非烟气工况下常规烟塔与改造烟塔内部结构的比较

根据流体力学理论,基于Fluent6.3.26计算平台,对常规冷却塔和改造后的排烟冷却塔进行了三维内部流场的模拟。分析非烟气工况下,两塔内部烟道布置对气流的影响,为进一步研究在工况条件下烟气、水蒸气塔内扰流与湿热蒸汽抬升作用提供理论基础。验证了改造烟塔内部烟道布置的优越性,对排烟冷却塔结构优化有一定的指导意义。     

Preimplantation genetic diagnosis using FISH for carriers of Robertsonian translocations: the Portuguese experience

Preimplantation genetic diagnosis (PGD) is an alternative to prenatal diagnosis for couples at risk of transmitting genetic disorders to their offspring. We present a fluorescence in situ hybridization (FISH) analysis of embryos obtained after seven PGD cycles in six couples with Robertsonian translocations and male factor infertility: 4 der(13;14), 1 der(14;21) and 1 der(15;21). Of 74 metaphase II (MII) injected oocytes, 61 (82.4%) fertilized normally and cleaved. Of these, 37/61 (60.7%) embryos were of high morphological quality with ≥6 blastomeres. After biopsy of 44 embryos at day 3 of development, seven degenerated, seven arrested in development and 30/44 (68.2%) evolved, of which 25/30 (83.3%) reached the morula/blastocyst stage. Analysis of biopsied blastomeres showed 23/44 (52.3%) of normal/balanced embryos, of which 15 (11 at the morula/blastocyst stage) were transferred in six cycles. One term pregnancy was achieved, which ended by cesarean section at 37 weeks of gestation, giving birth to two healthy newborn. Analysis of 49 embryos (excluding 12 inconclusive cases) showed a predominance of alternate segregation (38/49, 77.6%) over adjacent segregation (7/49, 14.3%), with one (2%) being a polyploid mosaic and three (6.1%) chaotic. Copyright © 2002 John Wiley & Sons, Ltd.     

湿法脱硫系统优化分析

分析了运用烟塔合一等技术对现有湿法脱硫系统简化的可行性.在湿法脱硫系统中,利用冷却塔排烟气代替烟囱排烟,取消烟囱和GGH换热器,将增压风机和引风机合二为一,可提高能源的利用效率,减少设备的投资,降低系统运行及维护费用.     

流动注射-分光光度法测定工业废水中的Fe^2＋和Fe^3＋

将Fe^2 与邻菲啰啉的显色反应引入流动注射系统，用盐酸羟胺将Fe^3 预先还原，0～6μg/ml的Fe^2符合比耳定律，检测出限0．11μg／ml。0．25μg／mlFe^2 经5次测定的标准偏差为2．2％，进样频率为120次／h，回收率98．5～104％。对工业废水中铁的测定取得了满意的效果。     

A theoretical model of air and steam co-injection to prevent the downward migration of DNAPLs during steam-enhanced extraction

When steam is injected into soil containing a dense volatile non-aqueous phase liquid contaminant the DNAPL vaporized within the heated soil region condenses and accumulates ahead of the steam condensation front. If enough DNAPL accumulates, gravitational forces can overcome trapping forces allowing the liquid contaminant to flow downward. By injecting air with steam, a portion of the DNAPL vapor remains suspended in equilibrium with the air, decreasing liquid contaminant accumulation ahead of the steam condensation front, and thus reducing the possibility of downward migration. In this work, a one-dimensional theoretical model is developed to predict the injection ratio of air to steam that will prevent the accumulation of volatile DNAPLs. The contaminated region is modeled as a one-dimensional homogeneous porous medium with an initially uniform distribution of a single component contaminant. Mass and energy balances are combined to determine the injection ratio of air to steam that eliminates accumulation of the contaminant ahead of the steam condensation front, and hence reduces the possibility of downward migration. The minimum injection ratio that eliminates accumulation is defined as the optimum injection ratio. Example calculations are presented for three DNAPLs, carbon tetrachloride (CCl4), trichloroethylene (TCE), and perchloroethylene (PCE). The optimum injection ratio of air to steam is shown to depend on the initial saturation and the volatility of the liquid contaminant. Numerical simulation results are presented to validate the model, and to illustrate downward migration for ratios less than optimum. Optimum injection ratios determined from numerical simulations are shown to be in good agreement with the theoretical model.     

AA3流动注射同时测定地表水中挥发酚和氰化物

利用AA3流动注射分析仪,同时对地表水中的挥发酚和氰化物进行测定,分析流程中使用了在线恒温蒸馏器。同传统的分析方法相比,本法分析测定数据准确、可靠、高效,大大缩短了测定时间,只需将两种标准配制成混合标样,一次取样完成两个项目的测定。回收率为90％～110％,相关系数达到0．9992以上。     

流动注射双环己酮草酰二腙光度法测定水中的铜

为了克服传统分析法操作繁琐、分析时间长的缺陷,将流动注射分析技术和双环己酮草酰二腙光度法相结合,建立了测定工业废水中铜的快速、简便分析方法。方法的线性范围为0 mg/L～10 mg/L,分析速率可达55次/h,应用于工业废水样的测定,加标回收率在95.5%～104.0%之间,结果令人满意。     

在线消解流动注射分光光度法测定废水中总氮

为了克服传统分析法消解条件苛刻,工作效率低的缺点,采用微波在线消解水样,并将流动注射分析技术与N-(1-萘基)乙二胺光度法相结合,建立了一种测定水中总氮的分析方法。通过优化试剂浓度等实验条件,总氮的检出限为0.03mg/L,线性范围为0.03～3.5mg/L。对TN-203214的标准样品进行测定的结果与推荐值基本一致。应用于废水样的测定,加标回收率为96.8%～97.3%。     

FIA技术在水质监测分析中的应用

通过使用Lachat流动注射分析仪测定环境水样中的四个常规项目总磷、总氮、挥发酚和总氰来介绍兀A技术在水质分析领域的应用。实验结果表明,各项目的标样测定值均在保证值范围之内,相对标准偏差在0．2％-3．7％之间。方法的精密度及准确度较好,加标回收率在91％-102％之间,满足水质监测实验室质量控制的要求。     

流动注射法测定水中高锰酸盐指数的研究

研究了用流动注射分析技术测定水体中高锰酸盐指数。使用新发明的耐腐蚀恒流泵、低记忆高效混合器、不存留气泡流通池等部件,通过高温高压,缩短消解时间,从而建立了一种可用于无人值守的自动在线快速监测水体中高锰酸盐指数的分析方法。通过实验研究了流动注射法测定水中高锰酸盐指数的优越性。对方法的检出限、精密度和准确度进行了测定,并与GB／T11892—89《水质高锰酸盐指数的测定》进行了比对,取得了满意的结果。