Truncation errors in finite difference models for solute transport equation with first-order reaction

The truncation errors associated with finite difference solutions of the advection-dispersion equation with first-order reaction are formulated from a Taylor analysis. The error expressions are based on a general form of the corresponding difference equation and a temporally and spatially weighted parametric approach is used for differentiating among the various finite difference schemes. The numerical truncation errors are defined using Peclet and Courant numbers and a new Sink/Source dimensionless number. It is shown that all of the finite difference schemes suffer from truncation errors. In particular it is shown that the Crank–Nicolson approximation scheme does not have second order accuracy for this case. The effects of these truncation errors on the solution of an advection–dispersion equation with a first order reaction term are demonstrated by comparison with an analytical solution. The results show that these errors are not negligible and that correcting the finite difference scheme for them results in a more accurate solution.     

Two (or three) is not equal to one: Multiple jobholding as a neglected topic in organizational research

The objective of this Incubator is to stimulate research in the area of multiple jobholding (MJH), a long‐neglected topic in organizational behavior. We first discuss the prevalence of, and motivation for, MJH and then discuss possible dangers and benefits of MJH. Throughout, we discuss ideas for future research. Copyright © 2014 John Wiley & Sons, Ltd.     

What does team–member exchange bring to the party? A meta‐analytic review of team and leader social exchange

Both leader–member exchange (LMX) and team–member exchange (TMX) measure the quality of reciprocal exchange among employees in the workplace. Although LMX focuses on supervisor–subordinate relationships while TMX examines the relationships among team members, both have theory‐based and empirically proven relations with workplace outcomes such as job performance, organizational commitment, job satisfaction, and turnover intentions. However, it is not yet known which has more of an impact on such workplace outcomes—specifically, it is not clear if an employee's time is best spent developing vertical relationships among supervisors and subordinates (LMX) or on the horizontal relationships among team members (TMX). Accordingly, this meta‐analysis explores the incremental validity and relative importance of these two social exchange‐based constructs. The theoretical logic underlying LMX and TMX is clarified, and the parameter estimates between LMX, TMX, and work outcomes are reported. Results demonstrate that TMX shows incremental validity above and beyond LMX for some outcomes (organizational commitment and job satisfaction), but not others (job performance and turnover intentions). Also, LMX shows greater relative importance across all four outcomes. In sum, the clarification of the theoretical and empirical landscape lays a foundation for recommendations for future research. Copyright © 2013 John Wiley & Sons, Ltd.     

国家标准GB 30188-2013《电焊条生产行业防尘防毒技术规程》解读

本文主要介绍了国家标准GB 30188-2013的意义、适用范围和内容,重点强调了电焊条生产行业有害物质及其对人体的健康危害,以及工程防治技术,为我国电焊条生产行业及其相关领域人员使用标准提供帮助。     

Concurrent nitrate and Fe(III) reduction during anaerobic biodegradation of phenols in a sandstone aquifer

The biodegradation of phenols (5, 60, 600 mg l⁻¹) under anaerobic conditions (nitrate enriched and unamended) was studied in laboratory microcosms with sandstone material and groundwater from within an anaerobic ammonium plume in an aquifer. The aqueous phase was sampled and analyzed for phenols and selected redox sensitive parameters on a regular basis. An experiment with sandstone material from specific depth intervals from a vertical profile across the ammonium plume was also conducted. The miniature microcosms used in this experiment were sacrificed for sampling for phenols and selected redox sensitive parameters at the end of the experiment. The sandstone material was characterized with respect to oxidation and reduction potential and Fe(II) and Fe(III) speciation prior to use for all microcosms and at the end of the experiments for selected microcosms.The redox conditions in the anaerobic microcosms were mixed nitrate and Fe(III) reducing. Nitrate and Fe(III) were apparently the dominant electron acceptors at high and low nitrate concentrations, respectively. When biomass growth is taken into account, nitrate and Fe(III) reduction constituted sufficient electron acceptor capacity for the mineralization of the phenols observed to be degraded even at an initial phenols concentration of 60 mg l⁻¹ (high) in an unamended microcosm, whereas nitrate reduction alone is unlikely to have provided sufficient electron acceptor capacity for the observed degradation of the phenols in the unamended microcosm.For microcosm systems, with solid aquifer materials, dissolution of organic substances from the solid material may occur. A quantitative determination of the speciation (mineral types and quantity) of electron acceptors associated with the solids, at levels relevant for degradation of specific organic compounds in aquifers, cannot always be obtained. Hence, complete mass balances of electron acceptor consumption for specific organic compounds degradation are difficult to confine. For aquifer materials with low initial Fe(II) content, Fe(II) determinations on solids and in aqueous phase samples may provide valuable information on Fe(III) reduction. However, in microcosms with natural sediments and where electron acceptors are associated with the sediments, complete mass-balances for substrates and electron acceptors are not likely to be obtained.     

Heuristic space–time design of monitoring wells for contaminant plume characterization in stochastic flow fields

An optimization methodology for designing groundwater quality monitoring networks applicable to stochastic flow fields is presented and evaluated. The approach sets itself apart from previous techniques by incorporating the time dimension directly into the objective function. This function is extremized using a directed partial enumeration strategy guided by physical considerations related to transport processes. The result is a set of monitoring well locations and a sampling schedule that minimizes plume characterization error while satisfying constraints on the maximum number of wells and allowable number of active wells. The method is evaluated using hypothetical plumes with varying degrees of heterogeneity. Results indicate that the proposed approach is successful in generating near-optimal sampling networks that satisfy all imposed constraints. Monitoring networks with as little as three active wells and a total of 12 wells are found to provide adequate plume characterization for low toxicity contaminants.     

Geostatistical spatiotemporal analysis of air temperature as an aid to delineating thermal stability zones in a potential show cave: implications for environmental management

Air temperature in several galleries of the Covadura System (Sorbas Gypsum Karst, Almería) was measured at monthly intervals over a period of 1 year. The spatial temperature distribution for each month was modeled in a geostatistical framework. The mean trend of the air temperature and the difference between each experimental temperature measurement and this trend were calculated over space and time. Both the trend and residual component were characterized using a geostatistical space-time model. A large spatial trend of the air temperature was found due to the orientation of galleries within the cave system and as a function of the distance from the main cave entrance. Kriging was used for the spatial estimation of the time covariance of the residuals. This enabled the delimitation of the cave into three zones of varying environmental risk in the event of being opened to visits by the public, according to the degree of stability of air temperature over space and time. The influence of human presence on the spatial temperature distribution was assessed using data collected during a year (2000/2001) in pilot galleries opened to the public. An average visit corresponding to August was selected comprising 16 people over a period of 53 min. This average visit influenced the spatial temperature pattern at distances of more than 90 m from the cave entrance, according to the geostatistical model adopted. Within this zone the mean thermal increment generated by human presence was estimated to be 0.26 degrees C. The spatiotemporal mathematical model of the cave air temperature has been revealed as a useful tool for the environmental management of show caves.     

The U.S. Flood Control Program at 75: Environmental Issues1

Black, Peter E., 2012. The U.S. Flood Control Program at 75: Environmental Issues. Journal of the American Water Resources Association (JAWRA) 48(2): 244‐255. DOI: 10.1111/j.1752‐1688.2011.00609.x Abstract: Recent, recurring, and increased magnitude floods adversely challenge long‐held and erroneous concepts of flood control. This article focuses on the environmental issues with comprehensively reviewed essentials of the United States (U.S.) riverine Flood Control Program, including news reports, scientific articles, books, and landmark treatises. For the past three‐quarters of a century, U.S. floods have continued (and will continue) to occur, causing increasing property damage with growing fiscal loss. Reasons include inattention to fundamental principles of physics, hydrology, and ecology. There are also important challenges involving environmental policy, economics, and common sense. Measures afforded by the existing program encourage and enable investment in floodplains while violating a variety of natural principles that make the situation worse. This detailed review includes the questionable (actually untrue) justification in the document‐setting policy for the 1936 Omnibus Flood Control Act. The well‐documented evidence is overwhelming. An alternative approach is presented that would enable and celebrate natural floods, managing their ecological and hydrological values, and not attempting to control them.     

The Transboundary Nature of the Allende–Piedras Negras Aquifer Using a Numerical Model Approach

The Allende–Piedras Negras (APN) aquifer is located between the states of Texas (United States [U.S.]) and Coahuila (Mexico). The Rio Grande crosses the aquifer, acting as a natural and political divide between the countries. However, it remains unclear whether the APN aquifer can be considered a truly transboundary aquifer flow system, which would potentially require joint management by two different administrative jurisdictions. The main purpose of this study was to evaluate the transboundary nature of this aquifer. This was achieved by developing a detailed hydrogeological model to analyze the direction of volumetric fluxes within the APN aquifer using Visual MODFLOW. The model simulated a spatially averaged cumulative drawdown of 0.76 m for the entire aquifer over an 18‐year modeling period (2000–2017). The flow convergence zone, previously located below the Rio Grande, has shifted to the U.S. side in most locations, driven by higher pumping rates of the wells located near the river. This shift of the convergence zone from one country to the other means that groundwater recharge from one side flows underneath the river to the other side. This qualifies the APN aquifer as a “transboundary groundwater flow system.” The procedure followed in this study may be applied to other aquifers that straddle the U.S.–Mexico border and may motivate future modeling studies on other poorly studied transboundary aquifers around the world and thereby enable bi‐national aquifer management.     

Spatial disaggregation of traffic emission inventories in large cities using simplified top–down methods

Simple, inexpensive and accurate methods for assessing the spatial distribution of traffic emissions are badly needed for the environmental management in South American cities. In this study, various spatial disaggregation methods of traffic emissions of carbon monoxide are presented and evaluated for a large city (Santiago de Chile). Previous methods have used a simplified road network as a proxy for deriving spatial patterns of emissions. However, these approaches resulted in underestimation of emissions in urban centers, industrial zones and highly loaded roads, as well as overestimation in residential zones. Here we modify these methods by adding data correlated with the emissions (e.g. traffic counts, vehicles mean speed, road capacity) solving partially or completely the indicated problems. After an accuracy-simplicity analysis two methodologies stand out over the others: using traffic count classification and using a land use map, both combined with a simplified road network. Both are top–down approaches that correlate well (0.9) with the reference emissions and capture emission peaks (within 30% relative error). Hence the proposed changes allow an improved balance between accuracy and costs (monetary, availability of data and time to obtain data).