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131.
Evaluating Controlling Factors to Ali/(Ca + Mg) Molar Ratio in Acidic Soil Water, Southern and Southwestern China: Multivariate Approach 总被引:2,自引:0,他引:2
Guo JH Zhang XS Vogt RD Xiao JS Zhao DW Xiang RJ Luo JH 《Environmental monitoring and assessment》2007,129(1-3):321-329
Ali/(Ca + Mg) molar ratio in soil water has been used as an indicator to the effects of acid deposition on terrestrial ecosystems.
However, the main factors controlling this ratio have not been well documented in southern and southwestern China. In this
study, we presented the variation in inorganic aluminum (Ali) and Ali/(Ca + Mg) molar ratio in different sites and soil horizons based on two to three years monitoring data, and evaluated the
main factors controlling Ali/(Ca + Mg) molar ratio using principle component analysis (PCA) and partial least square (PLS) regression. Monitoring data
showed although Ali/(Ca + Mg) molar ratios in most soil water were lower than assumed critical 1.0, higher molar ratios were found in some soil
water at TSP and LXH site. Besides acid loading, both soil properties and soil water chemistry affected the value of Ali/(Ca + Mg) molar ratio in soil water. Partial least square (PLS) indicated that they had different relative importance in
different soil horizons. In A-horizon, soil aluminum saturation (AlS) had higher influence on Ali/(Ca + Mg) molar ratio than soil water chemistry did; higher soil aluminum saturation (AlS) led to higher Ali/(Ca + Mg) molar ratio in soil water. In the deeper horizons (i.e., B1-, B2- and BC-horizon), inorganic aluminum (Ali) in soil water had more and more important role in regulating Ali/(Ca + Mg) molar ratio. On regional scale, soil aluminum saturation (AlS) as well as cation exchange capacity (CEC) was the
dominant factor controlling Ali/(Ca + Mg) molar ratio. This should be paid enough attention on when making regional acid rain control policy in China. 相似文献
132.
133.
本文根据历年的监测资料,分析了陕西省酸雨的分布规律及其特征。指出:受煤烟型大气污染的影响,酸雨以硫雨型为主,从北而南频率逐步增大,pH值介于4.5~5.6之间的占90.5%。并探讨了酸雨形成的原因及防治措施。 相似文献
134.
Stuart Batterman 《Environmental management》1992,16(1):133-141
This article addresses the use of critical loads in optimized emission abatement strategies. Critical loads represent the
maximum tolerable deposition possible without adverse impacts, a limit that is highly spatially variable. As deposition targets,
critical loads cannot be satisfied at all receptors in Europe. Consequently, there is a need for alternative criteria that
still relate to ecological indicators, yet that are feasible, consistent, and equitable. Two criteria are suggested: the relative
critical load coverage and the relative deposition reduction. Deposition goals based on these criteria will guarantee that
a specified fraction of ecosystems will attain target loads and thus will be protected from adverse environmental impacts.
In areas that cannot achieve target loads with the best available control measures, deposition can be reduced to a specified
fraction of the unabated level.
Examples are presented that demonstrate their derivation and application of the two criteria. The criteria have been implemented
in the European-scale Regional Acidification Information and Simulation (RAINS) model. Results obtained indicate that optimized
emission strategies based on critical loads may be similar to emission strategies based on deposition reductions at certain
levels of the two criteria. This suggests that it may not be necessary to utilize critical loads to formulate deposition targets.
A second example shows the effect of excluding countries from European cost minimization. A country's participation can save
costs with moderate deposition targets; however, significant costs can be imposed with low (stringent) deposition targets.
These preliminary results have significant implications for multilateral negotiations. 相似文献
135.
Long Term Effects of Acid Irrigation at the Höglwald on Seepage Water Chemistry and Nutrient Cycling
Wendelin Weis Roland Baier Christian Huber Axel Göttlein 《Water, Air, & Soil Pollution: Focus》2007,7(1-3):211-223
In order to test the hypothesis of aluminium toxicity induced by acid deposition, an experimental acid irrigation was carried out in a mature Norway spruce stand in Southern Germany (Höglwald). The experiment comprised three plots: no irrigation, irrigation (170 mm a?1), and acid irrigation with diluted sulphuric acid (pH of 2.6–2.8). During the seven years of acid irrigation (1984–1990) water containing 0.43 molc m?2 a?1 of protons and sulphate was added with a mean pH of 3.2 (throughfall?+?acid irrigation water) compared to 4.9 (throughfall) on both control plots. Most of the additional proton input was consumed in the organic layer and the upper mineral soil. Acid irrigation resulted in a long lasting elevation of sulphate concentrations in the seepage water. Together with sulphate both aluminium and appreciable amounts of base cations were leached from the main rooting zone. The ratio between base cations (Ca?+?Mg?+?K) and aluminium was 0.79 during acid irrigation and 0.92 on the control. Neither tree growth and nutrition nor the pool of exchangeable cations were affected significantly. We conclude that at this site protection mechanisms against aluminium toxicity exist and that additional base cation runoff can still be compensated without further reduction of the supply of exchangeable base cations in the upper mineral soil. 相似文献
136.
澳大利亚矿山酸性废水的管理与处理 总被引:3,自引:1,他引:2
本文简要介绍了澳大利亚矿山含酸废弃物及酸性废水的管理与处理方法 ,将为我国的矿山环境保护提供借鉴作用。 相似文献
137.
Ren Lefebvre Daryl Hockley Jason Smolensky Ann Lamontagne 《Journal of contaminant hydrology》2001,52(1-4):165-186
Acid mine drainage (AMD) results from the oxidation of sulfides, mainly pyrite, present in mine wastes, either mill tailings or waste rock. This is the second of two papers describing the coupled physical processes taking place in waste rock piles undergoing AMD production. Since the oxidation of pyrite involves the consumption of oxygen and the production of heat, the oxidation process initiates coupled processes of gas transfer by diffusion and convection as well as heat transfer. These processes influence the supply of oxygen that is required to sustain the oxidation process. This second paper describes a numerical simulator used to represent the interaction of these coupled transfer processes. Numerical simulations are applied to two large sites with extensive characterization programs and widely different properties and behavior that were described in the first paper. The South Dump of the Doyon mine in Canada is permeable and has a high pyrite oxidation rate, thus making temperature-driven air convection the main oxygen supply mechanism. The Nordhalde of the Ronnenberg mining district in Germany contains lower permeability material which is less reactive, thus leading to a more balanced contribution of gaseous diffusion and convection as oxygen supply mechanisms. Overall, simulations allow a coherent representation of the conditions monitored within the waste rock piles and the confirmation of their physical properties. Conceptual simulations are also carried out to illustrate the potential effect of border membranes and layered co-mingling as mitigation methods used to control AMD production in either active or future waste rock piles. 相似文献
138.
研究硬脂酸改性磁铁矿对石油污水中油类物质的吸附,通过改变温度、超声振荡时间和磁铁矿与硬脂酸的质量比等因素,在最佳的改性条件下制得改性磁铁矿。将改性后的磁铁矿应用于石油污水处理,改变震荡时间,用红外分光测油仪得出吸附结果。结果表明:当改性温度为35℃、改性时间为35min、硬脂酸与磁铁矿质量比为3.5%时磁铁矿改性效果最佳,当吸附时间为8min时,对石油炼化污水中油类物质的吸附效果最好,吸附量为216.65mg/g。 相似文献
139.
Zhang Lin Meiqing Shi Xiaobo Min Chen Tian Taixu Hao Sijie Zhu Yun Ge Qingwei Wang Xu Yan 《环境科学学报(英文版)》2022,34(12):128-137
Lead (Pb) coprecipitation with jarosite is common in natural and engineered environments, such as acid mine drainage (AMD) sites and hydrometallurgical industry. Despite the high relevance for environmental impact, few studies have examined the exact interaction of Pb with jarosite and the dissolution behavior of each phase. In the present work, we demonstrate that Pb mainly interacts with jarosite in four modes, namely incorporation, occlusion, physically mixing, and chemically mixing. For comparison, the four modes of Pb-bearing natrojarosite were synthesized and characterized separately. Batch dissolution experiments were undertaken on these synthetic Pb-bearing natrojarosites under pH 2 to simulate the AMD environments. The introduction of Pb decreases the final Fe releasing efficiency of jarosite-type compounds from 18.18% to 3.45%-5.01%, showing a remarkable inhibition of their dissolution. For Pb releasing behavior, PbSO4 dissolves in preference to Pb-substituted natrojarosite, i.e., (Na, Pb)-jarosite, which primarily results in the sharp increase of Pb releasing concentration (> 40 mg/L). PbSO4 occlusion by jarosite-type compounds can significantly reduce the release of Pb. The results of this study could provide useful information regarding Fe and Pb cycling in acidic natural and engineered environments. 相似文献
140.
Modified kaolin clays were used as adsorbents for SO(2) gas adsorptions. The clays were heated up to 900 °C previous to acid treatments with 0.5 N sulfuric acid solutions at boiling temperature during different times up to 1440 min. Equilibrium adsorption at 25 °C and 0.1 MPa was carried out by using a volumetric apparatus. The samples were characterized by chemical analysis, X-ray diffraction and infrared analysis. The heating of the clays followed by acid treatment improved the adsorption capacity of the kaolin clays. The presence of amorphous silica and hydroxyl in the final products improved SO(2) adsorption capacity. Better properties for SO(2) adsorption were found in kaolin rich in not well ordered kaolinite clay mineral. 相似文献