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71.
In Finland, a new Government Decree on the Assessment of Soil Contamination and Remediation Needs (214/2007) came into force
on 1 June 2007. According to the Decree, natural baseline concentration levels should be taken into account when assessing
potential soil contamination and the need for remediation. This applies particularly in the case of toxic metallic elements,
since baseline concentrations may naturally be rather high. The new decree prescribes soil screening values for 52 substances
or groups of substances. The natural baseline concentrations have been taken into account in the definition of the screening
values for inorganic pollutants. The Geological Survey of Finland (GTK) carried out a nation-wide geochemical mapping of till
on a reconnaissance scale in 1983 and on a regional scale during 1984–1992. These surveys have provided information on natural
elemental distribution in subsoils of the glacial till. However, some important trace elements in regional mapping such as
arsenic are missing from the analysis, and subsoil samples do not reflect the diffuse anthropogenic input. Thus, GTK has continued
the survey work by determining geochemical baselines around suburban areas. Samples have been taken from humus, topsoil and
subsoil layers, and the soil parent material has covered sandy soils, glacial tills and fine-grained sediments. According
to the studies, a regional difference in the levels of arsenic and some other trace elements can be clearly seen, especially
in minerogenic soils. The results illustrate the importance of information on regional baseline concentrations while assessing
potential soil contamination. 相似文献
72.
Environmental exposure to arsenic (As) in terms of public health is receiving increasing attention worldwide following cases of mass contamination in different parts of the world. However, there is a scarcity of data available on As geochemistry in Brazilian territory, despite the known occurrence of As in some of the more severely polluted areas of Brazil. The purpose of this paper is to discuss existing data on As distribution in Brazil based on recent investigations in three contaminated areas as well as results from the literature. To date, integrated studies on environmental and anthropogenic sources of As contamination have been carried out only in three areas in Brazil: (1) the Southeastern region, known as the Iron Quadrangle, where As was released into the drainage systems, soils and atmosphere as a result of gold mining; (2) the Ribeira Valley, where As occurs in Pb-Zn mine wastes and naturally in As-rich rocks and soils; (3) the Amazon region, including the Santana area, where As is associated with manganese ores mined over the last 50 years. Toxicological studies revealed that the populations were not exposed to elevated levels of As, with the As concentrations in surface water in these areas rarely exceeding 10 microg/L. Deep weathering of bedrocks along with formation of Fe/Al-enriched soils and sediments function as a chemical barrier that prevents the release of As into the water. In addition, the tropical climate results in high rates of precipitation in the northern and southeastern regions and, hence, the As contents of drinking water is diluted. Severe cases of human As exposure related to non-point pollution sources have not been reported in Brazil. However, increasing awareness of the adverse health effects of As will eventually lead to a more complete picture of the distribution of As in Brazil. 相似文献
73.
Health risk assessment maps for arsenic groundwater content: application of national geochemical databases 总被引:3,自引:0,他引:3
This investigation assesses the feasibility of calculating and visualizing health risk estimates from exposure to groundwater
contaminated with arsenic (As) using data from national geochemical databases. The potential health risk associated with As-contaminated
groundwater was assessed based on an elaboration of existing geochemical data in accordance with accepted methodological procedures
established for human health risk assessment (U.S. Environmental Protection Agency methodology). A screening analysis approach
was used for estimating the contribution of As to the total chronic health risk from exposure to groundwater contaminated
with potentially toxic elements, including As, Ba, Cd, Cu, Hg, Pb, Sb, Se and Zn, and the results indicate that As contributes
significantly (>50%) to this total health chronic risk in about 10% of Slovak territory. Based on the calculation of the
potential risk level by exposure modelling, increased chronic as well as carcinogenic risk levels (medium to high) were documented
in approximately 0.2 and 11% of the total Slovak area, respectively. The areas characterized by high health risk levels are
mainly those geogenically contaminated. High and very high carcinogenic risk was determined in 34 of 79 districts and in 528
of 2924 municipalities. 相似文献
74.
双道原子荧光同时测定海水中痕量砷和汞 总被引:5,自引:0,他引:5
沈志群 《环境监测管理与技术》2005,17(6):30-31
建立了双道原子荧光同时测定海水中痕量砷和汞的方法。在试验条件下,砷和汞测定的相对标准偏差≤4.0%.加标回收率在92.0%~104%之间。方法操作简便,灵敏快速,适用于海水及其他水体中砷和汞的测定。 相似文献
75.
76.
臭氧对有机物混凝的影响 总被引:5,自引:2,他引:3
采用PDA(Photometric Disperse Analysis)和有机物表观分子量分级、有机物化学极性分级技术从絮体形成过程、絮体表现、有机物分子水平变化等方面研究了臭氧预氧化对混凝过程的影响;并对比了不同混凝剂在预臭氧条件下的混凝过程和效率.结果表明:臭氧预氧化对混凝过程有复杂的影响,其剂量和水体有机物特征决定了其对混凝的整体影响效果.有机物分级显示,臭氧化对有机物结构有重要影响,导致有机物极性、亲水性组分含量大幅提高(36.7%),小分子量组分(<10×103)大幅增高(100%左右);但总的DOC去除率不高(3.28%).对PACl而言,在中、低剂量(O3/TOC<0.7)下,臭氧对絮体形成过程影响较小,但对絮体沉降性和浊度去除已经有阻碍作用.在中、高剂量下(O3/TOC>0.7),对絮体形成有显著滞后,浊度、有机物去除效率下降.AlCl3对臭氧化作用反应敏感,臭氧化在试验剂量条件下,对絮体形成和浊度、有机物去除都有明显的阻碍作用. 相似文献
77.
78.
Dietary uptake is the major way that inorganic arsenic (iAs) enters into benthic fish; however, the metabolic process of dietborne iAs in fish muscle following chronic exposure remains unclear. This was a 40-day study on chronic dietborne iAs [arsenite (AsIII) and arsenate (AsV)] exposure in the benthic freshwater food fish, the crucian carp (Carassius auratus), which determined the temporal profiles of iAs metabolism and toxicokinetics during exposure. We found that an adaptive response occurred in the fish body after iAs dietary exposure, which was associated with decreased As accumulation and increased As transformation into a non-toxic As form (arsenobetaine). The bioavailability of dietary AsIII was lower than that of AsV, probably because AsIII has a lower ability to pass through fish tissues. Dietary AsV exhibited a high potential for transformation into AsIII species, which then accumulated in fish muscle. The largely produced AsIII considered more toxic at the earlier stage of AsV exposure should attract sufficient attention to human exposure assessment. Therefore, the pristine As species and exposure duration had significant effects on As bioaccumulation and biotransformation in fish. The behavior determined for dietborne arsenic in food fish is crucial for not only arsenic ecotoxicology but also food safety. 相似文献
79.
Arsenic contamination and potential health risk implications at an abandoned tungsten mine, southern China 总被引:3,自引:0,他引:3
Chuan-ping Liu Chun-ling Luo Fang-bai Li Lan-wen Lin Xiang-dong Li 《Environmental pollution (Barking, Essex : 1987)》2010,158(3):820-826
In an extensive environmental study, field samples, including soil, water, rice, vegetable, fish, human hair and urine, were collected at an abandoned tungsten mine in Shantou City, southern China. Results showed that arsenic (As) concentration in agricultural soils ranged from 3.5 to 935 mg kg−1 with the mean value of 129 mg kg−1. In addition, As concentration reached up to 325 μg L−1 in the groundwater, and the maximum As concentration in local food were 1.09, 2.38 and 0.60 mg kg−1 for brown rice, vegetable and fish samples, respectively, suggesting the local water resource and food have been severely contaminated with As. Health impact monitoring data revealed that As concentrations in hair and urine samples were up to 2.92 mg kg−1 and 164 μg L−1, respectively, indicating a potential health risk among the local residents. Effective measurements should be implemented to protect the local community from the As contamination in the environment. 相似文献
80.
Yuki Sakai Toshihiro Watanabe Jun Wasaki Takuro Shinano 《Environmental pollution (Barking, Essex : 1987)》2010,158(12):3663-3669
The roles of low-molecular-weight thiols (LMWTs), such as glutathione and phytochelatins, in arsenic (As) tolerance and hyperaccumulation in Pteris vittata an As-hyperaccumulator fern remain to be better understood. This study aimed to thoroughly characterize LMWT synthesis in P. vittata to understand the roles played by LMWTs in As tolerance and hyperaccumulation. LMWT synthesis in P. vittata was induced directly by As, and not by As-mediated oxidative stress. Expression of PvECS2, one of the putative genes of γ-glutamylcysteine synthetase (γECS), increases in P. vittata shoots at 48 h after the onset of As exposure, almost corresponding to the increase in the concentrations of γ-glutamylcysteine and glutathione. Furthermore, localization of As showed similar trends to those of LMWTs in fronds at both whole-frond and cellular levels. This study thus indicates the specific contribution of LMWTs to As tolerance in P. vittata. γECS may be responsible for the As-induced enhancement of LMWT synthesis. 相似文献