环境管理手段体系研究

社会经济的快速发展和环境保护的日趋重要,要求环境保护与社会经济协调发展。科学有效地应用环境管理手段,是促进协调发展的有效途径之一。为了促进环境管理手段作用的有效发挥,完善环境管理,在分析现有的5种环境管理手段的基础上,提出了环境管理参与手段和环境管理投资手段,并对这两个新的手段的必要性和内容做了分析。通过对环境管理手段关系的论述,构建了环境管理手段体系,对环境管理手段体系的目标、架构、作用和内容进行了分析论述,并研究了环境管理手段的选择与实施方法。     

腐殖酸对土壤挥发汞植物有效性的影响研究

土壤挥发汞对植物是非常有效的,并能通过食物链威胁人体健康,因此,本试验设计了“密闭箱的水培试验”定量研究了腐殖酸及其组份对土壤挥发汞生物活性的影响,结果发现：腐殖酸能有效地抑制土壤汞的挥发,降低植株对土壤挥发汞的吸收,其作用机理在于土壤挥发汞的形态转化,通过对转化条件的调节,可以达到控制土壤挥发汞向食物的链转移的目的。     

Application of a luminescence-based biosensor for assessing naphthalene biodegradation in soils from a manufactured gas plant

Despite numerous reviews suggesting that microbial biosensors could be used in many environmental applications, in reality they have failed to be used for which they were designed. In part this is because most of these sensors perform in an aqueous phase and a buffered medium, which is in contrast to the nature of genuine environmental systems. In this study, a range of non-exhaustive extraction techniques (NEETs) were assessed for (i) compatibility with a naphthalene responsive biosensor and (ii) correlation with naphthalene biodegradation. The NEETs removed a portion of the total soil naphthalene in the order of methanol > HPCD > βCD > water. To place the biosensor performance to NEETs in context, a biodegradation experiment was carried out using historically contaminated soils. By coupling the HPCD extraction with the biosensor, it was possible to assess the fraction of the naphthalene capable of undergoing microbial degradation in soil.     

EDTA and HCl leaching of calcareous and acidic soils polluted with potentially toxic metals: remediation efficiency and soil impact

The environmental risk of potentially toxic metals (PTMs) in soil can be diminished by their removal. Among the available remediation techniques, soil leaching with various solutions is one of the most effective but data about the impact on soil chemical and biological properties are still scarce. We studied the effect of two common leaching agents, hydrochloric acid (HCl) and a chelating agent (EDTA) on Pb, Zn, Cd removal and accessibility and on physico-chemical and biological properties in one calcareous, pH neutral soil and one non-calcareous acidic soil. EDTA was a more efficient leachant compared to HCl: up to 133-times lower chelant concentration was needed for the same percentage (35%) of Pb removal. EDTA and HCl concentrations with similar PTM removal efficiency decreased PTM accessibility in both soils but had different impacts on soil properties. As expected, HCl significantly dissolved carbonates from calcareous soil, while EDTA leaching increased the pH of the acidic soil. Enzyme activity assays showed that leaching with HCl had a distinctly negative impact on soil microbial and enzyme activity, while leaching with EDTA had less impact. Our results emphasize the importance of considering the ecological impact of remediation processes on soil in addition to the capacity for PTM removal.     

Interrelation of Cd‐lon concentrations and the growth and activities of microorganisms in two growth media†

Partitioning of native or anthropogenic heavy metals in solid and solution phases of soil is a result of network of several physico‐chemical reactions. The attainment of equilibrium between two phases is also regulated by biochemical processes. For practical purposes, the bioavailability of metal present in soil is predominantly regulated by the soil solution phase which is in dynamic equilibrium with the solid phase. The results of a model laboratory and greenhouse growth experiments have been used to investigate the effect of Cd‐ion concentrations (either in soil solution or in nutrient solution) on the growth and activities of microorganisms. The soil solution has been simulated by preparing a suspension of soil with 0.1 M NaNO₃ (1: 2.5) equilibrated for two hours. Important conclusions are as follows:

Increase in Cd‐ion concentration in soil solution or in nutrient solution induces corresponding adverse effect on the growth and activities of microorganisms. Thus, it seems that Cd‐ion concentration is a more sensitive indicator for assessing the effect of metal pollution upon the growth and activities of soil microorganisms in comparison to total Cd contents.

During active microbial growth phase, a large part of the organically bound Cd was released in the soil solution which is largely bioavailable. This process is termed as mobilisation. There was momentary increase of Cd‐ion concentration in soil solution which intoxicated the growing organisms. After this stage, the Cd ions from the solution phase were removed by the newly formed solid phase (nonviable biomass) and were transformed in non‐available form. This process is termed as immobilisation.

The consequences and importance of these results for practical agriculture and in deciding the limits or guidelines on the maximum tolerable metal load in soils are discussed.     

Metal accumulation risks in regularly flooded and non-flooded parts of floodplains of the River Rhine: Extractability and exposure through the food chain

Ecotoxicological risks of sediment contamination in floodplains are supposed to be highest in the regularly flooded parts. Therefore, in risk assessments, the non-flooded parts are neglected or considered to be reference areas. We investigated the metal extractability and levels in important food sources for vertebrates, viz. grass shoots and earthworms, in flooded as well as non-flooded parts and compared these with total metal concentrations. A comparison of these areas in the moderately polluted ‘Afferdensche en Deestsche Waarden’ floodplains along the River Rhine showed that total Zn, Pb, and Cd concentrations were highest in the regularly flooded parts. However, CaCl₂-extractable Zn concentrations were highest in non-flooded areas, and those of Pb and Cd were equal in both areas. Total Cu concentrations were not significantly different between the two areas, but CaCl₂-extractable Cu concentrations were highest in the regularly flooded areas. The metal concentrations in grass shoots of non-flooded areas were equal to (Zn, Cu, Cd) or higher than (Pb) those in regularly flooded areas. Zn concentrations in earthworms in regularly flooded areas were higher, but concentrations of Cu, Pb, and Cd were not. Ecotoxicological risk assessments require analysis of the total and potentially bioavailable metal concentrations in soils as well as concentrations in biota. This study shows that the less contaminated non-flooded areas in moderately polluted floodplains cannot be neglected in metal accumulation studies and cannot be used as pristine reference areas.     

Heavy metals in Hediste diversicolor (polychaeta: nereididae) and salt marsh sediments from the lagoon of Venice (Italy)

The nereid polychaete Hediste diversicolor was frequently used as biomonitor of heavy metals contamination in estuaries. In the present work, the bioaccumulation of five heavy metals (Cd, Cr, Cu, Mn, Pb) in tissues of H. diversicolor collected from six salt marshes in the lagoon of Venice is studied by analysing the relationships between concentrations of the operationally-defined reactive fraction of trace metals in sediments and total concentrations in tissues. The characterisation of sediment samples shows a clear distinction between sites near and far from the Industrial Zone; no analogous pattern is observed for tissue concentrations suggesting that metal bioaccumulation is controlled by complex interactions between metal bioavailability and physiological factors. Considering relationships between metals, strong inverse correlations are observed in polychaetes and sediments for Cu and Cr concentrations suggesting a possible interaction between these two metals. The role played by organic matter (OM) in the availability of metal is highlighted considering inverse relationships found between bioaccumulation factors for Cu, Cr, Cd and OM.     

Encouraging the application of sustainable timber harvesting practices: A review of policy tool use and effectiveness in the eastern United States

States use a variety of approaches to encourage landowners and loggers to apply ecologically-sustainable timber harvesting practices, the latter generically referred to as timber harvesting guidelines. A survey of 37 state forestry agency administrators in the eastern U.S. (defined as a contiguous region with the northwest and southwest borders being North Dakota and Texas, respectively) was conducted in 2000 to assess the extent and nature of state guideline programs and the various methods by which states encourage their use. The study found states in the eastern U.S. use a variety of policy tools to promote guideline use, with certain policy tools more common for certain target audiences (e.g., loggers) as well as the types of resources (e.g., wildlife habitat) addressed by the guidelines. Eighty-three percent of the programs directed at encouraging forest landowners in the eastern U.S. to use the timber harvesting practices identified in their state guidebooks are technical assistance, educational, or cost-share programs. Technical assistance and education programs are the most common policy tools used to assist loggers in applying sustainable harvesting practices. Technical assistance and cost-share programs consistently rank among the most effective policy tools for encouraging loggers and landowners to apply the guidelines. Comparing the level of program investment to perceived benefits, assistance programs and education programs rank most efficient landowner programs, whereas premium prices for products and preferential access to contracts are the two most efficient programs directed at loggers. The paper concludes with an assessment of emerging trends and additional information needs associated with encouraging the application of sustainable timber harvesting practices.     

Assessing potential bioavailability of metals in sediments: A proposed approach

Due to anthropogenic inputs, elevated concentrations of metals frequently occur in aquatic sediments. In order to make defensible estimates of the potential risk of metals in sediments and/or develop sediment quality criteria for metals, it is essential to identify that fraction of the total metal in the sediments that is bioavailable. Studies with a variety of benthic invertebrates indicate that interstitial (pore) water concentrations of metals correspond very well with the bioavailability of metals in test sediments. Many factors may influence pore water concentrations of metals; however, in anaerobic sediments a key phase controlling partitioning of several cationic metals (cadmium, nickel, lead, zinc, copper) into pore water is acid volatile sulfide (AVS). In this paper, we present an overview of the technical basis for predicting bioavailability of cationic metals to benthic organisms based on pore water metal concentrations and metal-AVS relationships. Included are discussions of the advantages and limitations of metal bioavailability predictions based on these parameters, relative both to site-specific assessments and the development of sediment quality criteria.     

Thermal rehabilitation of Romanian housing: a low cost assessment tool

The numerous buildings that currently require thermal rehabilitation in Romania means that substantial resources and a large number of competent people are required to carry out surveys and energy audits. However, commercial energy balance software is mostly unaffordable for those organisations involved in this process. This paper describes an energy balance programme – ENEFControl – developed to be a rapid, low cost, local tool able to assist in the choice of energy efficient solutions for buildings. To test the software, thermal and energy analyses were carried out on a 1970s built apartment block in Transylvania. Based on these analyses, three constructive scenarios were proposed for thermal rehabilitation. Compared to the performance of the analysed building, the thermal and energy performance of the retrofitted building in all three scenarios significantly improved. Since European Union accession in 2007, rapidly rising energy costs have affected the Romanian population. ENEFControl offers Romanian engineers and architects an opportunity to speed up the rehabilitation programme of buildings without the need for more expensive expertise and tools.