Levels of polybrominated diphenyl ethers and hexabromocyclododecane in the atmosphere and tree bark from Beijing, China

Air samples in four seasons at one site and tree bark samples from four districts were determined to investigate seasonal variation and regional distribution of polybrominated diphenyl ethers (PBDEs) and hexabromocyclododecane (HBCD) in Beijing, China. The total concentrations of PBDEs (∑PBDE) and HBCD (∑HBCD) were in the range of 57-470 and 20-1800 pg m⁻³ in the atmosphere, respectively. The ∑PBDE and ∑HBCD concentrations were significantly influenced by the total suspended particulate matter in atmosphere. The total concentrations of PBDEs and HBCD in tree bark samples were in the range of 99-3700 and 26-3400 ng g⁻¹ lipid weight. It was found that regional distribution of PBDEs and HBCD was related to the function of each district. In addition, the study found that weeping willow bark was an ideal atmospheric PBDEs and HBCD passive sampler. Finally, atmospheric levels of BDE-209 and HBCD at tree bark sampling districts were estimated via applying an established bark/air partitioning model, which had been verified by the measured concentrations in tree bark and atmosphere in Beijing.     

广安市大气环境质量现状评价与优化布点监测

采用网格布点法对广安市城区大气环境质量进行了第一次普查监测，利用模糊综合评判法做出简易的现状评价，并评选出了一组优化点位作为日后大气自动化监测点位。     

TOPSIS法在大气环境质量评价中的应用

应用多目标决策中的TOPSIS法(即逼近于理想解的排序方法)对湖南长沙等十城市的大气环境质量进行评价,并与欧几里德贴近度法和上海指数法相比较,认为该评价方法对比较多个城市(或多个监测点,下同)的大气环境质量的优劣,比欧几里德贴近度法和上海指数法均优越.     

H2O2 formation from photocatalytic processes at the ZnO/water interface

The paper focuses on the production of H2O2 by photocatalysis over ZnO in an aerated aqueous phase. The presence of different reductants that increase the H2O2 production in the aqueous phase is analysed; particular attention is paid to nitrite, which has been shown to be the reductant that produces the most significant increments in the H2O2 production. The photocatalytic anodic decomposition of ZnO in the presence of the different reductants is also investigated. From the results obtained, the relevance of the ZnO photocatalysis in the formation of environmental hydrogen peroxide is estimated.     

通州市大气质量监测点数的设置

用比对方式分析拟设监测点和已设监测点的大气中SO2，NOx和TSP，得出拟设监测点和已设监测点的年日均值的相对偏差小于15％，并用F检验法和t检验法对已设监测点5年的大气监测结果进行方差和显著性差异检验，结果表明通州市环境监测站提出的拟在监测站设置1个空气自动监测点取代原有的两个监测点的想法是可行的。     

Hydroxyl, hydroperoxyl free radicals determination methods in atmosphere and troposphere

The hydroxyl radical (?OH) has a crucial function in the oxidation and removal of many atmospheric compounds that are harmful to health. Nevertheless, high reactivity, low atmospheric abundance, determination of hydroxyl, and hydroperoxyl radical's quantity is very difficult. In the atmosphere and troposphere, hydroperoxyl radicals (HO₂) are closely demanded in the chemical oxidation of the troposphere. But advances in technology have allowed researchers to improve the determination methods on the research of free radicals through some spectroscopic techniques. So far, several methods such as laser-induced fluorescence (LIF), high-performance liquid chromatography (HPLC), and chemical ionization mass spectroscopy have been identified and mostly used in determining the quantity of hydroxyl and hydroperoxyl radicals. In this systematic review, we have advised the use of scavenger as an advance for further researchers to circumvent some of these problems caused by free radicals. The primary goal of this review is to deepen our understanding of the functions of the most critical free radical (?OH, HO₂) and also understand the currently used methods to quantify them in the atmosphere and troposphere.     

大气监测网络通信系统设计与实现

根据监测网络通信的特点,设计了大气监测网络通信体系,并在系统中引入了学习算法和缓存机制,有效地提高了大气监测网络通信系统的灵活性和效率。     

上海大气环境的二氧化硫削减战略研究

从上海环境保护总目标和国家实施污染排放总量控制要求的角度,分析了上海在未来发展中对能源的需求和由此所可能带来的大气环境问题。提出了要从根本上提高大气环境质量,必须实施二氧化硫削减的战略,其中包括加快能源结构的调整和改善,实施燃煤脱硫和工业合理布局相结合的重大措施,采取法律、政策、行政和经济手段,对本市二氧化硫污染进行严格地控制,力争到2010年大气环境质量得到根本改善。     

江苏苏南地区大气环境质量变化分析及污染防治对策

通过对江苏省苏南地区大气环境中主要污染因子二氧化硫、二氧化氮及可吸入颗粒物2009年及2005～2009五年来变化情况及原因进行分析,提出污染控制对策和治理措施。