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551.
探讨了在聚乙烯醇存在下,砷钼杂多酸──罗丹明6G荧光猝灭法测定痕量砷的条件,其λ_(em)位于560nm,As(V)量在2~60ng/mL范围内与荧光猝灭值成线性关系。方法可用于环境水样中痕量砷的测定。 相似文献
552.
菌藻共生体去除废水中砷初探 总被引:25,自引:0,他引:25
研究了菌藻共生体对废水中砷的去除效果。研究发现:培养分离所得菌藻共生体中以小球藻为主,此时菌藻共生体积累砷达7.47g/kg干重。在引入菌藻共生体并培养16h后,其对无营养源的含As(Ⅲ)、As(V)的废水除砷率达80%以上,并趋于平衡;含营养源的As(Ⅲ)、As(V)的废水中,菌藻共生体对As(V)的去除率大于As(Ⅲ),对As(V)去除率超过70%,但对As(Ⅲ)的去除率也在50%以上,在除砷 相似文献
553.
Carbon and hydrogen isotope effects during sorption of organic contaminants on carbonaceous materials 总被引:1,自引:0,他引:1
Stable carbon and hydrogen isotopes can be an efficient means to validate biodegradation of organic contaminants in groundwater since it results in an isotopic fractionation. A prerequisite in applying this method in the field is the proof that other processes decreasing the contaminant concentration are conservative with respect to isotope effects. In this paper we show for carbon isotopes of halogenated hydrocarbon compounds [trichloroethene (TCE), cis-dichloroethene (c-DCE), vinylchloride (VC)] and carbon and hydrogen isotopes of BTEX compounds (benzene, toluene, p-xylene) that no significant fractionation occurs during equilibrium sorption onto activated carbon, lignite coke and lignite. In general, effects were in the range of the reproducibility limit of the analytical instrument (0.5 per thousand for delta13C, and 8 per thousand for delta2H). This observation was made for fractions sorbed of less than 5% to more than 95%. Also for rate-limited sorption of TCE onto activated carbon, no significant fractionation in carbon isotopes could be observed. These findings support the assumption that for these classes of compounds, sorption processes in aquifer systems are conservative with respect to isotope effects. 相似文献
554.
Concentrations of additive arsenic in Beijing pig feeds and the residues in pig manure 总被引:17,自引:0,他引:17
The swine industry in China has grown rapidly over last two decades. Great amount of pig manure is generated in China, which can be used as organic fertilizers on agricultural lands. Meanwhile, the organic arsenic compounds have been used as feed additives for swine disease control and weight improvement. Once the excessive additives are released in the environment, arsenic may compromise food safety and environmental quality. There is a growing public concern about the arsenic residues accumulation in pig manure, however, little work has been done to investigate the exact arsenic content in pig feed and the residues in manure in China This study investigates the concentrations of arsenic in 29 pig feed samples and 29 manure samples collected from eight pig farms in the Chaoyang district, Beijing city. The detected rate of arsenic in 29 couples of samples was 100%. The concentrations of arsenic in pig feeds and manures ranged from 0.15 to 37.8 mg/kg and 0.42 to 119.0 mg/kg, respectively. The result showed that arsenic concentration in pig manure will be greatly elevated when the arsenic in pig feed was largely increased. The loading rates of pig manure in fourteen Beijing counties and districts were in the range of 2.7–57.2 t/ha yr. Accordingly, the potential soil arsenic increase rates resulting from land application of pig manure might range between 11.8 and 78.9 μg/kg yr. Despite these findings, it is too early to draw the conclusion that arsenic pollution from pig manure is serious in Beijing farmland; therefore, longitudinal studies about the chemical form transformation and the environmental behaviors of pig manure arsenic are required in order to come up with more definitive conclusions. 相似文献
555.
氢化物发生-原子荧光光谱法测定水中微量砷 总被引:8,自引:0,他引:8
用氢化物发生-原子荧光光谱法测定天然水及废水中的微量砷,讨论并确定了试验的最佳测定条件。结果表明:砷的测定线性范围为1 ̄100ng/mL,回收率为96% ̄108%,对含0.5ng/mL砷溶液12次平行测定变异系数为1.9%,检出限为0.25ng/mL。 相似文献
556.
557.
558.
559.
硒,砷联合致畸作用的体外全胚胎培养实验研究 总被引:3,自引:0,他引:3
用体外全胚胎培养模型探讨在硒和砷共存环境下,对旋转培养48h的大鼠胚胎(9.5d)的生长发育和器官形态分化所产生的联合作用。结果表明,硒,砷联合毒性的主效应呈相互相拮抗的(P=0.0001)。除细胞干重指标外,其它反映胚胎生长发育和器官形态分化的各项指标均有明显好转,与正常对照组比较没有显著性差异(P〈0.05),砷在高剂量在(3.0μg/mL0,硒(0.5 ̄2.0μg/mL)对砷的毒性无明显缓解 相似文献
560.
氢化物发生—ICP/AES法测定地面水中的痕量砷 总被引:1,自引:0,他引:1
采用氢化物发生-ICP/AES法测定地面水中痕量砷,进行了分析线、正向入射功率的选择氢化物发生系统和气动雾化系统的性能比较等实验,砷的测定波长选用188.979nm,正向入射功率为850W。采用氢化物生系统进样,其灵敏度比气动雾化系统进样高75-110倍。方法的检测限为0.4μg/L;加标回收率为92.4%-104.6%;精密度实验的变异系数为1.8%-8.0%。 相似文献