危险化学品运输事故初探

危险化学品运输是一种动态危险源,在运输过程中火灾、爆炸、泄漏、中毒事故时有发生,对人类生命、物质财产和生态环境的安全构成极大威胁.对危险化学品在运输过程中事故发生的类型、事故的成因、事故的危害进行了探讨,阐述了事故的预防措施以及事故后如何做好减灾工作.     

水泥窑协同处置过程中Pb、Cd的挥发特性

对铅、镉2种重金属的氧化物开展了热重实验、熟料煅烧以及熟料消解实验,以重金属的挥发率为主要指标,研究了水泥窑协同处置过程中铅、镉在等温条件下随时间的挥发特性。结果表明,2种重金属的挥发率均是随温度的升高,时间的增加而增大。Pb的挥发率为96%,Cd的挥发率达到98%,根据等温动力学及阿累尼乌斯方程,对Pb,Cd的挥发率随时间变化的规律进行动力学模拟,得到较好的线性拟合效果,其中,Pb挥发反应的表观活化能E为88.73 kJ/mol,Cd挥发反应可以分2个部分：1 200℃以下的表观活化能E为61 kJ/mol;1 250℃以上的表观活化能E为184.6 kJ/mol。     

焚烧法处理环己酮生产中的皂化液

用环已烷氧化生产环已酮的生产过程中会产生大量的皂化液 ,它含有大量的有害物质 ,是一种难处理的高污染有机废水。某石化厂在借鉴造纸行业的黑液焚烧技术的基础上 ,采用焚烧法来处理皂化液 ,并得到副产蒸气和回收了碳酸钠 ,实现了皂化液的无害化与资源化 ,具有良好的社会效益、环境效益和经济效益 ,每处理 1t皂化液可盈利 10 0～ 2 0 0元     

Effect of soil moisture dynamics on dense nonaqueous phase liquid (DNAPL) spill zone architecture in heterogeneous porous media

The amount, location, and form of NAPL in contaminated vadose zones are controlled by the spatial distribution of water saturation and soil permeability, the NAPL spill scenario, water infiltration events, and vapor transport. To evaluate the effects of these processes, we used the three-phase flow simulator STOMP, which includes a new permeability-liquid saturation-capillary pressure (k-S-P) constitutive model. This new constitutive model considers three NAPL forms: free, residual, and trapped. A 2-D vertical cross-section with five stratigraphic layers was assumed, and simulations were performed for seven cases. The conceptual model of the soil heterogeneity was based upon the stratigraphy at the Hanford carbon tetrachloride (CT) spill site. Some cases considered co-disposal of NAPL with large volumes of wastewater, as also occurred at the Hanford CT site. In these cases, the form and location of NAPL were most strongly influenced by high water discharge rates and NAPL evaporation to the atmosphere. In order to investigate the impact of heterogeneity, the hydraulic conductivity within the lower permeability layer was modeled as a realization of a random field having three different classes. For six extreme cases of 100 realizations, the CT mass that reached the water table varied by a factor of two, and was primarily controlled by the degree of lateral connectivity of the low conductivity class within the lowest permeability layer. The grid size at the top boundary had a dramatic impact on NAPL diffusive flux just after the spill event when the NAPL was present near the ground surface. NAPL evaporation with a fine grid spacing at the top boundary decreased CT mass that reached the water table by 74%, compared to the case with a coarse grid spacing, while barometric pumping had a marginal effect for the case of a continuous NAPL spill scenario considered in this work. For low water infiltration rate scenarios, the distribution of water content prior to a NAPL spill event decreased CT mass that reached the water table by 98% and had a significant impact on the formation of trapped NAPL. For all cases simulated, use of the new constitutive model that allows the formation of residual NAPL increased the amount of NAPL retained in the vadose zone. Density-driven advective gas flow from the ground surface controlled vapor migration in strongly anisotropic layers, causing NAPL mass flux to the lower layer to be reduced. These simulations indicate that consideration of the formation of residual and trapped NAPLs and dynamic boundary conditions (e.g., areas, rates, and periods of different NAPL and water discharge and fluctuations of atmospheric pressure) in the context of full three-phase flow are needed, especially for NAPL spill events at the ground surface. In addition, NAPL evaporation, density-driven gas advection, and NAPL vertical movement enhanced by water flow must be considered in order to predict NAPL distribution and migration in the vadose zone.     

液体旋流分离器分离效率的研究

液体旋流分离器是水环境污染治理的主要设备之一.分离效率是衡量液体旋流分离器分离过程进行完善程度的最重要的技术指标,它能从质与量两方面反映出设备性能的优劣.当前液体旋流分离器设计过程还缺少具体量化的理论依据,为了给液体旋流分离器的设计提供理论依据,通过液体旋流分离器从水中分离固体粒子的性能实验,得出了液体旋流分离器各部结构尺寸、形状、相对比例对分离效率的不同影响程度,提出了结构参数的最佳取值范围.按照本研究提出的设计原则和方法,可以制造出性能优良的液体旋流分离器.     

Determination of 10 particle-associated multiclass polar and semi-polar pesticides from small streams using accelerated solvent extraction

A new analytical method using accelerated solvent extraction was developed for the determination of 10 particle-associated polar and semipolar pesticides. In addition, six deuterated analogues of the target compounds were evaluated as internal standards. The method yielded acceptable accuracy (73–103% recovery) and precision (<25% relative standard deviation) for eight compounds. Using size exclusion chromatography (SEC) as cleanup step resulted in higher recoveries compared to solid phase extraction (SPE) cleanup.

Deuterated standards with 10 or more deuterium atoms performed well as internal standards concerning similar recovery and correlation with the target analytes.

The method was employed to extract particle-associated pesticides from 16 streams located in an area with intense agriculture in France. Acetochlor, pirimicarb, tebuconazole, fenpropidin, -endosulfan and chlorfenvinphos were detected at concentrations up to 1 mg kg⁻¹ dry weight. A comparison with aquatic toxicity data indicated potential risk to the benthic fauna exposed to these concentrations of pirimicarb, -endosulfan and chlorfenvinphos.

We suggest that the method presented here be used for the extraction and quantitation of particle-associated polar pesticides.     

安全评价方法在危险废物处置环境风险评价中的应用探讨

对安全评价方法在危险废物处置建设项目环境风险评价中的运用进行初步探索。主要用"工艺过程风险因素分析表"对工艺过程潜在风险性识别;用蒙德法进行源项分析;用池火灾模型、蒸气云爆炸伤害模型对易燃、易爆物质的火灾、爆炸等重大事故后果进行计算,得出人员的伤亡半径和财产损失半径等参数,以便于判断风险的可接受水平。分析结果表明:采用安全评价方法对危险废物处置建设项目进行环境风险评价是适用的、可行的。     

电子封装行业职业有害因素的辨识与分析

从电子封装行业工艺入手,依据国家颁布的职业有害因素分类目录及职业有害因素致病模型,针对电子封装行业插入式(DIP)及表面贴装(QFP/SOIC)制造工艺使用的材料、设备、条件、人员作业特点,对行业内具有共性的职业有害因素进行分析,对工艺过程中存在的职业有害因素作出辨识,并提出把硅粉尘、铅、氩气、高温、环氧树脂、氢氧化钾、噪声、酸雾、重复性静态作业、重复性动态作业等有害因素作为防控重点,为电子封装行业职业有害因素的危害量化评价及其防控措施制定提供了科学依据。     

危险化学品泄漏扩散模型的研究现状分析与比较

为了对危险化学品港口装卸过程中泄漏危险度进行量化评定,基于泄漏扩散模型提高港口的应急处理技术,对危险化学品泄漏扩散模型的研究现状从理论研究、试验研究、应用研究3方面进行深入分析。着重对高斯模型(Gaussian model),BM模型,Sutton模型,FEM3模型,箱及相似模型,P-G模型等模型从理论描述方法、适用对象和范围、计算精度和难易、参数选取等方面进行优缺点的对比研究,认为:由于危险化学品泄漏和扩散行为的复杂性,影响因素的多样性,使各类模型在具备一定的理论价值和现实意义的同时,还存在着参数选取不确定性、试验模拟差异性以及实际应用局限性的问题和不足,运用计算机技术完善试验结果数据库、改进数学仿真模型是其进一步研究发展的趋势。     

我国危险化学品安全监管网络整合研究

分析我国危险化学品安全监管网络的特征,指出安全监管网络中存在的法律法规、监管部门信息共享、合作协调机制等方面存在的突出问题,提出了我国危险化学品安全监管网络整合的主要对策,包括建立监管部门之间的常态合作协调机制、无缝隙化城市安全监管平台以及跨区域合作监管机制。危险化学品安全监管网络整合,对提高我国危险化学品监管水平具有重要意义。