基于SPA模型的煤矿瓦斯危险源风险评价

根据危险源理论和三类危险源的观点,采用集对分析(SPA)方法,进行了安全一事故集对的同异反分析,指出应采取措施控制不确定项,尤其要控制其中的第二类、第三类危险源才能使系统趋于安全状态;同时建立了煤矿瓦斯危险源风险评价模型,通过联系度的计算得出煤矿瓦斯的安全等级.研究表明,将集对分析方法应用于某煤矿瓦斯危险源风险评价,计算简单,结果较为精确、可靠,为不确定系统的评价提供了一条新思路.     

pp´DDT and pp´DDE Accumulation in a Food Chain of Lake Maggiore (Northern Italy): Testing Steady-State Condition

- DOI: http://dx.doi.org/10.1065/espr2006.01.010 Background, Aims and Scope Although pp'DDT usage was strongly limited or banned in most parts of the world during the last three or four decades, the parent compound, its homologues and their metabolites still occur at levels which might pose a risk for many ecosystem components. A case of DDT pollution of industrial origin was discovered in 1996 in Lake Maggiore, the second largest (212 km2) and deepest (370 m) lake in Italy, causing concern for wildlife and human health. The extensive monitoring of many biotic and abiotic compartments which followed from 1998 in order to assess the pollution level and its trend in time, provided a great availability of data referring to DDT contamination of the different fish species of the lake. In this study, the recent contamination levels in selected fish species were compared to those measured in 1998 to evaluate the temporal pollution trend of the lake and its natural recovery, given that no remediation measures were carried out on the contaminated soils and sediments in this time span. Moreover, a modelling approach to test the equilibrium condition between water and pelagic fish species was used. Analytical results of pp'DDT and pp'DDE concentrations in lake water were used as input data in the bioenergetic model by Connolly & Pedersen (1988) to calculate concentrations in two fish species and to compare the predicted and the measured contamination. Methods Sampling and analytical determination of DDT homologues in lake water: Five water sampling campaigns were carried out from May 2002 to February 2004 in three sampling sites of Lake Maggiore. Suspended and dissolved pollutants were determined separately. Quantitative DDT homologue analyses were performed by HRGC coupled with ECD detection by the external standard method. Single water extracts were put together in correspondence with the stratification zones of the water column inferred on the basis of the temperature profile to improve analytical sensitivity. Selection of fish data: Concentrations of DDT and DDE in fishes were selected from recent literature (CIPAIS 2003, 2004). Bioaccumulation model: The bioenergetic model proposed by Connolly & Pedersen (1988) was used to assess the bioaccumulation of pp'DDT and pp'DDE of Alosa fallax (landlocked shad) and Coregonus spp. (whitefish), selected among the different species as representative of a secondary consumer level. Results and Discussion The average concentrations of pp'DDT and pp'DDE in water to be used as input data in the bioenergetic model were obtained considering all the concentrations measured at the three sampling stations in the epylimnion where the fish species considered in this study spend most of their life. The resulting values were 0.05 and 0.16 ng/L for pp'DDT and pp'DDE, respectively. Average measured pp'DDT and pp'DDE concentrations in landlocked shad were 0.81 +/- 0.39 and 1.69 +/- 0.71 mg/kg lipids, respectively, and were 0.29 +/- 0.12 and 1.06 +/- 0.41 mg/kg lipids for the whitefish. Calculated and measured values turned out to be in quite good agreement for pp'DDT, while measured pp'DDE concentrations were higher than expected on the basis of the bioenergetic model in both species. Probably metabolic transformations of pp'DDT accumulated in fish tissues in the past are responsible for the observed differences between calculated and expected pp'DDE concentrations in fish. Conclusions Pelagic fishes of Lake Maggiore seem to maintain the DDT accumulated during their life time and the most efficient mechanism responsible for the fish population recoveries is probably their generation changes; for this reason, equilibrium models cannot be used until negligible pp'DDT concentrations are reached in fish tissues. Recommendations and Outlook The limit proposed for pp'DDT in water by the EU Directive 2000/60, which will come in force in 2008, is 0.2 ng/L, four times higher than the average concentration measured in Lake Maggiore waters. Nevertheless, concentrations measured in Lake Maggiore fish were very close and sometimes exceeded the Maximum residue limits (MRLs) settled by the Italian legislation for foods (0.1 mg/kg w.w. for fish containing 5–20% lipid). It seems, therefore, that the 'environmental quality standard' of 0.2 ng/L cannot guarantee the suitability of fish for human consumption.     

纳米Al_2O_3和Cd联合暴露对铜锈环棱螺体内Cd的生物积累和抗氧化酶活性的影响

金属氧化物纳米颗粒的广泛应用导致它们大量地释放到水环境中,其独特的理化性质有可能改变水环境中其他共存污染物(如重金属)的生态毒性。为评价沉积物中纳米氧化铝(Al2O3-NPs)对重金属Cd生态毒性的影响,采用底栖生物慢性暴露研究了Al2O3-NPs存在条件下Cd在底栖动物铜锈环棱螺体内生物积累的变化和Cd对肝胰脏抗氧化防御系统关键成分超氧化物歧化酶(SOD)与脂质过氧化指标丙二醛(MDA)以及Ⅱ相反应的关键酶谷胱甘肽-S-转移酶(GST)的影响。结果表明,低Cd浓度(5μg·g-1)时,Al2O3-NPs对Cd生物积累没有影响;中、高Cd浓度(25、100μg·g-1)时,Al2O3-NPs显著促进Cd的生物积累,Al2O3-NPs对Cd的生物转运具有明显的携带效应。低Cd浓度时,无Al2O3-NPs处理组和Al2O3-NPs处理组的SOD活性与对照组相比均没有显著差异;中Cd浓度时,SOD活性显著升高,而高Cd浓度时,SOD活性显著下降,而且Al2O3-NPs处理组的SOD活性显著低于无Al2O3-NPs处理组,Al2O3-NPs的存在加重了Cd对肝胰脏细胞的氧化胁迫或损伤。高Cd浓度时,无Al2O3-NPs处理组和Al2O3-NPs处理组的MDA水平均显著升高,但Al2O3-NPs处理组的MDA水平显著低于无Al2O3-NPs处理组,进一步证明Al2O3-NPs对Cd氧化损伤的增强作用。中、高Cd浓度时,无Al2O3-NPs处理组和Al2O3-NPs处理组的GST活性均显著下降,但Al2O3-NPs处理组的GST活性均显著低于无Al2O3-NPs处理组,同样说明了Al2O3-NPs对Cd毒性的增强作用。本研究提供了在沉积物-底栖动物体系中Al2O3-NPs促进重金属生物积累的证据,而且Cd毒性的变化与肝胰脏中Cd的生物积累水平的变化基本一致,在中、高Cd浓度下,由于Al2O3-NPs的存在显著促进了Cd的生物积累,因而增强了Cd对铜锈环棱螺的生态毒性。     

油库泵站可燃气体智能型安全检测系统

根据目前油库泵站内存在可燃气体经常泄漏的实际情况,提出并应用计算机信息处理系统解决可燃气体泄漏监控问题。     

三峡库区陆生植物迁地保存初报

三峡植物物种多样性保护,重点在珍稀濒危植物,但对建群种和有实用价值的种也进行收集保存。7年来试验站保存三峡库区植物200余种,迁移成活率93%,有8种未成功。（1）到2002年已有30余种植物正常开花结实（其中木本植物24种）,可以选择繁殖试验,以达到保存的目的;（2）选择了8种植物,进行生长观测,在人为控制下,生长速度满意;（3）进行了部份种类的扦插繁殖和孢子繁殖,获得了相关结果;（4）少数种类收集遇到极大困难,需要继续努力。三峡库区生物多样性研究与保护,存在一些问题与困难,如漏项问题、库区物种问题、外来种问题、隔离对生物多样性的影响问题、生物多样性的功能问题等需要进一步研讨,从而使库区物种得以保存,环境得以优化,生物资源得到持续利用。     

江苏沿江开发研究

随着中国加入WTO和经济全球化进程的加快,长江三角洲以其独特的滨江临海的区位和发达的制造业基础,正在成为新的投资热点地区。江苏省沿江地区是长江三角洲重要的组成部分,拥有800多km的长江岸线和8个经济发达、人才资源优势明显的经济中心城市。传统的制造业基础和相对低廉的加工成本、商务成本,使江苏沿江开发既有对外来资本的吸引力,又有自我发展的内生机制。重点研究了全球化背景下江苏沿江开发的战略问题,主要包括：①江苏沿江地区开发的环境和条件比较分析;②沿江产业带重组与实施跨江开发;③再造新战略据点;④打破行政区界限沿江联动实施区域一体化,等等。最后指出：加快江苏沿江开发,必须科学规划、统筹安排,做到空间合理、时间有序,同时考虑沿江的环境容量有限,应实施可持续发展和南北联动的开发战略,拓展沿江的开发空间,提升沿江的产业发展水平。     

武钢签订安全生产目标责任状制度概述

概略地分析了武钢安全生产目标责任状制度的内容、作用和目的 ,以及实施和管理该责任制的一些主要做法、措施。通过实施签订安全生产目标责任状制度 ,促使各级领导、各部门落实安全生产责任制 ,取得了成效 ,确保了安全生产     

转cry1Ab基因水稻中毒蛋白的表达、分泌及其在土壤中的残留

研究了转cry1Ab基因水稻(克螟稻)中Cry1Ab毒蛋白的表达、根系分泌及其在土壤中的残留规律.结果表明,分蘖始期至成熟期,克螟稻地上部和根部中的Cry1Ab毒蛋白的表达量(FW)分别为3.23～8.22 μg/g和0.68～0.89 μg/g.生育期间克螟稻根系分泌的Cry1Ab毒蛋白含量仅为1.66～48.02 ng/(株·d).试验证实,克螟稻根际土中的Cry1Ab毒蛋白残留含量低于检测限(<0.5ng/g 干燥土).生物测定还表明,克螟稻根际土及其提取液对棉铃虫初孵幼虫和3龄幼虫不产生致死性效应.相对于Cry1Ab毒蛋白的根系分泌转移,克螟稻秸秆还田对土壤环境的影响应引起重视.     

某冶炼厂周边土壤环境Cd元素现状调查、污染预警及综合治理

对某冶炼厂以南约30km^3的区域进行了Cd元素土壤地球化学调查,分析了造成Cd富集的原因。通过统计分析,总结了土壤中Cd含量的空间分布特征(包括区域分布和垂向分布),并结合Cd元素的赋存形式、迁移机制对这些特征的成因进行了较为具体的解释。计算了该区cd的污染指数,以及受不同程度污染的土壤面积占研究区面积的百分比。运用“化学定时炸弹”的理论,对该区土壤达到I}缶界含量的年限进行了估测。针对该区的污染来源及状况,提出了综合治理对策。     

工业动火防护方法的探讨

介绍了在石油生产设备设施的建设安装和检修动火过程中 ,工程技术人员创造发明的防护盲板、防护接地、加装管道扫线接口和绝缘螺栓4种防护方法 ,简要叙述它们的结构、用途和适用范围 ,为油田施工单位进行动火作业提供技术参考。