近10年中国三大经济区太阳总辐射特征及其与O3、PM2.5的关系

采用中国地面气象观测站网2007~2016年的辐射日值数据集和中国空气质量在线监测平台2014~2016年逐日观测数据,分析了京津冀、长三角和珠三角近10a太阳总辐射年际和季节变化,近3a臭氧日最大8h平均（O_{3_8h_max}）和细颗粒物（PM_2.5）的污染过程频次变化,通过不同因子及其不同强度等级的分型统计,探讨PM_2.5、O_{3_8h_max}与太阳总辐射的关系.结果表明：京津冀近10a太阳总辐射显著上升,京津冀春季和珠三角夏季太阳总辐射显著上升.三大经济区PM_2.5污染过程年频次均呈现逐年递减,且从北到南递减;O₃污染过程年频次时间上呈现先减后增,空间上京津冀多于长三角和珠三角.三大经济区O_{3_8h_max}与太阳总辐射相关系数均在0.71以上,有较强的正相关;而PM_2.5与太阳总辐射的相关性具有区域差异性.三大经济区不同季节不同太阳总辐射下O_{3_8h_max}与PM_2.5的相关关系差异显著,其中京津冀春夏秋三季O_{3_8h_max}与PM_2.5在强太阳总辐射下有较好的正相关,冬季则存在一定的负相关;长三角四季两者相关性均较弱;珠三角夏季两者正相关最为显著;不同PM_2.5浓度下O_{3_8h_max}与太阳总辐射的线性拟合效果较好,体现出较强的正相关关系,各经济区拟合曲线的倾向率均随PM_2.5升高而增大.PM_2.5>75μg/m³时拟合优度均达到最大.     

牛粪-化肥配施对水稻田氮磷迁移转化的影响

在控制外源N输入量相同的前提下,通过田间小区实验,探讨有机肥与化肥不同施用量（牛粪施用量：5,10,20t/hm²）对稻田田间土-水界面氮磷迁移转化特征的影响.结果表明：控制稻田水中NH₄⁺-N、NO₃^--N、TN和TP输出的最佳时期分别为施肥后的第5,30,7,20d,且TN和TP浓度随时间变化符合单指数衰减方程（0.7444≤R²≤0.9724;1.1×10^-6≤F≤0.0055）.采用牛粪部分代替化肥的施肥方式,在一定范围内能降低稻田退水中TN、TP输出负荷（41.8%、36.0%、64.3%;20.3%、39.1%、48.9%）,还可以降低稻田水中N/P,降低水体富营养化风险.同时,牛粪的施用可提高土壤中脲酶和磷酸酶的含量,促进氮磷向植物可吸收形态转化.综合经济成本和生态效益核算,采用10t有机肥代替无机肥的处理是相对经济环保的施肥方法,该施肥方式下,氮磷年输出负荷分别为17.70,1.26kg/hm².     

Nanoencapsulation of hexavalent chromium with nanoscale zero-valent iron: High resolution chemical mapping of the passivation layer

Solid phase reactions of Cr(Ⅵ) with Fe(0) were investigated with spherical-aberration-corrected scanning transmission electron microscopy(Cs-STEM) integrated with X-ray energy-dispersive spectroscopy(XEDS). Near-atomic resolution elemental mappings of Cr(Ⅵ)–Fe(0) reactions were acquired. Experimental results show that rate and extent of Cr(Ⅵ) encapsulation are strongly dependent on the initial concentration of Cr(Ⅵ) in solution. Low Cr loading in nZⅥ(1.0 wt%) promotes the electrochemical oxidation and continuous corrosion of n ZⅥ while high Cr loading(1.0 wt%) can quickly shut down the Cr uptake. With the progress of iron oxidation and dissolution, elements of Cr and O counter-diffuse into the nanoparticles and accumulate in the core region at low levels of Cr(Ⅵ)(e.g., 10 mg/L). Whereas the reacted n ZⅥ is quickly coated with a newly-formed layer of 2–4 nm in the presence of concentrated Cr(Ⅵ)(e.g., 100 mg/L). The passivation structure is stable over a wide range of pH unless pH is low enough to dissolve the passivation layer. X-ray photoelectron spectroscopy(XPS) depth profiling reconfirms that the composition of the newly-formed surface layer consists of Fe(Ⅲ)–Cr(Ⅲ)(oxy)hydroxides with Cr(Ⅵ) adsorbed on the outside surface. The insoluble and insulating Fe(Ⅲ)–Cr(Ⅲ)(oxy)hydroxide layer can completely cover the n ZⅥ surface above the critical Cr loading and shield the electron transfer. Thus, the fast passivation of nZⅥ in high Cr(Ⅵ) solution is detrimental to the performance of nZⅥ for Cr(Ⅵ) treatment and remediation.     

Investigating the bacterial community and amoebae population in rural domestic wastewater reclamation for irrigation

Reclamation of domestic wastewater for agricultural irrigation is viewed as a sustainable option to create an alternative water source and address water scarcity. Free-living amoebae(FLA), which are amphizoic protozoa, are widely distributed in various environmental sources. The FLA could cause considerable environmental and health risks. However, little information is available on the risk of these protozoa. In this study, we evaluated the feasibility using rural domestic wastewater for agricultural irrigation, and analyzed dynamic changes of the microbial community structure and FLA populations in raw and treated wastewater, as well as the phyllosphere and rhizosphere of lettuce production sites that were irrigated with different water sources. The bacterial community dynamics were analyzed by terminal restriction fragment length polymorphism(T-RFLP). The bacterial community structures in the influent were similar to that in the effluent, while in some cases relative abundances varied significantly. The populations of Acanthamoeba spp. and Hartmannella vermiformis in the anaerobically treated wastewater were significantly higher than in the raw wastewater. The vegetables could harbor diverse amoebae, and the abundances of Acanthamoeba spp. and H. vermiformis in the rhizosphere were significantly higher than in the phyllosphere. Accordingly, our studies show insight into the distribution and dissemination of amoebae in wastewater treatment and irrigation practices.     

可靠性强化试验技术在某型伺服作动器研制中的适用性探索

目的探索可靠性强化试验技术在典型机电液一体化产品伺服作动器研制过程中的适用性。方法以某型伺服作动器为研究对象,从故障激发的角度对可靠性强化试验技术的应用进行可行性分析,在响应调查和应力分析的基础上,结合产品的工作特点设计适用于该类伺服作动器的可靠性强化试验方案,包含低温步进应力试验、高温步进应力试验、快速温度循环试验10个循环、振动步进应力试验(包含气锤式三轴向六自由度超高斯随机振动方式及电磁振动台随机振动方式)及综合环境应力试验5个循环,并依此进行试验。结果在快速温度循环试验及综合环境应力试验过程中,均有效地激发出了产品的漏油故障,与相似产品外场暴露的漏油故障模式相吻合。结论可靠性强化试验技术可有效地应用于典型机电液一体化产品伺服作动器的研制过程,设计的可靠性强化试验方案可有效地激发外场出现频率较高的故障,可作为该类产品研制的试验手段之一。     

密封组合形式对结构密封性能影响研究

目的研究密封组合形式对结构密封性能的影响。方法开展密封性能试验,从密封形式、装配形式和涂覆形式的3种组合形式开展试验研究,找出结构密封性能影响因素,筛选密封最优组合形式。结果结构密封3种组成形式分别为有无贴合面的密封形式,干涉装配、湿装配形式,部分涂覆、全涂覆形式。开展2种应力水平下8种密封组合形式的密封性能试验,在保证密封工艺质量条件下,按照飞机结构和受载特点选取合理密封组合形式能有效提高结构密封性能。结论在飞机应力较高、不常拆的密封部位应选择贴合面密封、干涉装配、部分涂覆的密封组合形式,在飞机结构设计要求间隙装配、常拆卸的密封部位选择贴合面密封、湿装配、部分涂覆的密封组合形式。     

电絮凝净化含聚污水影响因素研究

目的为保障油田正常安全生产,促进油田含聚污水的循环利用。方法采用电絮凝技术单因素研究方法开展净化含聚污水的静态实验研究,探讨外加电流密度、极板间距、初始pH及聚合物浓度等因素对净化效果的影响规律。结果当初始pH为7.0,电流密度为4.0 m A/m2,极板间距为1.0 cm,电解16 min时,综合处理效果最佳。此时,含油量与浊度去除率分别为98.85%,99.93%,处理每克油平均消耗为0.0494 g的Al,处理每立方米含聚污水的能耗为0.2895 k Wh。污水中的聚合物浓度越小,净化效果越好。结论中性处理,极板间距为1.0 cm,外加电流密度为4.0 m A/m2,通电16 min是最佳处理条件。     

奎屯市区城市废水排污系统网络化的探讨

根据奎屯市区城市废水的排放量大、排污口多、污染物浓度高以及排污下水管道污水处理设施的建成现状等特点，提出了以污水处理厂为治理中心，市区排污管道网络化的改造设想、存在问题及对策。     

Desert Water Harvesting to Benefit Wildlife: A Simple, Cheap, And Durable Sub-Surface Water Harvester for Remote Locations

A sub-surface desert water harvester was constructed in the sagebrush steppe habitat of south-central Idaho, U.S.A. The desert water harvester utilizes a buried micro-catchment and three buried storage tanks to augment water for wildlife during the dry season. In this region, mean annual precipitation (MAP) ranges between about 150–250 mm (6″–10″), 70% of which falls during the cold season, November to May. Mid-summer through early autumn, June through October, is the dry portion of the year. During this period, the sub-surface water harvester provides supplemental water for wildlife for 30–90 days, depending upon the precipitation that year. The desert water harvester is constructed with commonly available, “over the counter” materials. The micro-catchment is made of a square-shaped, 20 mL. “PERMALON” polyethylene pond liner (approximately 22.9 m × 22.9 m = 523 m²) buried at a depth of about 60 cm. A PVC pipe connects the harvester with two storage tanks and a drinking trough. The total capacity of the water harvester is about 4777 L (1262 U.S. gallons) which includes three underground storage tanks, a trough and pipes. The drinking trough is refined with an access ramp for birds and small animals. The technology is simple, cheap, and durable and can be adapted to other uses, e.g. drip irrigation, short-term water for small livestock, poultry farming etc. The desert water harvester can be used to concentrate and collect water from precipitation and run-off in semi-arid and arid regions. Water harvested in such a relatively small area will not impact the ground water table but it should help to grow small areas of crops or vegetables to aid villagers in self-sufficiency.     

CTL-12型化学需氧量速测仪与标准法测定CODCr之比较

使用CTL—12型化学需氧量速测仪分析废水化学需氧量，简便、快速，且方法可行，完全能满足环境监测技术要求。