Role of glycine on sulfuric acid-ammonia clusters formation: Transporter or participator

Glycine(Gly) is ubiquitous in the atmosphere and plays a vital role in new particle formation(NPF).However,the potential mechanism of its on sulfuric acid(SA)-ammonia(A)clusters formation under various atmospheric conditions is still ambiguous.Herein,a(Gly)_x·(SA)_y·(A)_z(z≤x+y≤3) multicomponent system was investigated by using density functional theory(DFT) combined with Atmospheric Cluster Dynamics Code(ACDC) at different temperatures and precursor concentrations.The results show that Gly,with one carboxyl(-COOH) and one amine(-NH_2) group,can interact strongly with SA and A in two directions through hydrogen bonds or proton transfer.Within the relevant range of atmospheric concentrations,Gly can enhance the formation rate of SA-A-based clusters,especially at low temperature,low [SA],and median [A].The enhancement(R) of Gly on NPF can be up to 340 at T=218.15 K,[SA]=10~4,[A]=10~9,and [Gly]=10~7 molecules/cm~3.In addition,the main growth paths of clusters show that Gly molecules participate into cluster formation in the initial stage and eventually leave the cluster by evaporation in subsequent cluster growth at low [Gly],it acts as an important "transporter" to connect the smaller and larger cluster.With the increase of [Gly],it acts as a "participator" directly participating in NPF.     

过硫酸钾氧化-紫外光度法测定总氮方法的改进

过硫酸钾氧化紫外光度法测定总氮的空白吸光度高的主要原因是：K2S2O3是220nm波长上有特征吸收，适当降低K2S2O3、NaOH的用量，延长消解时间，使用二次蒸馏水，用低浓度亚砷酸钠溶液，还原消解后剩余的极少量的K2S2O3，可以降低空白吸光度。K2S2O3-NaOH碱溶液不稳定，使用期短，三天后氧化能力迅速降低，原因是：K2S2O3溶液中，加入NaOH，加速了K2S2O3的分解。K2S2O3和NaOH分别配制，并在K2S2O3溶液中，加入少量HCl，抑制其水解。两种溶液可使用半年以上时间。     

曲面零件在拉深过程中内皱时刻及影响因素

进一步推导了曲面零件悬空区上的应力分布及临界失稳公式。然后通过计算机编程 ,求解了临界失稳方程 ,得到了拉深系数、相对锥顶半径、相对圆角半径、材料相对厚度与临界失稳时刻间的关系曲线 ,并对曲线变化的规律进行了分析。     

大气可吸入颗粒物研究进展

简述了国内外有关大气颗粒物中的可吸入颗粒物 (空气动力学直径小于或等于 10 μm)的研究进展 ,主要围绕可吸入颗粒物的基本特性、可吸入颗粒物与健康的关系、可吸入颗粒物的源解析 ,对其研究动向进行阐述。     

温差拉深法在制造大型杯形件中的应用

用温差拉深法制造大型杯形件毛坯,可避免毛坯拉断和起皱,最大限度地降低拉深系数、减少拉深次数、降低加工成本。     

Influence of chlorsulfuron herbicide on size of microbial biomass in the soil

ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｕｓｅｏｆｃｈｅｍｉｃａｌｓ,ｉｎｃｌｕｄｉｎｇｐｅｓｔｉｃｉｄｅｓ,ｈａｓｂｅｃｏｍｅａｎｉｎｔｅｇｒａｌａｎｄｅｃｏｎｏｍｉｃａｌｌｙｅｓｓｅｎｔｉａｌｐａｒｔｏｆｍｏｄｅｒｎａｇｒｉｃｕｌｔｕｒｅ.Ｐｅｓｔｉｃｉｄｅ?..     

冷拉螺旋叶片展开的精确算法

提出了一种新的、更趋精确合理的关于冷拉螺旋叶片坯料的展开与放样计算方法 ,并从实践中探索出叶片在展开与放样时其内径的精确修正系数k之值。     

Petro-chemical wastewater treatment by biological process

Ｉｎｔｈｅｃｏｕｒｓｅｏｆｏｉｌｒｅｆｉｎｉｎｇ,ｏｒｇａｎｉｃｗａｓｔｅｗａｔｅｒｗｉｔｈｈｉｇｈｃｏｎｃｅｎｔｒａｔｉｏｎｏｆｅｍｕｌｓｉｆｉｅｄｏｉｌａｎｄｐｈｅｎｏｌｉｓｐｒｏｄｕｃｅｄ,ｓｏｆａｒ,ｔｈｅｍｅｔｈｏｄｓｏｆｐｈｙｓｉｃｏｃｈｅ?..     

On the study of ecosystem health:state of the art

ＩｎｔｒｏｄｕｃｔｉｏｎＤｕｒｉｎｇｌａｓｔｄｅｃａｄｅｓ,ｔｈｅｔｅｒｍ“ｅｃｏｓｙｓｔｅｍｈｅａｌｔｈ”ｉｓｕｓｅｄｗｉｔｈｉｎｃｒｅａｓｉｎｇｆｒｅｑｕｅｎｃｙｉｎｔｈｅｌｉｔｅｒａｔｕｒｅ.Ｔｈｅｇｒｏｗｉｎｇｉｎｔｅｒｅｓｔｓｉｎｔｈｅｓｔｕ...     

Stipulation of the criteria for the construction of eco agricultural county in China

ＩｎｔｒｏｄｕｃｔｉｏｎＮｏｗｗｅａｌｌｃｏｎｃｅｒｎｏｕｒｓｅｌｖｅｓｗｉｔｈｔｈｅｃｏｎｔｅｍｐｏｒａｒｙｐｒｏｂｌｅｍｓｏｆｏｖｅｒｐｏｐｕｌａｔｉｏｎ,ｒｅｓｏｕｒｃｅｅｘｐｌｏｉｔａｔｉｏｎ,ｅｎｖｉｒｏｎｍｅｎｔａｌｐｏｌｌｕｔｉｏｎａｎｄ...