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51.
David D. Cornell 《Journal of Polymers and the Environment》2007,15(4):295-299
The existing plastic bottle reclaiming industry has working technology, satisfied customers, raw material, and investors.
Adding new materials to the current mix requires satisfying all four needs for those materials. Rigid plastic container recycling
focuses on high-density polyethylene (HDPE) and polyethylene terephthalate (PET) bottles, the overwhelming percentage of bottles
sold in North America. Bottles of other resins, including polyvinyl chloride (PVC), polypropylene and biopolymers, lack critical
mass necessary for independent reclamation. To be mechanically recycled, biopolymers must be either completely fungible with
existing recycled resins or be available in sufficient quantity to achieve the needed critical mass. So far, biopolymer volume
projections are not encouraging. Biopolymers, like all minor bottle resins, must pay their own way in sorting and processing
without subsidy from PET and HDPE recycling. Based on limited data, some biopolymers may have little effect on recycled HDPE
performance, but will represent a yields loss and added economic burden at some level of occurrence. Biopolymers have not
been shown to be compatible with PET and likely will represent performance problems and economic burdens at even low levels
of occurrence. Applications for biopolymers should be carefully selected so as to not interfere with currently recycled materials
unless critical mass can be achieved quickly.
相似文献
David D. CornellEmail: |
52.
53.
为改善β-环糊精的水溶性,将β-环糊精和甘氨酸在碱性条件下用环氧氯丙烷连接起来,得到水溶性极好的甘氨酸-β-环糊精,研究了甘氨酸-β-环糊精对菲的增溶、解吸行为,考察了pH、甘氨酸-β-环糊精初始浓度、温度、不同环糊精类型对菲解吸的影响。结果表明,甘氨酸-β-环糊精对菲的增溶效果显著,其初始质量浓度为30 g/L时,对菲的增溶倍数可以达到近30倍;甘氨酸-β-环糊精对菲的解吸随pH的升高而降低;升高甘氨酸-β-环糊精初始浓度和温度有利于菲的解吸;甘氨酸-β-环糊精对菲的解吸好于α-环糊精和β-环糊精,甘氨酸-β-环糊精对菲污染土壤的解吸符合准二级动力学方程。该静态解吸研究可以为菲污染土壤的修复提供基础信息。 相似文献
54.
Margaret J. Sobkowicz John R. Dorgan Keith W. Gneshin Andrew M. Herring J. Thomas McKinnon 《Journal of Polymers and the Environment》2008,16(2):131-140
Nucleation of polylactide and polypropylene using novel renewable resource biobased carbon nanospheres (CNS) is investigated
using differential scanning calorimetry and polarized optical microscopy. Isothermal studies near the optimal crystallization
temperature demonstrate at least a five-fold increase in crystallization rate in PP but only a 1.4 times faster crystallization
in PLA. Non-isothermal studies reveal an asymptotic relationship of the maximum crystallization temperature with increasing
CNS weight loading in PP and no relationship in PLA. Microscopy indicates some aggregation in the solution blended samples
and that average spherulite size is reduced 10-fold due to faster nucleation in the composites as compared to the neat polymer.
The fractional crystallinity achieved during non-isothermal crystallization increases by about 7% with addition of a small
amount of CNS and decreases with weight loading higher than 1%. The crystallization rates obtained in polypropylene are competitive
with widely used mineral talc nucleating agents. 相似文献
55.
Immunoassays are potentially valuable tools for use in screening environmental samples for a broad range of contaminants, such as polychlorinated dibenzo-p-dioxins (PCDDs). The performance of the radioimmunoassay (RIA) for PCDDs was characterized using 4 solubilization systems: Cutscum, Triton, horse serum, and dimethyl sulfoxide (DMSO). The DMSO based assay appeared to perform best at low 2,3,7,8-TCDD levels. The effects of assay incubation time and hapten storage conditions on the DMSO based assay were assessed. The separation of bound from unbound radioactivity was accelerated without adversely affecting assay performance. Further assay development through the use of an alternative labelled hapten is considered. 相似文献
56.
S-TE污泥溶解过程中主要固形物质的变化及动力学分析 总被引:1,自引:0,他引:1
筛选出一株能分泌胞外酶、促进污泥溶解的嗜热脂肪芽孢杆菌Bacillus stearothermophilus sp.AT06-2,将AT06-2培养液接种入不同浓度(TSS约为7、14和21 g·L-1)的剩余污泥,于60℃进行嗜热菌溶解试验,并与未接种试验进行对比.结果表明,接种后TSS和VSS溶解率都得到提高60h后接种试验VSS溶解率分别达到58.76%、50.17%和39.38%,而未接种试验VSS溶解率仅为34.00%、28.63%和25.22%.在固形物质溶解机理方面,VSS的溶解主要受酶催化效应和热水解效应的影响,TSS的溶解减量取决于VSS和FSS的组成比例.VSS溶解在初始阶段(t=3d)符合准一级反应动力学模型,接种后溶解速率常数Kd显著提高,分别从未接种的0.14 d-1,0.10 d-1、0.10 d-1相应提高到接种条件下的0.30 d-1、0.23 d-1和0.16 d-1. 相似文献
57.
表面活性剂对苊的增溶作用及应用初探 总被引:14,自引:2,他引:14
比较研究了阴、阳、非离子表面活性剂及阴 非、阳 非离子混合表面活性剂对苊的增溶作用 .SDS ,CTMAB ,TritonX 1 0 0都能显著地增加苊在水中的溶解度 ,苊在SDS ,CTMAB ,TritonX 1 0 0单体上的分配系数Kmn分别为 1 3 0× 1 0 3,0 92× 1 0 3,1 3 0× 1 0 3,在胶束相的分配系数Kmc分别为 5 6 4× 1 0 3,1 5 0× 1 0 4 ,5 5 7× 1 0 3.阴 非离子混合表面活性剂和一定条件下的阳 非离子混合表面活性剂对苊具有协同增溶作用 ,这是由于混合表面活性剂对苊的胶束分配系数Kmc增大所致 .比较了CTMA 单体态、胶束态、膨润土吸附态对苊分配作用的大小 ,以及苊在表面活性剂单体、胶束和土壤上有机质标化的分配系数Kom的大小 ,为表面活性剂在有机污染环境修复中的应用提供参考 相似文献
58.
59.
表面活性剂增效修复土壤有机污染研究进展 总被引:9,自引:0,他引:9
系统评述了表面活性剂增效修复土壤有机污染的原理、研究现状及存在的问题。 相似文献
60.
表面活性剂去除土壤和地下水中LNAPLs作用机制研究 总被引:5,自引:2,他引:3
去除多孔介质中滞留的LNAPLs,表面活性剂对LNAPLs的增溶和降低界面张力是关键.在实验测得不同浓度Triton X-100溶液对正十六烷的增溶以及它们之间界面张力的基础上,通过平衡清洗实验和砂柱冲洗实验分析了不同形态正十六烷的产生规律和机制.结果表明,正十六烷溶解能力与Triton X-100浓度成正比,当Triton X-100浓度大于临界胶束浓度CMC时,计算得摩尔增溶比MSR=1.680 4,胶束相/水相分配系数对数值lgKmc=1.715 8;正十六烷-Triton X-100溶液之间界面张力与Triton X-100浓度成反比,其变化规律符合高斯模型(R2=0.996 4);溶解态正十六烷和自由态正十六烷与增溶和降低界面张力分别有较好的对应关系,表明增溶和降低界面张力都对多孔介质中正十六烷去除有影响,其中降低界面张力可以有效增加多孔介质中正十六烷的流动性,在正十六烷去除过程中起主要作用. 相似文献