硅烷的危险特性及安全操作

硅烷作为一种提供硅组分的气体源 ,广泛应用于微电子、光电器件以及高纯度多晶硅生产 ,潜在应用前景更为广阔。随着硅烷应用领域的扩大 ,硅烷安全使用和处理已成为首要的问题。通过对硅烷着火的研究和事故分析表明 ,硅烷的危险特性在于它与氧反应的极强活性 :自燃 ,着火下限低 ,燃烧能量大。由于硅烷的自燃特性 ,对它的安全防范 ,与一般的易燃易爆物质相比 ,除一些共同点之外 ,还有显著的不同之处。在操作中必须预防高浓度硅烷与氧接触发生自燃着火。同时还必须防止硅烷泄漏在有限的空间内与氧混合 ,形成不稳定爆炸性气团。笔者综合分析和研讨了硅烷着火和爆炸的最新进展和成果 ,在实践经验和分析典型硅烷事故的基础上 ,提出了处理和使用硅烷的安全操作要点。     

Determination of particulate polycyclic aromatic hydrocarbons in ambient air by gas chromatography-mass spectrometry after molecularly imprinted polymer extraction

A solid phase extraction procedure (SPE) is described for the quantitative analysis of polycyclic aromatic hydrocarbons (PAHs) in atmospheric particulate matter (PM), as ubiquitous environmental pollutants routinely measured in air quality monitoring. A SPE cartridge was used based on a molecular imprinted polymer (MIP-SPE) properly tailored for selective retention of PAHs with 4 and more benzene fused rings. The performance of the clean-up procedure was evaluated with the specific concern of selective purification towards saturated hydrocarbons, which are the PM components mostly interfering GC analysis of target PAHs. Under optimized operative conditions, the MIP-SPE provided analyte recovery close to 95% for heavier PAHs, from benzo(α)pyrene to benzo(ghi)perylene, and close to 90% for four benzene rings PAHs, with good reproducibility (RSDs: 2.5%-5.9%). Otherwise, C₁₇-C₃₂ n-alkanes were nearly completely removed. The proposed method was critically compared with Solid Phase Micro Extraction (SPME) using a polyacrylate fiber. Both methods were successfully applied to the analysis of ambient PM_2.5 samples collected at an urban polluted site. Between the two procedures, the MIP-SPE provided the highest recovery (R% ≥ 93%) for PAHs with 5 and more benzene rings, but lower for lighter PAHs. In contrast, SPME showed a mean acceptable R% value (∼ 80%) for all the investigated PAHs, except for the heaviest PAHs in the most polluted samples (R%: 110%-138%), suggesting an incomplete purification from the interfering n-hydrocarbons.     

苏北闵桥地区含油玄武岩中皂石的矿物学特征

作为储油层的沉积岩中蒙皂石矿物学特征报道较多，而作为储油层的火山岩中蒙皂石矿物学特征报道则较少。本文较详细地阐述了苏北闵桥地区含油玄武岩中主要蚀变矿物－皂石的形态、成分及X射线衍射、差热、红外特征，总结了鲍休皂石的形态特征，并对皂石的分布和成因作了探讨。认为加强皂石在油气地质，尤其是火山岩作为储油层中的应用研究十分必要。     

Environmental characteristics of sandstorm in Minqin Oasis in China for Recent 50 years

IntroductionAsandstormis a kind of severe weather phenomenawhere strong winds blowa huge amount of sand and dust intothe air ,reducing the horizontal visibility to less than 1 km( Wang, 2003a) . It is not only an important process ofaccelerating land dese…     

洱海沉积物重金属地球化学相及其污染历史研究

高原封闭、半封闭型湖泊是气候和环境演化的敏感指示器，其沉积物记录具有连续性、敏感性和高分辨率的特点。高原湖泊沉积记录在恢复和重塑各种短时间尺度（千年、百年、十年）的气候和环境演化序列上，具有其它自然历史记录无法替代的优势，尤其在揭示近代环境污染历史方面更有其独到之处。本文通过对洱海沉积物重金属地球化学相的研究，利用因子分析方法，识别了沉积物重金属的主要来源和影响其分布的主要因素，即：流域侵蚀作用、大气沉降作用、工业废水与生活污水的排放，以及早期成岩作用。同时，结合沉积物柱芯210PBex计年结果，本文初步评价了洱海150多年来的重金属污染历史：1958年以来．因为化石燃料使用量的增加．洱海湖区大气污染日趋严重；1982年后，由于西洱河水电站的建成运行和湖区植被的破坏，流域侵蚀作用显著加强，应当引起重视。     

昆明市工业固体废弃物污染特征与控制对策研究

通过对昆明市工业固体废弃物排放与处理处置现状调查,深入系统地分析了昆明市工业固体废弃物产生量、构成、来源、综合利用率和处置率等污染特征,并对工业固废的增长趋势进行了预测。从立法、执法、管理等方面提出了相应的控制对策和建议。     

Electrochemical reduction characteristics and mechanism of nitrobenzene compounds in the catalyzed Fe-Cu process

The reduction of the nitrobenzene compounds （NBCs） by the catalyzed Fe-Cu process and the relationship between the electrochemical reduction characteristics of NBCs at copper electrode and reduction rate were studied in alkaline medium（pH=11）. The catalyzed Fe-Cu process was found more effective on degradation of NBCs compared to Master Builder＇s iron. The reduction rate by the catalyzed Fe-Cu process decreased in the following order： nitrobenzene 〉4-chloro-nitrobenzene ≥m-dinitrobenzene ：〉 4-nitrophenol ≥2,4-dinitrotoluene 〉2-nitrophenol. The reduction rate by Master Builder＇s iron decreased in the following order： m-dinitrobenzene ≥4-chloro-nitrobenzene 〉4-nitrophenol 〉2,4-dinitrotoluene ≈nitrobenzene 〉2-nitrophenol. NBCs were reduced directly on the surface of copper rather than by the hydrogen produced at cathode in the catalyzed Fe-Cu process. The reduction was realized by the hydrogen produced at cathode and Fe（OH）2 in Master Builder＇s iron, It is an essential difference in reaction mechanisms between these two technologies. For this reason, the reduction by the catalyzed Fe-Cu depended greatly on NBC＇s electron withdrawing ability.     

对防震减灾工作依法行政的探讨

《中华人民共和国防震减灾法》等一系列法律、规章的出台实施，规范了防震减灾的管理体制、行政执法，并将地震部门作为行政主体推向了依法行政的前沿。笔者结合自己在行政办事中心“窗口”的工作实际，对防震减灾依法行政工作的特点和存在问题进行一些简单的探讨。     

浅析绿色制造的战略环境评价

绿色制造的战略环境评价是实现可持续发展的关键技术 ,是协调环境与社会经济发展的重要手段。它要求在绿色制造初期———绿色设计阶段就考虑整个制造过程的环境影响 ,从决策源头上控制环境污染的产生和生态环境的破坏。本文从绿色制造的广义内涵入手 ,分析了绿色制造战略环境评价的理论基础和综合集成特性 ,并提出了战略环境评价的指标体系和综合集成评价方法。     

厌氧折流板反应器(ABR)的水动力学及污泥特性

ABR作为一种新型的厌氧反应器工艺 ,具有许多优良的性能 ,如良好的水力条件及抗冲击能力、简单的构造、良好的生物种群分布及处理效果等。目前 ,其在不同废水处理中运行效果已得到越来越多的研究和实际应用。在此就该工艺的水力流态及污泥性能作了探讨