全文获取类型
收费全文 | 368篇 |
免费 | 17篇 |
国内免费 | 45篇 |
专业分类
安全科学 | 5篇 |
废物处理 | 8篇 |
环保管理 | 57篇 |
综合类 | 199篇 |
基础理论 | 33篇 |
污染及防治 | 90篇 |
评价与监测 | 33篇 |
社会与环境 | 4篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 4篇 |
2022年 | 3篇 |
2021年 | 1篇 |
2020年 | 4篇 |
2019年 | 2篇 |
2018年 | 2篇 |
2017年 | 5篇 |
2016年 | 9篇 |
2015年 | 12篇 |
2014年 | 16篇 |
2013年 | 33篇 |
2012年 | 17篇 |
2011年 | 29篇 |
2010年 | 11篇 |
2009年 | 20篇 |
2008年 | 29篇 |
2007年 | 28篇 |
2006年 | 17篇 |
2005年 | 8篇 |
2004年 | 11篇 |
2003年 | 17篇 |
2002年 | 11篇 |
2001年 | 11篇 |
2000年 | 16篇 |
1999年 | 4篇 |
1998年 | 17篇 |
1997年 | 16篇 |
1996年 | 14篇 |
1995年 | 8篇 |
1994年 | 9篇 |
1993年 | 11篇 |
1992年 | 17篇 |
1991年 | 5篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1987年 | 4篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1979年 | 1篇 |
排序方式: 共有430条查询结果,搜索用时 15 毫秒
161.
《International Journal of Sustainable Engineering》2013,6(4):272-280
ABSTRACTPoultry skin waste is considered to be a promising source of biodiesel. However, this source presents an environmental threat as it is being discharged into landfills without any treatment. We studied the feasibility of biodiesel production from poultry skin waste. Two-step extraction of lipids from chicken’s skin was developed and gave 97.5% yield using the optimum time and temperature. Esterification was then optimised to remove free fatty acids (FFA) where the ideal parameters were 65 °C during 30min with a molar ratio of methanol to oil of (1:3) and 1% of H2SO4. The third step was the transesterification which was performed using 60 °C and 300–600 rpm agitation for 1 h, with 1% basic catalyst and 1:3 (molar ratio) of methanol to oil. The biodiesel (FAME), was characterised using gas chromatography coupled with mass spectrometry (GC-MS) followed by chemical and physical analyses such as iodine number, acid number, flash point and cetane number. The total conversion was obtained using above conditions and most of the studied proprieties of produced biodiesel meet the EN14214 standard. This is an extremely encouraging result, offering a good source of biodiesel by valuing poultry skin waste. 相似文献
162.
In this paper, sulfonic groups functionalized annealed bio-based carbon microspheres loaded polytetrafluoroethylene (A-BCMSs-SO3H@PTFE) fibers with high activity, high stability, and easy regeneration were successfully fabricated by a simple method using low-cost raw materials. The characterization results showed that the annealed biomass carbon microspheres derived from waste Camellia oleifera shells were evenly distributed on the polytetrafluoroethylene fibers and the sulfonic groups can be successfully loaded on the surface of annealed biomass carbon microspheres by room temperature sulfonation. Subsequently, the as-prepared A-BCMSs-SO3H@PTFE fibers were applied to the acid-catalyzed synthesis of liquid biofuel 5-ethoxymethylfurfural. The catalytic experiment results indicated that the annealing temperature and time during catalyst preparation have a significant effect on the activity and selectivity of A-BCMSs-SO3H@PTFE fibers. The results of catalytic reaction kinetics showed that the yield of 5-ethoxymethylfurfural can reach more than 60%after 72 h of acid-catalyzed reaction. The stability test showed that the as-prepared A-BCMSs-SO3H@PTFE fibers still maintained a stable acid catalytic activity after four recycles. 相似文献
163.
The typical parameters of acid precipitation are evaluated in the forest of Vallombrosa (Tuscan Appennines) during the dry period 1988-89. Individual rain events (dry and wet deposition) were sampled in a clearing of the forest and below the canopy of an evergreen tree as well as a deciduous broadleaf tree. In atmospheric precipitation the pH values usually vary around 4.4, with neutralization in the hot season due to calcareous material from distant sources. Relatively large concentrations of Pb and Cd are found in rain, but only in a small amount in canopy leachate. Aluminium, manganese and iron are more significantly washed off than Pb and Cd. 相似文献
164.
为研究酸沉降对水生生态系统的影响,1991年至1992年间,对地处我国重酸雨区域的重庆市郊6个水体中的藻类进行了比较研究,结果表明,绿藻门的种类最多,占种类总数的50%以上,其次是蓝藻或硅藻。藻类的细胞密度、生物量和叶绿素a,在酸化水体中(pH值<5.0)分别为23.3~49.9万个/L,0.59~1.05mg/L和0.65~3.01mg/m3;在轻度酸化水体(6.0>pH值>5.0)分别为433.9~680.0万个/L,6.6~21.75mg/L和14.66~25.19mg/m3。三项指标均随水体酸度的增加而减少。酸化水体中的藻类生长潜力(AGP)很弱,低pH值和可给态磷的不足是造成AGP低的主要限制因素。 相似文献
165.
166.
大连市酸雨的变化趋势及来源简析 总被引:1,自引:0,他引:1
“十一五”期间大连市的酸雨污染呈波动趋势,2009年的酸雨污染最为严重,酸雨频率达到40.3%,pH均值4.84,属于中酸雨污染。大连市酸雨的来源受外来地区输送的影响较大,大连市本地源排放对硫和氮的湿沉降的贡献仅在10—20%之间;外来源中,山东排放的贡献占30~40%,辽宁其他区域的贡献10%左右,同时日本、朝鲜和韩... 相似文献
167.
Distribution of Al-, Fe- and Mn-pools and their correlation in soils from two acid deposition small catchments in Hunan, China 总被引:2,自引:0,他引:2
Distribution of Al-, Fe- and Mn-pools was investigated in five forest soil profiles (consisting of four horizons) in each of two Hunan catchments (BLT and LKS) where acid deposition has been considered critical. Al- and Fe-pools were higher in BLT than those in LKS, but Mn-pools much lower in BLT. Mn-pools vary from topsoils to bottom soils, but there are different trends for different Mn speciation. Al- and Fe-pools, except amorphous Feox, were positively correlated to contents of soil organic matter (OM) showed by the loss on ignition in the two catchments. Accumulation of Al- and Fe-pools may occur in the area where soil organic matter was enriched (e.g. in top soil and rhizosphere soil). However, no direct correlation is observed between Mn and OM. Acidic atmospheric deposition may affect transforming among speciations of Al-, Fe- and Mn-pools and leaching of soil Al, Fe and Mn through formation of soluble organo-metal dissolved Al which was potentially toxic, increased. There were significant correlations between Al-pools complexes or change of oxidation–reduction conditions. Mnex (exchangeable Mn) and Mnox (amorphous and organic Mn) were highly linearly correlation with soil pH values at LKS but at BLT. Under acid deposition, the availability of the nutrient Fe increased with the amount of dissolved Al, which was potentially toxic, in the two catchments. There are no significant correlations between Alex (exchangeable Al) and Mnex, Feex (exchangeable Fe) and Mnex in this work, indicating potentially toxic Mn increase seldom accompanying with Al increase in the two catchments. 相似文献
168.
169.
170.
Acid hydrolysis of estuarine water samples for the determination of amino acids (AAs) was tested and found to be effective
at high (250 μM) nitrate concentrations when the anti-oxidant, ascorbic acid, was added to the samples. Hydrolysable AA concentrations
were then determined in surface sediments collected from low and high salinity regions of the Tamar Estuary (UK) during winter
2003 and 2004, and in overlying water when simulated resuspension of sediment particles was performed. Concentrations of AAs
in sediment samples comprised <50% of particulate nitrogen, fitting the paradigm that most sedimentary nitrogen is preserved
within an organic matrix. When sediment samples were resuspended in overlying water (salinity 17.5), the rapid, measured increase
in dissolved AA concentrations almost equalled the reported nitrate concentration in the lower estuary, with the subsequent
decrease in the total dissolved AA levels suggested that bacterial uptake was occurring. Our data concur with previous studies
on nitrogen desorption from sediments and suggest that an understanding of organic nitrogen cycling will be an important aspect
of future effective estuarine management. 相似文献