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41.
42.
《环境科学学报(英文版)》2023,35(3):319-331
Oxidation-absorption technology is a key step for NOx removal from low-temperature gas. Under the condition of low O3 concentration (O3/NO molar ratio = 0.6), F-TiO2 (F-TiO2), which is cheap and environmentally friendly, has been prepared as ozonation catalysts for NO oxidation. Catalytic activity tests performed at 120°C showed that the NO oxidation efficiency of F-TiO2 samples was higher than that of TiO2 (about 43.7%), and the NO oxidation efficiency of F-TiO2-0.15 was the highest, which was 65.3%. Combined with physicochemical characteristics of catalysts and the analysis of active species, it was found that there was a synergistic effect between F sites and oxygen vacancies on F-TiO2, which could accelerate the transformation of monomolecular O3 into multi-molecule singlet oxygen (1O2), thus promoting the selective oxidation of NO to NO2. The oxidation reaction of NO on F-TiO2-0.15 follows the Eley-Rideal mechanism, that is, gaseous NO reacts with adsorbed O3 and finally form NO2. 相似文献
43.
呼和浩特市大气中酞酸酯的初步研究 总被引:8,自引:0,他引:8
通过对呼和浩特市不同功能区和不同季度的大气中酞酸酯污染物的采样监测调查,证实了酞酯不仅存在于大气中,且浓度比较高,为531ng/m^3,是草原地区背景值(10-33ng/m^3)的16倍以上。根据调查表明,不同功能区中大气中酞酸酯(DNBP和DEHP)的浓度差异较大;相同功能区的不同季节,酞酸酯浓度也存在较大差异,但酞酸酯浓度与大气颗粒物呈现出良好的相关性,冬、夏季的相关系数分别为0.971和0. 相似文献
44.
45.
《环境科学学报(英文版)》2023,35(3):309-318
Accurate quantification of dissolved organic nitrogen (DON) has been a challenge due to the cumulative analytical errors in the conventional method via subtracting dissolved inorganic nitrogen species (DIN) from total dissolved nitrogen (TDN). Size exclusion chromatography coupled with an organic nitrogen detector (SEC-OND) has been developed as a direct method for quantification and characterization of DON. However, the applications of SEC-OND method still subject to poor separations between DON and DIN species and unsatisfied N recoveries of macromolecules. In this study, we packed a series of SEC columns with different lengths and resin materials for separation of different N species and designed an independent vacuum ultraviolet (VUV) oxidation device for complete oxidation converting N species to nitrate. To guarantee sufficient N recoveries, the operation conditions were optimized as oxidation time ≥ 30 min, injection mass (sample concentration × injection volume) < 1000 µL × mg-N/L for macromolecular proteins, and neutral pH mobile eluent. The dissolved O2 concentration in SEC mobile phase determined the upper limit of VUV oxidation at a specific oxidation time. Compared to conventional HW50S column (20 × 250 mm), HW40S column (20 × 350 mm) with mobile phase comprising of 1.5 g/L Na2HPO4·2H2O + 2.5 g/L KH2PO4 (pH = 6.85) could achieve a better separation of DON, nitrite, nitrate, and ammonia. When applied to river water, lake water, wastewater effluent, groundwater, and landfill leachate, the SEC-OND method could quantify DON as well as DIN species accurately and conveniently even the DIN/TDN ratio reached 0.98. 相似文献
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47.
降低油品储运损耗 改善大气环境 总被引:4,自引:0,他引:4
从石油开采到成品油进入清费的过程中,损耗量约占原油量的3%-5%,其中储运过程中的损耗占总耗的40%-50%,着重论述了油品储运过程中降低损耗的措施,以减少经济损失和对环境的破坏。 相似文献
48.
《环境科学学报(英文版)》2023,35(3):831-842
This study represents the first quantitative evaluation of pollution transport budget within the boundary layer of typical cities in the Beijing-Tianjin-Hebei (BTH) region from the perspective of horizontal and vertical exchanges and further discusses the impact of the atmospheric boundary layer (ABL)-free troposphere (FT) exchange on concentration of fine particulate matter (PM2.5) within the ABL during heavy pollution. From the perspective of the transport flux balance relationship, differences in pollution transport characteristics between the two cities is mainly reflected in the ABL-FT exchange effect. The FT mainly flowed into the ABL in BJ, while in SJZ, the outflow from the ABL to the FT was more intense. Combined with an analysis of vertical wind profile distribution, BJ was found to be more susceptible to the influence of northwest cold high prevailing in winter, while sinking of strong cold air allowed the FT flowing into the ABL influence the vertical exchange over BJ. In addition, we selected a typical pollution event for targeted analysis to understand mechanistic details of the influence of ABL-FT exchange on the pollution event. These results showed that ABL-FT interaction played an important role in PM2.5 concentration within the ABL during heavy pollution. Especially in the early stage of heavy pollution, FT transport contributed as much as 82.74% of PM2.5 within the ABL. These findings are significant for improving our understanding of pollution transport characteristics within the boundary layer and the effect of ABL-FT exchange on air quality. 相似文献
49.
循环流化床锅炉对环境保护的意义 总被引:1,自引:0,他引:1
五明光 《石油化工环境保护》2000,(2):29-33
重点论述循环流化床锅炉对环境保护的特殊贡献。阐述了我国大气污染现状及防治对策 ;循环流化床锅炉工作原理及主要特点 ;循环流化床锅炉脱硫机理 ;循环流化床锅炉降低 NOX排放的机理等问题。 相似文献
50.
大气功能区划分的模糊综合评价法 总被引:3,自引:0,他引:3
文章分析了大气环境功能区的重要作用以及目前功能分区方法中存在的问题,探讨了功能分区中正确考虑风的向影响的原则,剖析了模糊数学理论进行了功能分区的必要性。最后,提出了综合考虑社会功能,气候地理特征及环境现状的定量划分功能区的模糊综合评价法,阐述了这一方法的具体步骤,并将之应用于一案例中。 相似文献