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Differential Pulse Anodic Stripping Voltammetry (DPASV) was employed to measure Apparent Copper Complexing Capacity (Lt) and Stability Constants (Ks) of related cupric complexes of cell exudates of the phytoplanktonic alga Dunaliella salina. Three natural seawater samples collected 0.1, 2, 5 miles off the Tyrrhenian coast were used as culture medium. The measurements were carried out 1h and 7 days after the inoculum. Furthermore, on one culture the medium was passed through C18‐SEP‐PAK cartridges in order to separate the cell exudates. The results show that Dunaliella salina influences the value of Lt but does not affect the value of Ks . The C18SEP‐PAK retain only 50% of the ligands produced by the cells and capable of complexing copper. 相似文献
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Complex formation of Cd2+ and Zn2+ with thiol derivatives has been investigated by differential pulse polarography. The binding of Cd2+ and Zn2+ with cysteine (CySH), glutathione (GSH) and the model peptide N‐acetyl‐cysteine‐methylamide (ASH) reveals different stoichiometry. Thus, Cd2+ forms 1:1 and 1:2 complexes with CySH while 1:2 and 1:4 complexes have been observed with GSH and ASH, respectively. Overall formation constants of Cd2+ with CySH (Iogβ 2 15.3) and with GSH (Iogβ52 14.4) have been estimated using competitive complexation with nitrilotriacetic acid (NTA). Investigation of competition between Zn2+ and Cd2+ for the thiol complexation has underlined the role played by the amino group in CySH for the stabilization of Zn complexes in contrary to Cd complexes. 相似文献
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A polarographic method was optimised for the quantitative determination of metallothionein (MT) in whole body Gammarus locusta (Crustacea: Amphipoda). The identity of the MT-like proteins was examined using electrophoretic analysis (SDS-PAGE) and induction studies (water-borne exposures to copper). The MT-method was then used to examine changes in MT levels over the lifetime (juveniles, sub-adults and adults) of a laboratory population of G. locusta; copper (Cu) and zinc (Zn) body burden were also measured by flame atomic absorption spectrometry. MT was quantified by heat-denaturation of 30?000?g supernatants (to remove the bulk of non-MT proteins) followed by differential pulse polarography (DPP) to measure sulphydryl-group containing proteins. DPP proved to be a sensitive and reliable method to quantify heat-stable total sulphydryl-proteins. The majority of the latter was indicated to be MT from SDS-PAGE and induction studies. SDS-PAGE revealed a putative MT of 23?±?0.6?kDa app. mol. wt., consistent with the average size of dimeric MTs (10–20?kDa) found in several aquatic invertebrate species. Copper-exposure revealed parallel increases in the amounts of 23?kDa protein and total sulphydryl-proteins. Levels of whole body MT (rabbit pure MT as standard) range between 1.3 and 2.3?mg?g?1 dry wt. over the lifetime of G. locusta. Sex-related changes in MT status were observed, the levels in females being 1.6 times higher than in males (p<0.05). Copper and Zn body content changed over the lifetime of G. locusta, the levels in juveniles (p>0.05) and sub-adults (p<0.05) being higher than in adults. It is concluded that the inclusion of MT in ecotoxicological studies with amphipod crustaceans require some caution with respect to the stages of moulting and/or sexual maturation of organisms, but this should not provide any major impediment in its use in metal pollution monitoring. 相似文献
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针对电、布除尘器的特点,提出了一种新型静电布袋混合式除尘器,并已应用于工业中。在没有使用任意阀门的前提下,该产品将电除尘器和布袋除尘器结合在一起,取长补短,充分发挥了电除尘器能大量收尘、节能、维护检修工作量小,还可捕集高比电阻和低比电阻等特殊干性粉尘,解决了电除尘难以净化的含微米或亚微米烟尘的难题。兼具布袋除尘器对粉尘粒度和比电阻不敏感、排放浓度低的优点。一级静电除尘器效率可达90%,对于粉尘浓度为30 g/m3左右的燃煤锅炉,经过静电除尘后进入滤袋的粉尘浓度只有3 g/m3。对于这种粉尘浓度,滤袋的清灰周期可达3 h以上。由于清灰周期的大大增长,可大大提高滤袋的寿命。该产品性价比优良、占地面积少、结构简单。尤其在净化效率、气体阻力等主要技术指标方面达到了环保要求。 相似文献
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通过对中铝洛铜熔铸厂16t黄铜炉组除尘系统出现的问题采取相应对策进行改造,探讨了通过屋顶罩排烟系统来解决黄铜炉组炉盖开启操作时产生大量烟尘的方法,具有实用性,同时针对黄铜炉熔炼产生烟尘的特点,提出了适合氧化锌回收的除尘改造方案. 相似文献
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为进一步提高循环式活性污泥工艺(CASS)的脱氮除磷效果,改变其运行方式,采用好氧脉冲曝气,提出频繁硝化-反硝化循环式活性污泥工艺(FND-CASS).结果表明,FND-CASS工艺与CASS工艺相比,在去除污水中有机物方面能力略有下降,但在脱氮除磷方面具有明显的优势.在同样的进水流量且DO浓度控制较低的运行条件下,F... 相似文献
49.
我国化学品分类和标签与GHS的差距分析 总被引:2,自引:0,他引:2
为明确我国现阶段实施GHS存在的问题,促使我国化学品分类和标签满足GHS要求。研究了我国化学品分类标准、标签标准与GHS存在的差距。发现了《危险化学品名录》没有分类标准,并且未涵盖GHS爆炸物中的不稳定爆炸物和1.2项、1.5项、1.6项爆炸物,易燃气溶胶,以及除急性毒性以外的健康危害和环境危害的化学品,剧毒化学品、有毒物质存在不同监管部门分类标准不统一,现行多套危险化学品标签标准问题。提出了在《危险化学品名录》中明确规定危险性分类标准;统一剧毒化学品、有毒品分类标准;在相关的危险化学品法规中明确规定危险化学品标签应符合的标准。 相似文献
50.