Mineralogical compositions of aquifer matrix as necessary initial conditions in reactive contaminant transport models

Mineralogical compositions and their spatial distributions are important initial conditions for reactive transport modeling. However, popular Kd-based "reactive" transport models only require contaminant concentrations in the pore fluids as initial conditions, and minerals implicitly represent infinite sources and sinks in these models. That situation results in a general neglect of mineralogical characterization in site investigations. This study uses a coupled multi-component reactive mass transport model to predict the natural attenuation of a ground water plume at a uranium mill tailings site in western USA. Numerous ground water geochemistry data are available at this site, but mineralogical data are sketchy. Even given the well-defined pore fluid chemistry, variations of secondary mineral species and mineral abundances in the aquifer resulted in significantly different modeling outcomes. Results show that the amount of calcite in the aquifer determines the distances of plume migration. The possible presence of jurbanite, an aluminum sulfate phase, can store acidity temporarily but cause more severe contamination on a later date. The surfaces of iron oxyhydroxides can store significant amounts of sulfate and protons and serve as a second source for prolonged contamination. These simulations under field conditions illustrate that mineralogical compositions are an essential requirement for accurate prediction of contaminant fate and transport.     

春季连阴雨对江苏省夏收作物产量的影响

分析了江苏省40年(1960～1999)春季连阴雨的发生概率、发展趋势及其时空分布规律。研究发现,春季连阴雨累计日数、总雨量与夏粮产量呈显著负相关关系,且累计日数≥30d时,夏粮减产非常明显,这种情况的发生概率达59．1％。     

The Impact of Uncertainty on Banking Behavior: Evidence from the US Sulfur Dioxide Emissions Allowance Trading Program

In this paper, we study empirically whether uncertainty has an influence on trade in the US sulfur dioxide allowances market. In particular, we investigate the role of uncertainty on banking behavior. To do this, we introduce a tractable, structural model of trading permits under uncertainty. The model establishes a relation between banking behavior and risk preferences, especially prudence in the Kimball (1990) sense. We then test this model using data on allowances, for utilities submitted to the US Environmental Protection Agency’s Acid Rain Program, carried over from one year to the next. Evidence is found of imprudence, namely, utilities bank permits in order to favor higher profits. Another finding is that larger utilities do not adopt behavior significantly different from that of smaller ones. This paper was presented at the “International Workshop on Uncertainty in Greenhouse Gas Inventories: Verification, Compliance & Trading” in Warsaw, Poland, September 2004, under the title “Portfolio Management of Emissions Permits and Prudence Behavior.”     

重庆高速公路安全现状分析及对策

首先分析了重庆高速公路路网现状及当前安全管理模式,再依据交警部门最新权威统计信息以及近三年交通事故总体统计信息对重庆高速安全状况进行比较分析,从宏观阐述安全形势,最后对重庆高速安全现状进行概述并提出详尽的对策。     

The Kinetics of Interesterfication on Waste Cooking Oil (Sunflower Oil) for the Production of Fatty Acid Alkyl Esters using a Whole Cell Biocatalyst (Rhizopus oryzae) and Pure Lipase Enzyme

Recent research and technology have provided promising outcomes to rely on biodiesel as the alternative and conventional source of fuel. The use of renewable sources constitutes the main stream of research. Waste Cooking Oil (WCO) was used for biodiesel production in this study. Lipase enzyme producing fungi Rhizopus oryzae 262 and commercially available pure lipase enzyme were used for comparative study in the production of FAAE. The whole cell biocatalyst and pure enzyme were immobilized using calcium alginate beads. It was prepared by optimizing with different molar ratios of calcium chloride and different percent sodium alginate. Entrapment immobilization was done for whole cell biocatalyst. PE was also immobilized by entrapment for the transesterification reaction. Four different solvents methanol, ethanol, n-propanol, n-butanol were used as the acyl acceptors. The reaction parameters like temperature, molar ratio, reaction time, and amount of enzyme to be used were also optimized for methanol alone. The same parameters were adopted for the other acyl acceptors too. Among the different acyl acceptors, methanol whose reaction parameters were optimized showed maximum conversion of triglycerides to FAAE - 94% with PE and 84% with WCB. On the whole, PE showed better catalytic converting ability with all the acyl acceptor compared to WCB, further study, it was observed that three consecutive and reversible reactions occurred in the interesterification of triglycerides. So, a kinetic model based on Michaelis-Menten equation with competitive substrate inhibition was used to find the maximum reaction rate V_i for the four solvents using pure enzyme and WCB.     

Comparing Green and Grey Infrastructure Using Life Cycle Cost and Environmental Impact: A Rain Garden Case Study in Cincinnati,OH

Green infrastructure (GI) is quickly gaining ground as a less costly, greener alternative to traditional methods of stormwater management. One popular form of GI is the use of rain gardens to capture and treat stormwater. We used life cycle assessment (LCA) to compare environmental impacts of residential rain gardens constructed in the Shepherd's Creek watershed of Cincinnati, Ohio to those from a typical detain and treat system. LCA is an internationally standardized framework for analyzing the potential environmental performance of a product or service by including all stages in its life cycle, including material extraction, manufacturing, use, and disposal. Complementary to the life cycle environmental impact assessment, the life cycle costing approach was adopted to compare the equivalent annual costs of each of these systems. These analyses were supplemented by modeling alternative scenarios to capture the variability in implementing a GI strategy. Our LCA models suggest rain garden costs and impacts are determined by labor requirement; the traditional alternative's impacts are determined largely by the efficiency of wastewater treatment, while costs are determined by the expense of tunnel construction. Gardens were found to be the favorable option, both financially (~42% cost reduction) and environmentally (62‐98% impact reduction). Wastewater utilities may find significant life cycle cost and environmental impact reductions in implementing a rain garden plan.     

连续流动法测定沉积物中的酸挥发性硫化物

优化沉积物中酸挥发性硫化物(Acid Volatile Sulfide,AVS)的提取方法并采用连续流动分析法检测提取液中的硫化物.研究了吸收液的种类、氮气流量与吹气的时间和反应温度对AVS提取效果的影响以优化提取方法.结果表明,与传统的氢氧化钠或硫酸镉-氢氧化钠吸收液相比,以氯化锌-羧甲基纤维素钠溶液为吸收液吸附效率好,稳定性高且无毒.用连续流动分析法检测提取液中的AVS快速、准确、稳定性好.     

武宜运河小流域平原河网地区水环境质量现状分析及改善对策研究

文章分析了武宜运河沿线4个例行监测断面2011年至2013年水质变化情况,结果表明武宜运河水质污染情况逐年减轻.在武宜运河流域布设了42个监测断面,其中武宜运河沿程布设14个监测断面,相关河流布设28个监测断面.监测结果表明,武宜运河全线水质属于Ⅴ类~劣Ⅴ类,水质总体上表现为宜兴段稍好于武进段.相关河道水质基本属于Ⅲ类~劣Ⅴ类.目前该区域水质污染以总氮污染为主,且总氮超标最为严重.掌握了武宜运河小流域河网地区的水环境质量现状,从工业、生活、农业面源、船舶污染等方面提出了改善水环境质量的建议对策,为开展综合整治奠定了基础,对改善流域水环境具有十分重要的意义.     

河池市城区环境空气污染现状与变化趋势研究

根据2007年-2012年河池市环境空气质量自动监测数据,采用环境空气质量指数法和综合污染指数法,评价河池市环境空气污染现状和了解污染变化趋势,并探讨变化原因,提出改善大气环境质量的应对措施,以期为河池市大气污染防治策略提供借鉴.通过分析主要污染物的监测数据,结果表明:河池市近6年来城区环境空气质量有明显好转.污染物浓度随季节性变化明显,二氧化硫第一季度至第四季度依次递减;二氧化氮与可吸入颗粒物变化相似,均为第四季度污染最严重、第二季度污染最轻.     

餐厨垃圾处理设备的现状与发展趋势研究

针对人类社会在日常运转中产生的大量餐厨垃圾,当下最有效的应对措施是发展相关的餐厨垃圾处理产业,以相关的工作模式和工作设备来应对餐厨垃圾的处理工作。由于餐厨垃圾的特殊性,不同于一般的日常生活垃圾,因此餐厨垃圾的处理设备自然也就有独特的特点与性质。当下社会中餐厨垃圾处理设备行业的发展可谓如火如荼,各种各样的餐厨垃圾处理设备应运而生,针对餐厨垃圾处理设备的发展现状与发展趋势详细的探讨,对促进中国餐饮垃圾处理行业的发展具有借鉴意义。