电凝聚处理轧制乳化废水的研究

用电凝聚法处理轧制乳化废水,探讨了影响破乳的各种因素,确定了最佳处理条件。研究结果表明:该法处理轧制乳化废水的效果很好,浊度去除率可达99.6%,COD去除率达99.5%。此外,还发现电凝聚法的处理效果优于药剂絮凝法。     

三峡库区小城镇水环境与工业产业结构优化模型——以万州区分水镇为例

以长江上游三峡库区腹部的重庆市万州区分水镇为研究对象,根据2005年分水镇工业各行业的结构特点及各行业对水环境的污染特点,建立水环境--经济工业结构多目标优化模型,选取工业生产总值最大和COD排放量最小作为优化目标,量化分水镇2010年工业结构,选择出符合当地经济发展"十一五"规划目标和水环境保护目标的工业结构优化方案,提出具体的工业产业发展建议,达到减少工业污染物对境内长江次级河流瀼渡河的污染,有效地改善瀼渡河水质状况,同时保证分水镇社会、经济、水环境的可持续发展的目的.文章同时也对三峡库区小城镇的工业产业结构优化调整,获得既符合经济发展目标又满足水环境保护要求的合理的工业产业结构,提供可借鉴的思路和方法.     

壳聚糖/PVA微粒上Cu2+的吸附平衡与动力学

采用粒径＜200μm、在酸碱介质中溶胀率小且能稳定存在的壳聚糖/PVA微粒对Cu2+的吸附进行了研究,结果表明,在pH 6,室温条件下,其饱合吸附量达56.0mg/g,随温度升高,吸附量降低.通过计算不同温度下各热力学参数△G0、△H0和△S0,证实该吸附为自发的放热过程.对实验数据运用相关数学模型拟合,显示等温吸附平衡符合Langmuir模型,吸附过程动力学更适合二级反应,被吸附在壳聚糖/PVA微粒上的Cu2+,可被0.01mo/L的EDTS或HNO3溶液快速地脱附出来,其洗脱率分别为85.3%和65.9%.     

MAGIC模型及其应用进展

介绍MAGIC模型及其在预测土壤和地表水酸化趋势及确定酸沉降临界负荷中的应用,提出了该模型的应用展望。     

山仔水库周边乡镇生态质量未确知测度评价

通过建立未确知模型,结合层次分析法确定权重,对福州由仔水库周边有人类聚居点的小沧乡、潘度乡、飞竹乡、霍口乡和日溪乡的生态环境质量做出了评价。得出了它们的生态环境质量均为四级,属较差水平。而在积分上,霍口乡的环境质量最好,潘度乡最差。     

Effects of acid,acid-ZVI/PMS,Fe(Ⅱ)/PMS and ZVI/PMS conditioning on the wastewater activated sludge(WAS)dewaterability and extracellular polymeric substances(EPS)

The effects of four conditioning approaches:Acid,Acid-zero-valent iron(ZVI)/peroxydisulfate(PMS),Fe(Ⅱ)/PMS and ZVI/PMS,on wastewater activated sludge(WAS) dewatering and organics distribution in supernatant and extracellular polymeric substances(EPS) layers were investigated.The highest reduction in bound water and the most WAS destruction was achieved by Acid-ZVI/PMS,and the optimum conditions were pH 3,ZVI dosage 0.15 g/g dry solid(DS),oxone dosage 0.07 g/g DS and reaction time 10.6 min with the reductions in capillary suction time(CST) and water content(Wc) as 19.67% and 8.49%,respectively.Four conditioning approaches could result in TOC increase in EPS layers and supernatant,and protein(PN) content in tightly bound EPS(TB-EPS).After conditioning,organics in EPS layers could migrate to supernatant.Polysaccharide(PS) was easier to migrate to supernatant than PN.In addition,Acid,Acid-ZVI/PMS or Fe(Ⅱ)/PMS conditioning promoted the release of some polysaccharides containing ring vibrations v P=O,v C-O-C,v C-O-P functional groups from TB-EPS.ESR spectra proved that both radicals of SO_4~-· and·OH contributed to dewatering and organics transformation and migration.CST value of WAS positively correlated with the ratios of PN/PS in LB-EPS and total EPS,while it negatively correlated with TOC,PN content and PS content in TB-EPS,as well as PS content in supernatant and LB-EPS.BWC negatively correlated to zeta potential and TOC value,PN content,and HA content in supernatant.     

Enhanced activity of ZnS(111) by N/Cu co-doping:Accelerated degradation of organic pollutants under visible light

High-efficiency photocatalysts are of great significance for the application of photocatalytic technology in water treatment.In this study,N/Cu co-doped ZnS nanosphere photocatalys(N/Cu-ZnS) is synthesized by a hydrothermal method for the first time.After doping,the tex ture of nanosphere becomes loose,the nanometer diameter is reduced,making the specific surface area of catalyst increased from 34.73 to 101.59 m²/g.The characterization results show that more ZnS (111) crystal planes a...     

一株硝基苯高效降解菌的筛选及其降解特性

自南京化工厂下水道底泥和废水处理系统曝气池活性污泥中驯化分离得到一株能快速降解硝基苯的菌株,初步鉴定其为不动杆菌属菌株。该菌株降解硝基苯的最适宜环境条件为温度25℃～35℃,pH7～8,振荡速率大于120r/m。在适宜环境条件下,该菌株能够在24h内全部降解初始浓度不超过400mg/L的硝基苯,该浓度范围内硝基苯的降解过程符合零级动力学特征;当硝基苯的初始浓度超过400mg/L时,降解菌的生长受到毒害作用,该浓度范围内硝基苯的降解在开始有一个明显的停滞期,降解过程不再符合零级或一级动力学特征。     

PVC包装材料中酞酸酯增塑剂残留的ASE-GC-MS分析

针对PVC包装材料中酞酸酯（PAEs）增塑剂残留，采用加速溶剂萃取（ASE）和GC／MS联用技术分析5种PAEs（DMP，DEP，DBP，BBP，DEHP），结果表明加速溶剂萃取用于PVC包装材料中PAEs的提取，最佳温度条件为120℃，最佳循环次数为3次。方法检出限达到0．1mg／kg，回收率达到95．5％-99．8％；并且具有很好的重现性和精密度。     

黑龙江省森林资源动态变化与发展趋势预测

以黑龙江省2004年统计年鉴的统计数据为依据,分析了全省森林资源现状的特点,并以近50多年来森林资源清查数据为基础,对森林资源主要项目的动态变化进行了客观的分析,力求寻找变化的原因.通过建立灰色预测GM(1.1)模型,预测未来时期森林资源发展趋势,提出了相应对策,以期实现科学经营森林以及森林资源的可持续发展.