1,2,4,5-四氯苯 C 18 Empore TM 膜/水分配系数的研究

研究了1,2,4,5-四氯苯在C18膜／水相之间的分配规律。1,2,4,5-四氯苯在：25℃,80r／min条件下恒温震荡96h可达分配平衡,温度和盐度对1,2,4,5-四氯苯C18膜／水的分配过程影响很小,1,2,4,5-四氯苯C18膜／水分配平衡时间受溶液体积和容器容积的影响,但不受溶液中C18膜膜量的影响,推测脂溶性小于或接近1,2,4,5-四氯苯的有机污染物在恒温震荡条件下C18膜与水之间的分配96h可达到平衡。     

Modeling Stream Shade: Riparian Buffer Height and Density as Important as Buffer Width1

DeWalle, David R., 2010. Modeling Stream Shade: Riparian Buffer Height and Density as Important as Buffer Width. Journal of the American Water Resources Association (JAWRA) 46(2):323-333. DOI: 10.1111/j.1752-1688.2010.00423.x Abstract: A theoretical model was developed to explore impacts of varying buffer zone characteristics on shading of small streams using a path-length form of Beer’s law to represent the transmission of direct beam solar radiation through vegetation. Impacts of varying buffer zone height, width, and radiation extinction coefficients (surrogate for buffer density) on shading were determined for E-W and N-S stream azimuths in infinitely long stream sections at 40°N on the summer solstice. Increases in buffer width produced little additional shading beyond buffer widths of 6-7 m for E-W streams due to shifts in solar beam pathway from the sides to the tops of the buffers. Buffers on the north bank of E-W streams produced 30% of daily shade, while the south-bank buffer produced 70% of total daily shade. For N-S streams an optimum buffer width was less-clearly defined, but a buffer width of about 18-20 m produced about 85-90% of total predicted shade. The model results supported past field studies showing buffer widths of 9-11 m were sufficient for stream temperature control. Regardless of stream azimuth, increases in buffer height and extinction coefficient (buffer density) were found to substantially increase shading up to the maximum tree height and stand density likely encountered in the field. Model results suggest that at least 80% shade on small streams up to 6-m wide can be achieved in mid-latitudes with relatively narrow 12-m wide buffers, regardless of stream azimuth, as long as buffers are tall (≈30 m) and dense (leaf area index ≈6). Although wide buffers may be preferred to provide other benefits, results suggest that increasing buffer widths beyond about 12 m will have a limited effect on stream shade at mid-latitudes and that greater emphasis should be placed on the creation of dense, tall buffers to maximize stream shading.     

粉煤灰固结技术及应用研究

为防治火电厂贮灰场扬尘污染对粉煤灰固技术进行了试验研究。目前已研制出２个系列的粉煤灰固结剂,固结后的抗压强度都在１６ｋｇ／ｃｍ２以上,最高达７０ｋｇ／ｃｍ２;水稳系数和冻稳系数都在０．９０—１．００。该项技术具有抑尘效果好、保持时间长、治理成本低、原料来源广泛、施工工艺简单和易于推广等待点。它可用于正在使用的灰场（包括中转灰场、碾压灰场）和贮满灰的灰场治理扬尘,还可用于灰场防渗和灰坝加固。     

矿区生态系统健康现状模糊综合评价方法

详细提出矿区生态系统健康现状模糊综合评价方法:首先建立矿区生态系统健康综合评价指标体系;其次用层次分析法(AHP)确定指标的权重系数,并利用熵技术对权重系数进行修正;然后计算评价指标隶属度,并采用3层次模糊综合评价方法进行评价;最后,根据实际需要采用最大隶属度法或分值法对评价结果进行处理。该评价方法首次采用层次分析法和熵技术来确定评价指标的权重系数,首次采用最大隶属度法或分值法对评价结果进行处理,为矿区生态系统健康现状定量评价提供了基础。该方法仍需进一步结合矿区的实际情况,对评价指标、一些指标的权重等进一步完善,以期推广应用。     

Parameters affecting partitioning of 6 PCB congeners in natural sediments

Polychlorinated biphenyls (PCBs) released by bottom sediments were determined by experiments in which the sediments were artificially resuspended using sediment contaminated with PCBs in a particle entrainment simulator (PES). Sediment cores, spikedwith PCBs, were collected from the Housatonic River in Connecticut and run in the PES at simulated shear stresses from 0 to 0.6 N m^-2. Experimental results from these simulations have shown that mean concentration of PCBs in thesolid phase for sites with high volatile organic carbon (VOC) were significantly greater than samples with low VOC; the reversewas true for the water phase. In addition, on a mass load basis,the amount of PCBs found in sediment increased when shear stresses were increased from 0 to 0.6 N m^-2, beyond which shear stress did not affect mass loads in the watercolumn. Partition coefficients (K _p) were determined from PESsediment and water data for the following congeners: PCB 28, PCB 52, PCB 101, PCB 138, PCB 153, PCB 180. K _p was determined to be inversely proportional to total suspended solids (TSS), butdirectly proportional to chlorine content of the congener. Because of the strong influence of TSS and VOC concentrations onK _p values, agitation of samples using a PES better simulatedreal environmental conditions when compared to jar studies where no agitation was employed. Therefore, a device like the PES is more appropriate in obtaining K _p that would be found underreal stream flow conditions when compared to the traditionalway of measuring K _p using the jar study technique.     

重庆地铁岩石隧道环境振动衰减规律

本文研究了重庆地铁岩石隧道环境振动衰减规律，并预测了重庆地铁振动的影响范围和程度。     

Heterogeneous uptake of NO2 on soils under variable temperature and relative humidity conditions

Heterogeneous reactions of nitrogen dioxide (NO₂) on soils collected from Dalian (S1) and Changsha (S2) were investigated over the relative humidity (RH) range of 5%-80% and temperature range of 278-328 K using a horizontal coated-wall flow tube. The initial uptake coefficients of NO₂ on S2 exhibited a decreasing trend from (10 ± 1.3) × 10^-8 to (3.1 ± 0.5) × 10^-8 with the relative humidity increasing from 5% to 80%. In the temperature effect studies, the initial uptake coefficients of S1 and S2 decreased from (10 ± 1.2) × 10^-8 to (3.8 ± 0.5) × 10^-8 and from (16 ± 2.2) × 10^-8 to (3.8 ± 0.4) × 10^-8 when temperature increased from 278 to 288 K for S1 and from 278 to 308 K for S2, respectively. As the temperature continued to increase, the initial uptake coefficients of S1 and S2 returned to (7.9 ± 1.1) × 10^-8 and (20 ± 3.1) × 10^-8 at 313 and 328 K, respectively. This study shows that relative humidity could influence the uptake kinetics of NO₂ on soil and temperature would impact the heterogeneous chemistry of NO₂.     

Numerical simulations on the attenuation effect of a barrier material on a blast wave

This paper numerically modeled previous experimental results and quantitatively revealed the attenuation effect of a barrier material on a blast wave. Four fluids were considered in the present study: the detonation products, water, foamed polystyrene, and air. These fluids were modeled by Jones-Wilkins-Lee (JWL), stiffened gas, and ideal gas equations of state. A mixture of water and foamed polystyrene was used as a barrier to encircle a 0.1 kg mass of spherical pentolite, and the interface problem between the barrier and the blast wave was investigated. The simulation parameters were the radius and the water volume fraction of the barrier. To elucidate the effect of the barrier, we conducted two series of numerical simulations; one without a barrier, and another with a barrier of 50 or 100 mm in outer radius and 0–1 in the water volume fraction. Peak overpressure, positive impulse, and pressure history all agreed well with the previous experimental results. We focused on the energy transfer from high-pressure detonation products to other fluids. The sum of the kinetic energies of the detonation products and the barrier induced by the blast wave could quantitatively estimate the attenuation effect of the blast wave and was minimized when the water volume fraction was 0.5, as was the case in the previous experiment.     

Taking advantage of storm and waste water retention basins as part of water use minimization in industrial sites

A methodology for water use minimization has been developed by the Clean Technology Network of Bahia over a 10 year period in joint cooperative programs with the chemical, petrochemical and copper metallurgy industries located in the largest Industrial Complex in Latin America, in Camaçari, Bahia, Brazil. The methodology comprises a set of tools including reconciled aqueous stream balances, database of aqueous streams; large scale training leading to the identification of water minimization alternatives in the processes, water reuse optimization approaches; geographical information systems as well as, consideration of the region's hydro and hydro-geological characteristics. The results of a study carried out to assess the possibility of using storm and wastewaters for industrial use is presented in this paper. The inorganic system is composed by three water reservoirs (basins) receiving stormwater contaminated with inorganic effluents, and occasionally with organics. These basins have been operated to control water flow inputs according to the capacity of the pumping outlet systems before their discharge to a submarine outfall. A mass balance was performed with historical updated data to assess water availability from the basins based on the daily volume variation and flow rate of inorganic effluent from 2001 to 2007. The study identified the possibility of recovering about 1140 m³/h of the overall 5400 m³/h consumed by the Industrial Complex at the moment. Organizational changes in the present effluent disposal and stormwater harvest systems will be required in order to maximize water recovery for industrial use.     

Radionuclides in the Ecosystem of Lake Tygish in the Zone of the Eastern Ural Radioactive Trace

The radioecological situation in Lake Tygish is described. The lake is situated on the central axis of the Eastern Ural Radioactive Trace (EURT), which was formed after the nuclear accident in the Southern Urals in 1957. The distributions of ⁹⁰Sr and ¹³⁷Cs among the main components of the water body and the results of the measurement of tritium concentration in the water are presented. Mathematical models are described that have made it possible to estimate changes in the concentrations of radionuclides and their amounts accumulated in the water and bottom sediments of the lake during the long period after the accident and to predict the development of the radioecological situation in the lake until 2057. Based on the mathematical models, more accurate data on the initial ecological situation in the lake in the year of the accident have been obtained.