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121.
污泥屏障氧化缓冲容量与重金属再溶出关系研究 总被引:1,自引:0,他引:1
借助微生物厌氧活动特别是硫酸盐还原反应,污泥屏障可用来固定尾矿堆场重金属.针对尾矿风化淋滤形成的酸性采矿废水(AMD)与污泥之间发生的氧化还原反应导致的重金属溶出问题,通过氧化滴定实验研究了不同污泥悬液的氧化缓冲容量及其与重金属浓度的关系.结果表明,污泥悬液的氧化缓冲容量随着悬液固液比的增大略有减小,但随着悬液厌氧培养时间的延长而增加.污泥的氧化缓冲容量主要来自Eh≤-150mV的强烈还原区间,可达氧化缓冲容量的50%以上.氧化滴定过程中发现,当Eh≥-150mV时,Zn首先明显溶出;当Eh≥150mV时,Cu和Pb明显溶出.基于实验结果,建立了污泥屏障在AMD渗流条件下氧化缓冲容量消耗的数学模型.模拟计算结果表明,当AMD水头高度为10m时,厚度2m的污泥屏障经历AMD溶液38787a的渗透氧化,仍可保持原有的强烈还原状态,具备对重金属的固定效果. 相似文献
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123.
酸缓冲容量对污泥屏障重金属再溶出控制研究 总被引:1,自引:0,他引:1
借助污泥中的厌氧微生物活动,污泥屏障可用来固定尾矿堆场的重金属.针对尾矿风化淋滤形成的酸性采矿废水(acidmine drainage,AMD)与污泥屏障相互作用,可能会引起已固定重金属再次溶出问题,通过酸滴定实验,研究了不同厌氧培养时间的污泥悬液的酸缓冲容量及其对重金属再溶出的影响.结果表明,污泥悬液酸缓冲容量与悬液固液比成正比,并随着厌氧还原程度的加深而增加.碳酸盐缓冲体系和有机质缓冲体系对污泥悬液酸缓冲有重要意义.酸滴定实验发现,随着pH降至6.2以下,重金属Zn、Pb和Cu开始快速溶解释放,且释放量符合ZnCuPb.基于实验结果,建立了污泥屏障在AMD渗透条件下酸缓冲容量消耗的数学模型.模拟计算结果表明,对于厚度2.0 m的污泥屏障,即使在10.0 m水头的AMD渗透酸化条件下,有效酸缓冲容量经历666 a之后才能被耗尽,在此时间内污泥屏障具备对重金属的生物化学固定能力. 相似文献
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为优化移动式人工制冷设备在高温独头掘进巷道工作面的制冷效果,通过设置风障形成密闭制冷空间,利用数值计算的方法,分别分析风障距工作面距离、回风管压力、回风管垂直高度对掘进工作面制冷效果的影响。研究结果表明:设置风障能够有效缩小制冷空间,阻隔热量,提高制冷效果;风障与工作面之间的距离对制冷效果有显著影响,风障的最佳布置距离为5 m;回风口压力过大或过小都不利于制冷效果,最佳压力为-70 Pa;回风管垂直高度不同,制冷效果也大有不同,其最佳高度为1 m。利用数值模拟所得工况参数进行现场试验,结果表明风障在高温独头掘进巷道降温中具有良好的实际应用效果。研究结果对高温矿井人工制冷工况优化,提高制冷效果具有指导意义。 相似文献
126.
Adsorption onto solid phases plays an important role in the transport of radionuclides and contaminants in the environment. Radionuclides in radioactive waste have been considered to be hazardous pollutants, and their migration with groundwater is strongly affected by sorption on the geologic media. Therefore, the knowledge of radionuclide sorption is of great importance in the management of radioactive wastes. A series of batch sorption experiments were conducted separately to investigate sorption and transport behaviour of cobalt, strontium and caesium on and through marble. Batch-mode kinetic and equilibrium studies have been carried out at different temperatures. Sorption experimental data were analysed by kinetic and isotherm models. Based on the results obtained, it can be concluded that the marble is an economic and efficient retaining material for environmental hazardous migration and/or leakage of some radionuclides. Therefore, this study could be used as a starting point to establish and consider that rock as a reactive barrier around the disposal facilities at the nuclear activity centres. 相似文献
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128.
Yunnan Province has many and unique natural resources and rich biodiversity. Natural reserves (NRs) play a significant role in maintaining and protecting the biodiversity and stability of ecosystems in this area. Yunnan is a typically eco-environmentally fragile area; thus positive effects of NRs are important in the construction of an ecological safety barrier for southwest China. Evaluation of the effectiveness of management of NRs has been implemented to improve management outcomes. This study provides indices to evaluate problems and management effectiveness for 60 NRs, covering national and provincial NRs of Yunnan Province. These indicate that management of NRs suffers from inadequate funding, poor infrastructure and equipment, low community participation, and a lack of government support. The indices had relatively low scores for infrastructure and equipment, ecotourism, monitoring, and evaluation, but high scores for planning and design and ownership. There were significant positive correlations between protection rank, size, age of NRs, and management effectiveness. International exchanges and collaboration would help to improve management of the NRs. NRs that straddle administrative boundaries had relatively higher scores than those within an administrative unit. Management success was not correlated with staff input, which might imply low efficiency of staff in this area. Some recommendations are offered to improve management of NRs based on analysis of management problems and identification of influencing factors. 相似文献
129.
ABSTRACTThe leather-processing industry (LPI) is constantly polluting the environment in Bangladesh. As a result, stakeholders are continuously pressurizing managers working in LPI to embrace green leather-processing activities. Thus, the green concept is attracting significant attention from managers in the Bangladeshi LPI. However, the industry is struggling with many barriers to implementing green supply chain management (GSCM). There are many studies regarding barriers to GSCM. However, those studies failed to show the possible pathways to implement GSCM. This study addresses the gap by evaluating barriers to GSCM considering effective pathways to GSCM. In this study, the Analytical Hierarchy Process (AHP) is integrated with Elimination Et Choix Traduisant La Realite (ELECTRE-I) method to identify and prioritize the barriers and to rank the possible pathways to implementing GSCM in the leather industry. To accredit the proposed framework, it is implemented on a leather-processing factory in Bangladesh. A sensitivity analysis is performed to inspect the strength of the outcome of this method. The outcome of this study indicates that the high cost of advanced technology is the most important barrier to implement GSCM while green technology and techniques are the most effective pathways to GSCM. The findings of this research will support researchers and practitioners by giving insights on barriers and possible pathways to implementing GSCM. 相似文献
130.
海上钻完井作业面临海洋环境恶劣、浅层地质灾害等复杂工况,极易发生油气泄漏、井喷等事故。为有效预防海上钻完井作业事故,提出基于瑞士奶酪模型的安全屏障模型。采用事故树和故障模式及影响分析相结合的方法,分析作业过程风险。该模型根据挪威标准D-010,建立完井作业关井阶段的物理安全屏障和安全屏障控制原理图,在此基础上构建油气泄漏事故树和失效模式与影响分析表,找出关井阶段可能的油气泄漏途径。通过对重要度计算和风险优先度值排序确定作业过程中最薄弱的安全屏障和关键故障模式。结果表明,作业过程中最薄弱的安全屏障是采油树、油管和地面控制井下安全阀(SCSSV),采油树腐蚀、密封失效、油管接头密封失效和SCSSV开关故障是影响作业过程的关键故障模式。 相似文献