中国城市温室气体清单研究

介绍城市温室气体排放特征和国际城市温室气体清单研究进展,研究了全球城市化和城市CO2排放的强正相关性,以及中国城市清单方法研究起步较早但发展缓慢的特点。分析了城市温室气体清单相对国家清单的特征,即城市清单编制往往采用消费模式,区别于国家清单的生产模式;国际城市清单中往往包括了由于外调电和供暖产生的CO2排放,同时城市温室气体清单编制灵活性和针对性更强。针对我国城市温室气体清单研究的不足,提出了我国城市温室气体清单方法,强调中国城市采用尺度1+尺度2的范围,暂不考虑尺度3的范围,即生产+消费的混合模式,并且在城市市域温室气体排放研究的基础上,加强狭义城市温室气体排放水平的研究。选择北京市和纽约市,对比分析了两个城市CO2排放特征,结果显示,在确定的清单体系下,北京市和纽约市具有较好的可比性。纽约市的总排放量(尺度1+尺度2)略低于北京市排放量,人均排放量略高于北京市。     

湖南省碳源与碳汇变化的时序分析

在全球气候变暖的背景下,减少温室气体排放、发展低碳经济成为各地区在发展中的普遍共识。以湖南省为研究区域,以1995~2008年为研究时序,从能源消费、主要工业产品生产工艺过程、土地利用变化与牲畜管理、固体废弃物处理与废水处理和排放4个方面综合分析了碳源与碳汇的变化情况。研究表明:1995~2008年,湖南省温室气体排放总量约在220亿t（2000年）至399亿t（2008年）CO2当量之间,14 a间增长了6118%,年均增长374%;碳汇总量约在1754亿t（1995年）至2537亿t（2007年）CO2当量之间,14 a间增长了3607%,年均增长约240%;能源消费与农业部门是湖南省温室气体的主要来源,林地是湖南省碳汇的主要来源;综合碳源与碳汇变化的均衡结果,1995~2008年湖南省呈碳汇盈余状态,净碳汇在2001~2007年持续增加,14 a间增长了31.94%,年均增长2.15%     

西南山区某气井井场地基稳定性模拟分析

中国西南山区蕴藏着丰富的天然气资源,但随着开发规模的日益扩大,天然气井逐步转向山区这类地质环境恶劣的地区。本文以西南山区某气井为原型,在详细阐明井场区地质环境背景特征的基础上,首先对井场出现的典型地质问题——地下采空区进行定性判断和分析;之后选用F lac-2D有限差分软件,对井场加载前/后地下采空区可能造成的井场地基应力和变形特征,采用双洞和采空区这2种计算模型,进行数值模拟分析。模拟结果表明,井场加载前/后地基最大位移量为2 mm,地基局部地段出现拉应力区,但总体上地基稳定。研究结论将为后期建设中井场建筑物的优化布局及基础的选型提供依据。     

Decay profile and metabolic pathways of quinalphos in water, soil and plants

The widespread occurrence of pesticide residues in different agricultural and food commodities has raised concern among the environmentalists and food chemists. In order to keep a proper track of these materials, studies on their decay profiles in the various segments of ecosystem under varying environmental conditions are needed. In view of this, the metabolites of quinalphos in water and soil under controlled conditions and in plants, namely tomato and radish in field conditions have been analysed and possible pathways suggested. In order to follow the decay of the pesticide, an HPLC procedure has been developed. Studies conducted in water at different temperatures, pH and organic content reveal that the persistence of the pesticide decreases with the increase in all the three variables. In the three different types of soils studied, the effect of pH is more or less apparent on a similar line. On an average a faster decay is observed in the case of plants than in water and soil. The decay profiles in all these cases follow first order kinetics. The metabolites were identified by GC-MS. The investigations reflect that degradation occurs through hydrolysis, S-oxidation, dealkylation and thiono-thiol rearrangement. The pathways seem to be complex and different metabolites were observed with the change in the matrix. Quinalphos oxon, O-ethyl-O-quinoxalin-2-yl phosphoric acid, 2-hydroxy quinoxaline and quinoxaline-2-thiol were observed in all the matrices. Results further indicate that the metabolites, 2-hydroxy quinoxaline and oxon, which are more toxic than parent compound, persist for a longer time.     

Polychlorinated dibenzo-p-dioxin and dibenzofuran in urban air of an Andean city

Particle-bound polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) in ambient air were monitored together with particulate matter less than 10 μm (PM₁₀) at three sampling sites of the Andean city of Manizales, Colombia; during September 2009 and July 2010. PCDD/Fs ambient air emissions ranged from 1 fg WHO-TEQ m⁻³ to 52 fg WHO-TEQ m⁻³ in particulate fraction. The PM₁₀ concentrations ranged from 23 μg m⁻³ to 54 μg m⁻³. Concentrations of PM₁₀ and PCDD/Fs in ambient air observed for Manizales - a medium sized city with a population of 380 000 - were comparable to concentrations in larger cities. The highest concentrations of PCDD/Fs and PM₁₀ found in this study were determined at the central zone of the city, characterized by public transportation density, where diesel as principal fuel is used. In addition, hypothetical gas fractions of PCDD/Fs were calculated from theoretical K_p data. Congener profiles of PCDD/Fs exhibited ratios associated with different combustion sources at the different sampling locations, ranging from steel recycling to gasoline and diesel engines. Taking into account particle and gas hypothetical fraction of PCDD/Fs, Manizales exhibited values of PCDD/Fs equivalent to rural and urban-industrial sites in the southeast and center of the city respectively. Poor correlation of PCDDs with PM₁₀ (r = −0.55 and r = 0.52) suggests ambient air PCDDs were derived from various combustion sources. Stronger correlation was observed of PCDFs with PM₁₀. Poor correlation between precipitation and reduced PM₁₀ concentration in ambient air (r = −0.45) suggested low PM₁₀ removal by rainfall.     

杂多酸水溶液脱除烟气中SO2的性能研究

合成了H3PMo12O40、H4SiW12O40、H3PW12O40、H4PMo11VO40、H5PMo10V2O40和H6PMo9V3O406种杂多酸,分别采用红外光谱（FT-IR）和X射线衍射（XRD）表征杂多酸的结构,并采用气相色谱仪对6种杂多酸水溶液进行脱硫实验测试。实验结果表明：制备的6种杂多酸具有良好的Keggin型结构;H3PMo12O40、H3PW12O40和H4SiW12O40的3种水溶液中,磷钼杂多酸的脱硫性能最好,脱硫率在120 min时可达到16.38%;不同比例的多原子也会使杂多酸有不同的脱硫性能,脱硫性能顺序为：H6PMo9V3O40〉H5PMo10V2O40〉H4PMo11VO40;且6种杂多酸的脱硫稳定性的顺序为：H4PMo11VO40〉H6PMo9V3O40〉H3PMo12O40〉H5PMo10V2O40〉H4SiW12O40≈H3PW12O40。     

电除尘器进口矩形烟道气流分布改进的CFD模拟

应用CFD软件对某电厂电除尘器进口矩形烟道内气流分布进行数值模拟.结果表明:电除尘器原进口矩形烟道监测截面的气流分布极其不均匀,数值模拟结果与实验结果速度分布趋势比较吻合.基于此,通过多次改变电除尘器进口矩形烟道内导流板的数量、位置、尺寸等结构参数,使得改造后烟道监测截面风量偏差降到了±2.2%,气流分布相对均方根值均...     

不同来源废水COD、TOC与Cl-的关系

通过对含盐化工废水(A)、受潮汐影响的河流水(B)、城市生活污水处理厂排水(C)、采油废水(D)4种不同来源废水进行为期15 d的采样监测,测定了其COD、TOC和Cl-浓度,分析比较了3种废水指标之间的关系,其中COD分别使用重铬酸钾法、氯气校正法和碘化钾碱性高锰酸钾法3种方法进行测定.实验结果表明,4种废水Cl-浓...     

Variability of dust iron solubility in atmospheric waters: Investigation of the role of oxalate organic complexation

Atmospheric dust deposition is a major external iron source for remote surface ocean waters. Organic complexation is known to play a role in the dissolution of iron-containing minerals. In this paper, we present our study on the effect of oxalate on dust iron solubility in simulated rainwater. Our results reveal that the solubility of iron carried by analogs of different African dusts varies with the dust source. Our experiments indicate a positive linear correlation between iron solubility and oxalate concentration. Soluble iron (SFe) increases from 0.0025(±0.0005)% to 0.26(±0.01)% of total iron, considering all dust sources and with oxalate concentrations ranging from 0 to 8 μM. These results show that the observed variability of iron solubility in aerosols collected over the Atlantic Ocean is, at least partly, due to an increase in dust iron solubility, with the presence of oxalate complexation, rather than to the presence of more soluble anthropogenic iron. Considering the mineralogical composition of those particles, experiments with pure minerals (hematite, goethite and illite) were performed to study the dissolution process. We found that oxalate promotes the solubility of iron contained in clay and hence confirmed that more than 95% of SFe from soil dust is provided by clay (illite). This experimental work enables us to establish a parameterization of iron solubility in dust as a function of oxalate concentration and based on the individual iron solubility of pure iron-bearing minerals usually present in dust particles. Finally, our results emphasize that oxalate contributes to iron solubility on the same order of magnitude as the acid processes. Organic complexation appears to be a process that increases iron solubility and likely enhances the bioavailability of iron from dust.     

烟气NO氧化催化剂Cu-V/Ti-PILCs的制备及其硫水稳定性

采用等体积浸渍法制备了以钛交联粘土为载体,Cu与V氧化物为活性组分的烟气NO氧化催化剂(Cu-v/Ti-PILCs),并考察了各种制备条件下催化剂的活性及稳定性.结果显示,当V水/V丙酮 =1∶2,负载4%CuO和2%V2O5,并在500℃煅烧时制得的Cu-V/Ti-PILCs催化剂,在NO浓度为350 mg/m3,O...