactrum sp. BAP5 and proteins characterization

A bacterial strain BAP5 with a relatively high degradation ability of benzo[a]pyrene (BaP) was isolated from marine sediments of Xiamen Western Sea, China and identified as Ochrobactrum sp. according to 16S rRNA gene sequence as well as Biolog microbial identification system. Strain BAP5 could grow in mineral salt medium with 50 mg/L of BaP and degrade about 20% BaP after 30 d of incubation. Ochrobactrum sp. BAP5 was able to utilize other polycyclic aromatic hydrocarbons (PAHs) (such as phenanthrene, pyrene and fluoranthene) as the sole carbon source and energy source, suggesting its potential application in PAHs bioremediation. The profile of total soluble protein from Ochrobactrum sp. BAP5 was also investigated. Some over- and special-expressed proteins of strain BAP5 when incubated with the presence of BaP were detected by two-dimensional polyacrylamide gel electrophoresis, and found to be related with PAHs metabolism, DNA translation, and energy production based on peptide fingerprint analysis through matrix-assisted laser desorption/ionization-time of flight mass spectrometry.     

High-resolution modeling and evaluation of ozone air quality of Osaka using MM5-CMAQ system

High-resolution modeling approach is increasingly being considered as a necessary step for improving the monitoring and predictions of regional air quality. This is especially true for highly urbanized region with complex terrain and land-use. This study uses Community Multiscale Air Quality (CMAQ) model coupled with MM5 mesoscale model for a comprehensive analysis to assess the suitability of such high-resolution modeling system in predicting ozone air quality in the complex terrains of Osaka, Japan. The 1-km and 3-km grid domains were nested inside a 9-km domain and the domain with 1-km grid covered the Osaka region. High-resolution Grid Point Value-Mesoscale Model (GPV-MSM) data were used after suitable validation. The simulated ozone concentrations were validated and evaluated using statistical metrics using performance criteria set for ozone. Daily maxima of ozone were found better simulated by the 1-km grid domain than the coarser 9-km and 3-km domains, with the maximum improvement in the mean absolute gross error about 3 ppbv. In addition, 1-km grid results fared better than other grids at most of the observation stations that showed noticeable di erences in gross error as well as correlation. These results amply justify the use of the integrated high-resolution MM5-CMAQ modeling system in the highly urbanized region, such as the Osaka region, which has complex terrain and land-use.     

Multiple linear regression models of urban runoff pollutant load and event mean concentration considering rainfall variables

Rainfall is an important factor in estimating the event mean concentration (EMC) which is used to quantify the washed-off pollutant concentrations from non-point sources (NPSs). Pollutant loads could also be calculated using rainfall, catchment area and runoff coefficient. In this study, runoff quantity and quality data gathered from a 28-month monitoring conducted on the road and parking lot sites in Korea were evaluated using multiple linear regression (MLR) to develop equations for estimating pollutant loads and EMCs as a function of rainfall variables. The results revealed that total event rainfall and average rainfall intensity are possible predictors of pollutant loads. Overall, the models are indicators of the high uncertainties of NPSs; perhaps estimation of EMCs and loads could be accurately obtained by means of water quality sampling or a long term monitoring is needed to gather more data that can be used for the development of estimation models.     

发挥环境保护档案在突发性环境污染事件中的重要作用

环境保护档案是环境状况的历史记录,是环境保护成果及科技信息的载体。在环境形势十分严峻的今天,环境保护部门要充分发挥环保档案的信息潜能,变被动的、低档次、知识审查服务,为积极主动的、高层次、超前的知识配送服务,为政府及时处理突发性环境污染事件提供科学依据。     

海上溢油扩散图像处理的非线性方法研究

针对海上溢油应急处理问题,本文主要对溢油的初级行为--扩散进行探讨.提出了采用溢油扩散图像来预测溢油扩散未来发展趋势的3步非线性处理过程,即图像边缘检测、面积计算和面积预测,对这一过程中应采用的方法进行了分析与比较.并以奥里油在静止海水中扩散为范例,在MATLAB环境下,利用非线性方法对扩散图像进行边缘监测,通过对梯度算子阀值的调整来计算完整的油膜覆盖面积,并将其计算结果进行BP神经网络预测.结果表明:采用Roberts边缘算子可以得到很好的边缘检测结果,采用BP神经网络获得的面积预测结果与实验结果吻合程度较好.     

V2O5/CeO2催化剂用于低温NH3-SCR的性能研究

采用浸渍法制备了系列V2O5/CeO2催化剂,用于低温NH3选择性催化还原(NH3-SCR)NO.同时,考察了催化剂中V2O5负载量和煅烧温度对催化活性的影响,并运用SEM,BET和XRD物理化学技术对催化剂进行了表征.结果表明,V2O5/CeO2催化剂对模拟烟气中的NO转化呈现出较高的活性,但是V2O5负载量和催化剂的催化活性并不呈线性递增的关系.当V2O5负载量超过10%时,催化剂的催化活性开始下降.随着煅烧温度的升高,由于钒酸铈的生成,催化剂的催化活性下降.400℃为最佳煅烧温度.     

A methodology for assessment of long-term exposure to whole-body vibrations in vehicle drivers to propose preventive safety measures

Introduction: The appearance of musculoskeletal disorders (MDs) in professional drivers due to exposition to whole-body vibration (WBV) makes it relevant to assess this exposure. The European Directive 2002/44/EC has two methods to evaluate exposure to WBV (defined in ISO2631-1:2008). These methods evaluate the exposure associated with an 8-hour working day; however, MDs due to WBV could also be caused by accumulated exposure to vibrations over long term, and hence, the methods defined in the European directive may be limited in their ability to ensure the safety of workers exposed to WBV throughout their years of employment. Method: A detailed comparison and discussion of methods defined in the European Directive and the ISO2631-5:2018 was used as a starting point of the main results of this paper. On this basis, a new methodology for the management and organization of preventive measures is proposed to consider the assessment of ISO2631-5:2018 standard and the full working life of workers. Experimental data to assess exposure to WBV in heavy equipment vehicle (HEV) drivers under different road surface conditions and range of velocities were considered to illustrate the process of the proposed methodology. Results: The methods defined in the standards provide different assessments leading to a different possible consideration of safe operations when the risks associated with them may actually be high. The proposed methodology can be used with the aim of ensuring safety of workers throughout their working lives and providing an easy implementation of the calculations of ISO2631-5:2018 standard. Conclusions: A procedure to assess the health risk probability to which the HEV worker is exposed in terms of the exposure years and a different range of operational vehicle speeds is proposed and exemplified with a study case. Practical applications: This study provides a practical tool for the management of WBV exposure related to work-tasks in HEV drivers. Safety managers should consider the global exposition to WBV throughout their working life, and this research provides an easy tool to accomplish it.     

我国生态工业园区政策可持续性的动力机制

为了有效地推动工业园区的生态转型,相关的政策支持需要考虑时间的连续性及阶段性。本文以我国生态工业园区政策为例,运用事件序列分析方法,重构了政策长时期演化过程,剖析其序列规律,以此揭示促进我国生态工业园区政策可持续性的动力机制。结果表明：我国生态工业园区政策的演化路径经历了从单一机构到多部门合作治理的转变,从政策学习与实验型实施到实验型与行政规范化相结合的实施方式的转变。这些转变提升了政策实施初期的适应性与政策实施中后期的稳定性,从而提升了政策的生命力,促进了政策的可持续性与积极政策结果的实现。