成都市城区大气细颗粒物水溶性离子污染特征

为了解成都市城区大气细颗粒物水溶性离子污染特征,在成都市城区四季采集PM2.5有效样品共计102个,测得颗粒物质量浓度以及水溶性离子质量浓度(NH4+、Ca2+、Na+、Mg2+、K+、F-、NO3-、SO42-、Cl-),并分析其浓度变化特征,重点关注二次无机离子的污染特征及形成影响.结果表明,成都市城区水溶性离子与...     

乌鲁木齐市一次冷空气过境天气对空气污染的影响分析

根据对2006年11月20～28日乌鲁木齐市出现冷空气过境天气过程的天气形式和主要气象要素及空气污染变化情况进行的分析,结果表明:冷空气过境天气前后,诸多气象要素发生了变化,冷空气导致逆温层的破坏和降水过程使各项污染物均得到有效的清除.通过此分析可为类似天气的空气质量预报提供思路.     

房地产用地土壤污染环境风险评价——以江苏某搬迁企业原址用地为例

许多房地产项目都是在工业企业原址上进行开发建设,可能存在不同程度的土壤污染。土壤污染的评估和修复方案已成为房地产开发项目环评的重点,文中采用单因子指数法、内梅罗指数法和土壤背景值对照法对江苏某房地产用地土壤进行了环境风险评价,结果表明该地块不需要进行土壤修复和处置。     

Preparation and performance of arsenate (V) adsorbents derived from concrete wastes

Solid adsorbent materials, prepared from waste cement powder and concrete sludge were assessed for removal of arsenic in the form of arsenic (As(V)) from water. All the materials exhibited arsenic removal capacity when added to distilled water containing 10–700 mg/L arsenic. The arsenic removal isotherms were expressed by the Langmuir type equations, and the highest removal capacity was observed for the adsorbent prepared from concrete sludge with heat treatment at 105 °C, the maximum removal capacity being 175 mg-As(V)/g. Based on changes in arsenic and calcium ion concentrations, and solution pH, the removal mechanism for arsenic was considered to involve the precipitation of calcium arsenate, Ca₃(AsO₄)₂. The enhanced removal of arsenic for the adsorbent prepared from concrete sludge with heat treatment was thought to reflect ion exchange by ettringite. The prepared adsorbents, derived from waste cement and concrete using simple procedures, may offer a cost effective approach for arsenic removal and clean-up of contaminated waters, especially in developing countries.     

Comparison of criteria for prediction of runaway reactions in the sulphuric acid catalyzed esterification of acetic anhydride and methanol

Loss of temperature control is one of the major reasons that can lead to runaway reaction. This occurrence is commonly named thermal runway. The aim of this paper is the application of thermal runaway criteria in order to predict the onset of runaway phenomena and define the range of stability related to operating conditions in the reactor, with specific reference to the esterification of acetic anhydride and methanol catalysed by sulphuric acid tested in isoperibolic conditions. The isoperibolic calorimeter has also been used to obtain thermodynamic, kinetic and physical chemistry data necessary to develop a model for the reaction. Some runaway criteria applied in this work require a model for the process, so a model for the analyzed system been developed.Because of the modest reaction enthalpy and low activation energy this reacting system provide a severe test to the runaway criteria.In this work, various runaway criteria have been applied to the experimental and simulated data and the results obtained have been compared.     

The Coastal Environmental Characteristics of Taiwan

Abstract

There are three major factors affecting the coastal environment in Taiwan: tidal current, long-shore current and land subsidence. in Taiwan, most industrial areas are located on the southwestern coast. Most of the pollutants from the factories are discharged directly to the ocean, harbours or rivers. the pollutants in harbours or rivers will eventually be delivered to coastal waters. There, the tidal current is the major force dispersing the pollutants nearshore. the polluted water extends to an area about 5 km on both sides from the discharge source, and within about 3–4 km off-shore. in this study, Hsien-Da Harbour in southwestern Taiwan is cited to explain the effects of tidal current on the coastal environment. the long-shore current induced by breaking waves is the major force shaping the coastal morphology. Along the western coast of Taiwan, the long-shore current mainly flows northward along the southern section, and southward along the northern section. in the last one hundred years, in general, the coast has been eroded along the northern and southern sections of western coast, and some reclaimed lands were formed in the middle section. Recently, erosion in some coastal zones is quite serious because of excess groundwater extraction, especially along the southwestern coast. Groundwater extraction might also induce land subsidence. There are some areas near the coast which suffer serious land subsidence problems.     

Potential of acid activated clays in the clarification of menhaden stickwater

Abstract

The primary objective of this investigation was to determine the feasibility of using acid activated clays to clarify menhaden stickwater effluent. Experiments, such as physical and chemical properties determinations, effect of changes in pH and temperature and coagulation, and coagulation followed by clay treatment were also performed to study the separation of solids in stickwater.

Analysis of the stickwater showed that it contained 4.5% crude protein, 1.4% crude fat, 6.5% total solids, 1.13% ash and 93.1% water. At a wavelength of 575 um, the sample absorbed all the light and the percent transmittance was zero. When diluted 1:100 the percent transmittance was 0.39 at the same wavelength. Measured at 25°C the sample had a viscosity of 9.0 centipoises.

The results showed that the precipitation of fat increased with increasing temperatures, while the reverse was true for protein. A pH of 4.0 gave the maximum clarification at all temperatures employed. The viscosity decreased at pH values above and below the original pH of the sample.

Among the four different acid activated clays used in this study (trade names Supact‐150, Impact‐150, Impact‐12 and Impact‐1OORR), Impact‐150 was the most effective in protein and fat precipitation, and the degree of separation of these components increased by treating stickwater with a coagulant (aluminum sulfate) prior to treatment with acid activated clay.     

Chemical fluxes in time through forest ecosystems in the UK - Soil response to pollution recovery

Long term trend analysis of bulk precipitation, throughfall and soil solution elemental fluxes from 12 years monitoring at 10 ICP Level II forest sites in the UK reveal coherent national chemical trends indicating recovery from sulphur deposition and acidification. Soil solution pH increased and sulphate and aluminium decreased at most sites. Trends in nitrogen were variable and dependant on its form. Dissolved organic nitrogen increased in bulk precipitation, throughfall and soil solution at most sites. Nitrate in soil solution declined at sites receiving high nitrogen deposition. Increase in soil dissolved organic carbon was detected - a response to pollution recovery, changes in soil temperature and/or increased microbial activity. An increase of sodium and chloride was evident - a possible result of more frequent storm events at exposed sites. The intensive and integrated nature of monitoring enables the relationships between climate/pollutant exposure and chemical/biological response in forestry to be explored.     

Effect of tracer dyes on initial deposits and persistence of bacillus thuringiensis subsp. kurstaki toxin after application of two commercial formulations onto spruce trees

Abstract

The effect of two tracer dyes [Erio Acid Red (EAR) and Acid Black 48 (AB‐48)] on initial deposits and persistence of Bacillus thuringiensis subsp. kurstaki (Btk) toxin (delta‐endotoxin) was studied after spraying two commercial formulations, Foray® 48B and Foray® 76B, over potted white spruce [Picea glauca (Moench) Voss] seedlings, at a dosage rate of 30 billion international units (BIU) per ha. Spray was applied using a spinning disc atomizer calibrated to deliver droplet sizes similar to those utilized in ultra‐low‐volume (ULV) treatments in operational insect control programs. The sprayed seedlings were left outdoors at the Sault Ste. Marie laboratory for 18 days under natural conditions of sunlight, wind and rainfall. Initial deposits and persistence of delta‐endotoxin protein in spruce foliage were determined by immunoassay [enzyme linked immunosorbent assay (ELISA)] quantification of the delta‐endotoxin. The total protein (inactive plus active) and delta‐endotoxin (active protein) concentrations in the two formulations were determined by a gravimetric procedure and by ELISA respectively.

The initial deposit levels of the toxin on foliage were not markedly affected by the addition of either of the two tracer dyes, and showed only a narrow range of 1521 to 1625 ng/g foliage (fresh weight) for Foray 48B, and 1789 to 2056 ng/g for Foray 76B. However, the persistence of the toxin was significantly influenced by the presence of the dyes. The toxin persisted in foliage only for 7 d post‐spray When the EAR dye was added to Foray 48B, compared to 10 d when no dye was added. The average half‐life (DT₅₀) of disappearance was 17.4 h for Foray 48B with EAR, and 20.9 h when no dye was present. In contrast, the situation was reversed in Foray 76B, since the duration of persistence was 10 d when EAR was added to Foray 76B, compared to 7 d when no dye was added. The average DT₅₀ was 27.9 h for Foray 76B with EAR, and 22.2 h without the dye. Persistence was the longest (14 d) when the AB‐48 dye was added to Foray 76B, and the DT₅₀ was 44.9 h.     

The Declining Influence of Science On Marine Environmental Policy

Abstract

Differences between the scientific and environmental policy communities regarding marine environmental protection strategies are discussed in the context of the nature and extent of scientific influence on marine environmental policy. Public perceptions of the nature and severity of marine pollution frequently differ from scientific assessments. the thesis of this paper is that the increasing influence of public perception on marine environmental protection policy is leading to the adoption of simplistic and unnecessarily extreme approaches to marine pollution prevention and to a reduced reliance on science. This trend is illustrated by some recent international developments and some suggestions are made towards enhancing the influence of science on marine protection policy.