过硫酸钾溶液对测定总氮的影响

通过对过硫酸钾的配制方法,加热时的水浴温度,反应介质条件及其纯度等因素对总氮测定结果影响的讨论,提出了过硫酸钾有效的配制方法及其纯度要求,以进一步提高总氮测定的准确度.     

Fate of 14C‐lindane in a rice‐fish model ecosystem*

Abstract

A model ecosystem has been used to evaluate the impact of ¹⁴C‐lindane on rice‐fish agricultural system. The distribution of ¹⁴C‐residues among the constituents of the model ecosystem was studied over a period of 90 days. The insecticide was found to be readily absorbed by the roots and translocated to all parts of the rice plant. The peak level in the shoots (26 ppm) and roots (105 ppm) of plants was reached to within three weeks. Lindane was concentrated in fish and residues as high as 90 ppm could be detected after 30 days.

The major part of the residues present in the different constituents of the ecosystem could be extracted with hexane and proved to contain soley the parent compound. The data obtained show that lindane possesses a relatively low biodegradability in fish and in rice plant. The insecticide accumulates in fish and rice plant to considerable extent.     

东沙沙洲离岸潮间带风电场建设对鸟类的影响

对东沙沙洲离岸潮间带风电场的建设给鸟类造成的影响进行了调查。分析表明,噪声对东沙沙洲迁徙鸟类影响不大;光对夜间迁徙鸟类造成一定的影响;风机对候鸟迁徙影响不大,少数低飞候鸟可能存在撞机风险;风机基础和人工岛的永久占地造成的直接生物量损失为3.2 t/a,总计损失约64万元;风电场建设将使东沙沙洲鸟类栖息地面积减少81.5 km2,约占总栖息地面积的13.9%,但风机对鸻鹬类等中小型涉禽、水鸟的觅食影响不大,风电场区域仍可作为这些鸟类的觅食地。在影响分析的基础上提出了设计、施工、运营阶段相应的防范措施。     

基于在线监测数据的青奥会废气重点污染源临时管控效果评估

简述了南京市废气重点污染源在线监测系统的组成和工作原理。根据2014年南京青奥会废气重点污染源环境临时管控要求,利用在线监控点位对7月份(青奥会前)和8月份(青奥会期间)重点废气污染源在线监测数据进行了统计分析。结果表明,青奥会期间南京市管控废气重点污染源的SO2和NOX排放量虽有个别企业出现增加,但整体排放量均有所降低,环境空气中SO2和NOX的平均值也有所降低,基本达到了临时管控要求。     

Derivation of hazardous doses for amphibians acutely exposed to ionising radiation

Derivation of effect benchmark values for each taxonomic group, which has been difficult due to lack of experimental effects data, is required for more adequate protection of the environment from ionising radiation. Estimation of effects doses from nuclear DNA mass and subsequent species sensitivity distribution (SSD) analysis were proposed as a method for such a derivation in acute irradiation situations for assumed nuclear accident scenarios. As a case study, 5% hazardous doses (HD₅s), at which only 5% of species are acutely affected at 50% or higher lethality, were estimated on a global scale. After nuclear DNA mass data were obtained from a database, 50% lethal doses (LD₅₀s) for 4.8 and 36% of the global Anura and Caudata species, respectively, were estimated by correlative equations between nuclear DNA mass and LD₅₀s. Differences between estimated and experimental LD₅₀s were within a factor of three. The HD₅s obtained by the SSD analysis of these estimated LD₅₀s data were 5.0 and 3.1 Gy for Anura and Caudata, respectively. This approach was also applied to the derivation of regional HD₅s. The respective HD₅s were 6.5 and 3.2 Gy for Anura and Caudata inhabiting Japan. This HD₅ value for the Japanese Anura was significantly higher than the global value, while Caudata had no significant difference in global and Japanese HD₅s. These results suggest that this approach is also useful for derivation of regional benchmark values, some of which are likely different from the global values.     

Quantitative structure-activity relationship (QSAR) models for polycyclic aromatic hydrocarbons (PAHs) dissipation in rhizosphere based on molecular structure and effect size

Rhizoremediation is a significant form of bioremediation for polycyclic aromatic hydrocarbons (PAHs). This study examined the role of molecular structure in determining the rhizosphere effect on PAHs dissipation. Effect size in meta-analysis was employed as activity dataset for building quantitative structure-activity relationship (QSAR) models and accumulative effect sizes of 16 PAHs were used for validation of these models. Based on the genetic algorithm combined with partial least square regression, models for comprehensive dataset, Poaceae dataset, and Fabaceae dataset were built. The results showed that information indices, calculated as information content of molecules based on the calculation of equivalence classes from the molecular graph, were the most important molecular structural indices for QSAR models of rhizosphere effect on PAHs dissipation. The QSAR model, based on the molecular structure indices and effect size, has potential to be used in studying and predicting the rhizosphere effect of PAHs dissipation.     

Effect of sorbed and desorbed Zn(Ⅱ) on the growth of a green alga (Chlorella pyrenoidosa)

Toxic effect of Zn(Ⅱ) on a green alga (Chlorella pyrenoidasa) in the presence of sepiolite and kaolinite was investigated.The Zn-free clays were found to have a negative impact on the growth of C.pyrenoidosa in comparison with control samples (without adding any clay or Zn(Ⅱ)).When Zn(Ⅱ) was added,the algae in the presence of clays could be better survived than the control samples,which was actually caused by a decrease in Zn(Ⅱ) concentration in the solution owing to the adsorption of Zn(Ⅱ) on the clays.When the solution system was diluted,the growth of algae could be further inhibited as compared to that in a system which had the same initial Zn(Ⅱ) concentration as in the diluted system.This in fact resulted from desorption of Zn(Ⅱ) from the zinc-contaminated clays,although the effect varied according to the different desorption capabilities of sepiolite and kaolinite.Therefore the adsorption and desorption processes of Zn(Ⅱ) played an important part in its toxicity,and adsorption and desorption of pollutants on soils/sediments should be well considered in natural eco-environmental systems before their risk of toxicity to aquatic organisms was assessed objectively.     

对温度环境中产品失效机理的探讨

温度影响造成产品的故障是各种环境中最多的,本文对温度环境下产品失效机理进行了分析,并针对性地提出了对产品进行有效防护的方法.     

阴阳极协同作用降解有机污染物的研究进展

电化学法催化降解有机污染物已引起广泛兴趣。在电极的作用下,电化学反应和化学催化作用结合,可导致有机分子的电催化降解。选用合适的阳极和阴极材料可以加速电化学反应速率,有助于有机物的电化学转化。本文介绍了阳极和阴极氧化有机物的原理,综述了近年来阴阳两极协同作用降解有机物的进展。     

家用空调噪声监测与评价

为解决家用空调器噪声污染纠纷日益增多的问题,以一居民住宅楼为例,对家用空调噪声影响进行了监测与评价,并提出了防治措施。