全文获取类型
收费全文 | 286篇 |
免费 | 25篇 |
国内免费 | 29篇 |
专业分类
安全科学 | 86篇 |
废物处理 | 12篇 |
环保管理 | 20篇 |
综合类 | 120篇 |
基础理论 | 25篇 |
污染及防治 | 35篇 |
评价与监测 | 5篇 |
社会与环境 | 1篇 |
灾害及防治 | 36篇 |
出版年
2023年 | 1篇 |
2022年 | 9篇 |
2021年 | 11篇 |
2020年 | 10篇 |
2019年 | 7篇 |
2018年 | 4篇 |
2017年 | 12篇 |
2016年 | 8篇 |
2015年 | 10篇 |
2014年 | 12篇 |
2013年 | 15篇 |
2012年 | 23篇 |
2011年 | 31篇 |
2010年 | 20篇 |
2009年 | 12篇 |
2008年 | 18篇 |
2007年 | 20篇 |
2006年 | 20篇 |
2005年 | 12篇 |
2004年 | 14篇 |
2003年 | 13篇 |
2002年 | 12篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1999年 | 4篇 |
1998年 | 8篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 4篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有340条查询结果,搜索用时 78 毫秒
21.
给水管壁生物膜会吸附水中的重金属元素积累在管壁生物膜中,在受到扰动时释放回到水体,危害饮用水水质安全。试验以上海管网末梢水为实验对象,研究了PVC、铸铁和紫铜等三种管材上生物膜对铅、镉的解吸特性。结果表明,PVC、铸铁和紫铜附着生物膜对铅的解吸容量qe分别为:5.92211μmol·m^-2、128.3051μmol·m^-2和21.1808,解吸速率常数k分别为:0.001060 m^2·μmol^-1·min^-1、0.000041 m^2·μmol^-1·min^-1和0.000503 m^2·μmol^-1·min^-1,对于镉元素三种材质的解吸容量qe分别为:14.71519μmol·m^-2、18.50481μmol·m^-2和2.25225μmol·m^-2;解吸速率常数k分别为:0.000102 m^2·μmol^-1·min^-1、0.001070 m^2·μmol^-1·min^-1和0.000103 m^2·μmol^-1·min^-1。 相似文献
22.
以祖山为例,阐述了崩塌地质灾害的机理、特征和现状,并利用传递系数法对崩塌稳定性进行了计算和评价,采用削方卸载、修建抗崩塌挡土墙、构筑排水沟与格构等工程设施的防治对策及工程措施,取得了预期的效果。 相似文献
23.
Dimkpa CO Calder A Britt DW McLean JE Anderson AJ 《Environmental pollution (Barking, Essex : 1987)》2011,159(7):1749-1756
The toxicity of commercially-available CuO and ZnO nanoparticles (NPs) to pathogenic bacteria was compared for a beneficial rhizosphere isolate, Pseudomonas chlororaphis O6. The NPs aggregated, released ions to different extents under the conditions used for bacterial exposure, and associated with bacterial cell surface. Bacterial surface charge was neutralized by NPs, dependent on pH. The CuO NPs were more toxic than the ZnO NPs. The negative surface charge on colloids of extracellular polymeric substances (EPS) was reduced by Cu ions but not by CuO NPs; the EPS protected cells from CuO NPs-toxicity. CuO NPs-toxicity was eliminated by a Cu ion chelator, suggesting that ion release was involved. Neither NPs released alkaline phosphatase from the cells’ periplasm, indicating minimal outer membrane damage. Accumulation of intracellular reactive oxygen species was correlated with CuO NPs lethality. Environmental deposition of NPs could create niches for ion release, with impacts on susceptible soil microbes. 相似文献
24.
25.
The aim of this study was to find out whether ingested titanium dioxide nanoparticles (nano-TiO2) cause cell membrane damage by direct contact or by lipid peroxidation. We assessed lipid peroxidation and digestive gland cell membrane stability of animals fed on food dosed with nano-TiO2. Conventional toxicity measures were completed to determine if cellular effects are propagated to higher levels of biological complexity. An invertebrate model organism (Porcellio scaber, Isopoda, Crustacea) was fed with food containing nanosized TiO2 and the result confirmed that at higher exposure concentrations after 3 d exposure, nano-TiO2 destabilized cell membranes but lipid peroxidation was not detected. Oxidative stress as evidenced by lipid peroxidation was observed at longer exposure durations and high exposure doses. These data suggest that cell membranes are destabilized by direct interactions between nanoparticles and cell membrane, not solely via oxidative stress. 相似文献
26.
The present study was to isolate and identify a potent algicidal compound from extract of Salvia miltiorrhiza and study the potential inhibition mechanism on Microcystis aeruginosa. Column chromatography and bioassay-guided fractionation methods were carried out to yield neo-przewaquinone A, which was identified by spectral analysis. The EC50 of neo-przewaquinone A on M. aeruginosa were 4.68 mg L−1. In addition, neo-przewaquinone A showed relatively higher security on Chlorella pyrenoidosa and Scenedesmus obliquus, with the EC50 values of 14.78 and 10.37 mg L−1, respectively. For the potential inhibition mechanisms, neo-przewaquinone A caused M. aeruginosa cells morphologic damage or lysis, increased malondialdehyde content and decreased the soluble protein content, total antioxidant and superoxide dismutase activity, and significantly inhibited three photosynthesis-related genes (psaB, psbD, and rbcL). The results demonstrated the algicidal effect of neo-przewaquinone A on M. aeruginosa and provided the possible inhibition mechanisms. 相似文献
27.
Benzene is a representative member of volatile organic compounds and has been widely used as an industrial solvent. Groundwater contamination of benzene may pose risks to human health and ecosystems. Detection of benzene in the groundwater using chemical analysis is expensive and time consuming. In addition, biological responses to environmental exposures are uninformative using such analysis. Therefore, the aim of this study was to employ a microorganism, Euglena gracilis (E. gracilis) as a putative model to monitor the contamination of benzene in groundwater. To this end, we examined the wild type of E. gracilis Z and its mutant form, SMZ in their growth rate, morphology, chlorophyll content, formation of reactive oxygen species (ROS) and DNA damage in response to benzene exposure. The results showed that benzene inhibited cell growth in a dose response manner up to 48 h of exposure. SMZ showed a greater sensitivity compared to Z in response to benzene exposure. The difference was more evident at lower concentrations of benzene (0.005–5 μM) where growth inhibition occurred in SMZ but not in Z cells. We found that benzene induced morphological changes, formation of lipofuscin, and decreased chlorophyll content in Z strain in a dose response manner. No significant differences were found between the two strains in ROS formation and DNA damage by benzene at concentrations affecting cell growth. Based on these results, we conclude that E. gracilis cells were sensitive to benzene-induced toxicities for certain endpoints such as cell growth rate, morphological change, depletion of chlorophyll. Therefore, it is a potentially suitable model for monitoring the contamination of benzene and its effects in the groundwater. 相似文献
28.
为了研究钢筋混凝土防爆墙的抗爆能力,采用有限元分析方法对不同纵向配筋率、不同高跨比、不同厚度的墙体在爆炸动态荷载作用下的动力响应进行研究,对各种不同设置的钢筋混凝土防爆墙的抗爆性能进行评估。结果表明:减小高跨比对提高钢筋混凝土防爆墙的抗爆能力最为重要,提高纵向配筋率,增加厚度都能增加防爆墙的抗爆能力。 相似文献
29.
Sumana Siripattanakul Wanpen Wirojanagud John McEvoy Eakalak Khan 《Water, Air, & Soil Pollution: Focus》2008,8(3-4):257-266
Atrazine biodegradation by immobilized pure and mixed cultures was examined. A pure atrazine-degrading culture, Agrobacterium radiobacter J14a (J14a), and a mixed culture (MC), isolated from an atrazine-contaminated crop field, were immobilized using phosphorylated-polyvinyl
alcohol (PPVA). An existing cell immobilization procedure was modified to enhance PPVA matrix stability. The results showed
that the matrices remained mechanically and chemically stable after shaking with glass beads over 15 days under various salt
solutions and pH values. The immobilization process had a slight effect on cell viability. With the aid of scanning electron
microscopy, a suitable microstructure of PPVA matrices for cell entrapment was observed. There were two porous layers of spherical
gel matrices, the outside having an encapsulation property and the inside containing numerous pores for bacteria to occupy.
J14a and MC were immobilized at three cell-to-matrix ratios of 3.5, 6.7, and 20 mg dry cells/mL matrix. The atrazine biodegradation
tests were conducted in an aerobic batch system, which was inoculated with cells at 2,000 mg/L. The tests were also conducted
using free (non-immobilized) J14a and MC for comparative purpose. The cell-to-matrix ratio of 3.5 mg/mL provided the highest
atrazine removal efficiency of 40–50% in 120 h for both J14a and MC. The free cell systems, for both cultures, presented much
lower atrazine removal efficiencies compared to the immobilized cell systems at the same level of inoculation. 相似文献
30.
垂直面绿化植物遮阳系数与叶面积指数研究 总被引:6,自引:0,他引:6
李娟 《城市环境与城市生态》2001,14(5):4-5
比较、分析了农业研究中提出的叶面积指数LAI与用于建筑节能领域的垂直面绿化植物叶片遮阳系数SCPVW两个概念的异同和各自的应用范围。指出城市绿化采用水平或垂直绿化方式时,由于下垫面差异,植物叶片的遮阳系数应当分别采用LAI和SCPVW进行计算。 相似文献