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91.
The photodegradation of Acid blue 74 in aqueous solution employing a H2O2/ultraviolet system in a photochemical reactor was investigated. The kinetics of decolorization were studied by application of a kinetic model. The results show that the reaction of decolorization followed pseudo-first order kinetics. We demonstrate that there is an optimum H2O2 concentration, at which the rate of the decolorization reaction is maximum. Irradiation at 253.7 nm of the dye solution in the presence of H2O2 results in complete discoloration after ten minutes of treatment. 相似文献
92.
The governments of British Columbia, Alberta, Saskatchewan, Manitoba, Northwest Territories, and Canada held joint consultations in 1980 to review the available information on acid rain from Western and Northern Canada. It was concluded that acid rain might become a problem in the future and, hence, a research, monitoring, and management strategy for acidic deposition was needed. An overview of the joint governments' management strategy, organization of research and monitoring programs, and accomplishments to date are discussed in this article.The authors are members of the Technical Committee for the Long Range Transport of Atmospheric Pollutants (LRTAP)/Acid Deposition in Western and Northern Canada, and represent Alberta and British Columbia, respectively. 相似文献
93.
94.
基于气流轨迹聚类分析方法浅析桂林市酸雨来源 总被引:1,自引:0,他引:1
通过对桂林市2009—2013年的酸雨状况及变化趋势分析,结果表明:桂林市酸雨强度及频率从2010年出现峰值后,呈现逐渐下降的趋势;酸雨的季节分布差异明显,冬、春季酸雨频率较高,夏季相对较低;酸雨中的阴离子主要为SO2-4和NO-3,阳离子主要为Ca2+和NH+4。利用后向轨迹和聚类分析方法对桂林市酸雨来源进行气流轨迹模拟分析,结果显示,主要作用气流来自南方地区,其中东南和偏东南方向气流形成的降雨酸性较强,酸雨频率较高。 相似文献
95.
Yasmin Kelsall Mayumi Allinson Graeme Allinson Nick Turoczy Frank Stagnitti Masataka Nishikawa 《毒物与环境化学》2013,95(3-4):375-384
The movement of copper, chromium and arsenic originating from samples of the wood preservative Tanalith® through mildly acidic, sandy loam soil was investigated. Small, undisturbed soil cores (of dimensions 15 × 15 × 15 cm) were removed from the topsoil of a paddock adjacent to the Glenelg River in the Western District of Victoria, Australia. The paddock soils were thin (<30cm) greyish brown, mildly acidic, sandy loams with a moderate organic carbon content (2–5%) overlying a limestone cap. Tanalith® was applied to the surface of the cores which were then irrigated with deionised water at approximately 30 mm day‐1. Copper concentrations in all leachate remained at background levels throughout the experiment, and this element was found to be immobilised in the top 4 cm of the soil. Up to 29% of the applied dose of chromium was detected in the leachate, with breakthrough occurring within 20 days of Tanalith® application. Up to 13% ofthe applied dose ofarsenic was detected in the leachate, although in this case breakthrough was not observed until 25 days after Tanalith® application and leachate concentrations were still rising when the experiment came to a close. Significant concentrations of arsenic and chromium were found in the top 6 cm of the soil profile. 相似文献
96.
The typical parameters of acid precipitation are evaluated in the forest of Vallombrosa (Tuscan Appennines) during the dry period 1988-89. Individual rain events (dry and wet deposition) were sampled in a clearing of the forest and below the canopy of an evergreen tree as well as a deciduous broadleaf tree. In atmospheric precipitation the pH values usually vary around 4.4, with neutralization in the hot season due to calcareous material from distant sources. Relatively large concentrations of Pb and Cd are found in rain, but only in a small amount in canopy leachate. Aluminium, manganese and iron are more significantly washed off than Pb and Cd. 相似文献
97.
转鼓式内电解装置处理水中酸性橙Ⅱ染料 总被引:3,自引:1,他引:3
设计制作了转鼓式内电解反应装置,将铁屑与活性炭按体积比为1:1混匀后装填在转鼓内,对偶氮染料酸性橙Ⅱ(AOⅡ)进行降解实验,考察了溶液pH、转鼓转速和溶液浓度对AOⅡ降解过程的影响.结果表明,AOⅡ降解过程符合准一级动力学方程,酸性条件有利于AOⅡ的降解,转鼓转速过快和溶液浓度过高则不利于AOⅡ的降解.解决了铁炭床长时间运行板结结块的问题.AOⅡ分子在转鼓式内电解的作用下,其可见光和紫外光区的特征吸收峰逐渐降低直至消失,并新生成更容易生物降解的对氨基苯磺酸盐. 相似文献
98.
用灰色系统理论GM(1,1)建立大气降水中酸雨pH值的预测模型 总被引:1,自引:0,他引:1
本文用灰色系统理论GM(1,1)建立了大气降水中pH值的预测模型。经三种不同方法检验。对我市1990—1993年大气降水中酸雨pH值进行了预测,结果令人满意。 相似文献
99.
石灰—硫酸亚铁法处理高浓度砷和氟酸性废水试验研究 总被引:7,自引:0,他引:7
采用二级石灰-硫酸亚铁法处理砷和氟浓度分别高达110mg/L和650mg/L以上的酸性废水。当一、二级控制条件分别为pH9.5和9.0、Fe/As比为2.5和15时,一级砷和氟去除率分别可达99.5%和94%,二级出口砷和氟残余浓度分别可低至0.1mg/L和13.8mg/L,Cu、Zn和Pb等重金属离子均达检不出水平。 相似文献
100.