中国低碳发展的国际比较:世界贸易格局

近年来随着我国经济的持续平稳快速发展,与之相伴随的碳排放总量持续攀升,中国也因此被推上世界碳减排的风口浪尖.为了明确中国碳排放的国际地位,本文从世界贸易格局视角对中国的碳排放现状进行了国际比较研究.首先分析研究了我国2007年面临的碳排放国际形势,继而对我国的出口贸易形势进行了国际比较,最后采用GDP比例法和类推法对我国商品出口隐含的碳排放进行了初步测算,并分析了剔除出口贸易影响后的我国碳排放情况.通过研究认为:①出口贸易对我国的碳排放总量影响巨大,我国的商品出口占GDP比例长期维持在20%以上,近几年高峰值超过36%;②在当前的世界贸易格局、国际分工体系下,采用“生产者责任体系”碳排放测算模式大大高估了中国的碳排放水平,中国的碳排放总量中有34-60%是为他国服务而产生;③中国在当前世界贸易格局和国际分工体系中的地位使得中国在目前的碳排放测算模式下必然“产生较高的碳排放”;④世界各国应该重新审视和正确认识中国的“高”碳排放形势,中国为世界各国提供商品服务而产生的碳排放不应该受到指责.     

火电厂烟气排放对广州大气环境的影响

广州市是酸雨、可吸入颗粒物污染严重的地区之一,这与其能源结构以煤为主有关.广州发电厂以燃煤为主,其周围大气采样数据分析显示燃煤电厂可对周围大气环境造成较大影响,是酸雨前体物、可吸入颗粒物的主要排放源.酸雨破坏了生态环境,也阻碍了经济的发展;燃煤排放的烟尘细颗粒物属于可吸入颗粒物,其上附着的As、Cr等微量元素多为致癌物质和致基因毒性诱变物质,对周围居民的健康危害极大.最后, 对当前的环境保护工作及存在的问题进行了阐述.     

Comparison of criteria for prediction of runaway reactions in the sulphuric acid catalyzed esterification of acetic anhydride and methanol

Loss of temperature control is one of the major reasons that can lead to runaway reaction. This occurrence is commonly named thermal runway. The aim of this paper is the application of thermal runaway criteria in order to predict the onset of runaway phenomena and define the range of stability related to operating conditions in the reactor, with specific reference to the esterification of acetic anhydride and methanol catalysed by sulphuric acid tested in isoperibolic conditions. The isoperibolic calorimeter has also been used to obtain thermodynamic, kinetic and physical chemistry data necessary to develop a model for the reaction. Some runaway criteria applied in this work require a model for the process, so a model for the analyzed system been developed.Because of the modest reaction enthalpy and low activation energy this reacting system provide a severe test to the runaway criteria.In this work, various runaway criteria have been applied to the experimental and simulated data and the results obtained have been compared.     

Potential of acid activated clays in the clarification of menhaden stickwater

Abstract

The primary objective of this investigation was to determine the feasibility of using acid activated clays to clarify menhaden stickwater effluent. Experiments, such as physical and chemical properties determinations, effect of changes in pH and temperature and coagulation, and coagulation followed by clay treatment were also performed to study the separation of solids in stickwater.

Analysis of the stickwater showed that it contained 4.5% crude protein, 1.4% crude fat, 6.5% total solids, 1.13% ash and 93.1% water. At a wavelength of 575 um, the sample absorbed all the light and the percent transmittance was zero. When diluted 1:100 the percent transmittance was 0.39 at the same wavelength. Measured at 25°C the sample had a viscosity of 9.0 centipoises.

The results showed that the precipitation of fat increased with increasing temperatures, while the reverse was true for protein. A pH of 4.0 gave the maximum clarification at all temperatures employed. The viscosity decreased at pH values above and below the original pH of the sample.

Among the four different acid activated clays used in this study (trade names Supact‐150, Impact‐150, Impact‐12 and Impact‐1OORR), Impact‐150 was the most effective in protein and fat precipitation, and the degree of separation of these components increased by treating stickwater with a coagulant (aluminum sulfate) prior to treatment with acid activated clay.     

Chemical fluxes in time through forest ecosystems in the UK - Soil response to pollution recovery

Long term trend analysis of bulk precipitation, throughfall and soil solution elemental fluxes from 12 years monitoring at 10 ICP Level II forest sites in the UK reveal coherent national chemical trends indicating recovery from sulphur deposition and acidification. Soil solution pH increased and sulphate and aluminium decreased at most sites. Trends in nitrogen were variable and dependant on its form. Dissolved organic nitrogen increased in bulk precipitation, throughfall and soil solution at most sites. Nitrate in soil solution declined at sites receiving high nitrogen deposition. Increase in soil dissolved organic carbon was detected - a response to pollution recovery, changes in soil temperature and/or increased microbial activity. An increase of sodium and chloride was evident - a possible result of more frequent storm events at exposed sites. The intensive and integrated nature of monitoring enables the relationships between climate/pollutant exposure and chemical/biological response in forestry to be explored.     

Effect of tracer dyes on initial deposits and persistence of bacillus thuringiensis subsp. kurstaki toxin after application of two commercial formulations onto spruce trees

Abstract

The effect of two tracer dyes [Erio Acid Red (EAR) and Acid Black 48 (AB‐48)] on initial deposits and persistence of Bacillus thuringiensis subsp. kurstaki (Btk) toxin (delta‐endotoxin) was studied after spraying two commercial formulations, Foray® 48B and Foray® 76B, over potted white spruce [Picea glauca (Moench) Voss] seedlings, at a dosage rate of 30 billion international units (BIU) per ha. Spray was applied using a spinning disc atomizer calibrated to deliver droplet sizes similar to those utilized in ultra‐low‐volume (ULV) treatments in operational insect control programs. The sprayed seedlings were left outdoors at the Sault Ste. Marie laboratory for 18 days under natural conditions of sunlight, wind and rainfall. Initial deposits and persistence of delta‐endotoxin protein in spruce foliage were determined by immunoassay [enzyme linked immunosorbent assay (ELISA)] quantification of the delta‐endotoxin. The total protein (inactive plus active) and delta‐endotoxin (active protein) concentrations in the two formulations were determined by a gravimetric procedure and by ELISA respectively.

The initial deposit levels of the toxin on foliage were not markedly affected by the addition of either of the two tracer dyes, and showed only a narrow range of 1521 to 1625 ng/g foliage (fresh weight) for Foray 48B, and 1789 to 2056 ng/g for Foray 76B. However, the persistence of the toxin was significantly influenced by the presence of the dyes. The toxin persisted in foliage only for 7 d post‐spray When the EAR dye was added to Foray 48B, compared to 10 d when no dye was added. The average half‐life (DT₅₀) of disappearance was 17.4 h for Foray 48B with EAR, and 20.9 h when no dye was present. In contrast, the situation was reversed in Foray 76B, since the duration of persistence was 10 d when EAR was added to Foray 76B, compared to 7 d when no dye was added. The average DT₅₀ was 27.9 h for Foray 76B with EAR, and 22.2 h without the dye. Persistence was the longest (14 d) when the AB‐48 dye was added to Foray 76B, and the DT₅₀ was 44.9 h.     

交通事故动态分析法在肇事逃逸案件侦查中的研究与实践

针对传统交通事故动态分析法在交通肇事逃逸案件侦查中投入高、效率低、精度差的缺点,笔者在信息主导警务理念的指导下,综合运用逻辑学、系统科学、社会学、心理学、情报科学相关原理,动态分析交通事故现场的痕迹、车辆行驶轨迹、道路交通环境、警情综合信息、驾驶人行为与逃逸心理,以及受害者损伤特征,准确掌握车辆或驾驶人局部特征,从而为侦破交通肇事逃逸案件提供精确的查缉信息,使警务行动实现精确用警、快速反应和精确打击的目标。笔者给出了利用动态分析法侦破交通肇事逃逸案件的流程和步骤;指出提高办案水平,迫切需要加强警务信息和社会信息的有效融合,研发专门系统,强化信息研判。     

Long-term depletion of calcium and other nutrients in eastern US forests

Both harvest removal and leaching losses can deplete nutrient capital in forests, but their combined long-term effects have not been assessed previously. We estimated changes in total soil and biomass N, Ca, K, Mg, and P over 120 years from published data for a spruce-fir site in Maine, two northern hardwood sites in New Hampshire, central hardwood sites in Connecticut and Tennessee, and a loblolly pine site in Tennessee. For N, atmospheric inputs counterbalance the outputs, and there is little long-term change on most sites. For K, Mg, and P, the total pool may decrease by 2%–10% in 120 years depending on site and harvest intensity. For Ca, net leaching loss is 4–16 kg/ha/yr in mature forests, and whole-tree harvest removes 200–1100 kg/ha. Such leaching loss and harvest removal could reduce total soil and biomass Ca by 20%–60% in only 120 years. We estimated unmeasured Ca inputs from rock breakdown, root-zone deepening, and dry deposition; these should not be expected to make up the Ca deficit. Acid precipitation may be the cause of current high leaching of Ca. Although Ca deficiency does not generally occur now in acid forest soils, it seems likely if anthropogenic leaching and intensive harvest removal continue.     

Integrated assessment: Missing link in the acid rain debate?

The United States is finding it difficult to develop a coherent policy on acid rain. Despite more than a decade of scientific research and policy initiatives, no clear course of action has been identified. This article argues that what is missing is an integrated assessment of the scientific knowledge that will guide the political process. The role of the integrated assessment is described, and a conceptual framework presented that would accomplish the desired goal. Currently available acid rain assessment models are compared against this framework and found to be less than satisfactory. The article concludes by stressing the opportunity now available to the National Acid Precipitation Assessment Program to perform such an assessment and break the logjam.     

PRECIPITATION CATCH MEASURED BY TUE WYOMING SHIELD AND TUE DUAL-GAGE SYSTEM1

ABSTRACT: The Wyoming shield and dual-gage measuring systems were developed to measure all precipitation, but more specifically snowfall under windy conditions. Results of a study at five sites on the Reynolds Creek Experimental Watershed in southwest Idaho indicate that gages with Wyoming shields and the dual-gage system measured the same amount when air temperatures were higher than ?2.2°C. Precipitation amounts computed from the dual. gage system were slightly more than from gages with Wyoming shields for snowfall, especially under windy conditions. Results also show how well the Alter shielded and unshielded gages used in the dual-gage system represent the computed catch if data were only available from one or the other of the gages.