首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   219篇
  免费   15篇
  国内免费   60篇
安全科学   50篇
环保管理   20篇
综合类   161篇
基础理论   14篇
污染及防治   9篇
评价与监测   22篇
社会与环境   1篇
灾害及防治   17篇
  2022年   6篇
  2021年   6篇
  2020年   6篇
  2019年   5篇
  2018年   2篇
  2017年   5篇
  2016年   6篇
  2015年   8篇
  2014年   9篇
  2013年   12篇
  2012年   10篇
  2011年   10篇
  2010年   8篇
  2009年   5篇
  2008年   16篇
  2007年   8篇
  2006年   8篇
  2005年   8篇
  2004年   21篇
  2003年   22篇
  2002年   19篇
  2001年   8篇
  2000年   46篇
  1999年   3篇
  1998年   7篇
  1997年   7篇
  1996年   1篇
  1995年   3篇
  1994年   9篇
  1993年   3篇
  1992年   3篇
  1991年   1篇
  1989年   1篇
  1988年   1篇
  1979年   1篇
排序方式: 共有294条查询结果,搜索用时 812 毫秒
41.
目的研制开发"海军航空装备保障统筹图绘制系统",实现海军航空装备保障管理智能化,有效利用保障资源,提高保障工作效率。方法采用C/S和B/S模式相结合,前台以NevronNETVision为系统开发平台,后台数据管理采用大型关系型数据库SQLServe,通过网络计划技术和AOE网分析技术,实现图形绘制和确定关键路线。结果通过导入Excel工作薄,实现统筹图、甘特图、资源载荷图的自动生成,提供可视化的图形编辑和统筹图的规范性检查,能进行关键路径、时间参数计算和人员负荷分析。结论 "海军航空装备保障统筹图绘制系统"智能、高效,为海军航空装备保障管理智能化提供了技术支持。  相似文献   
42.
Delphin JE  Chapot JY 《Chemosphere》2006,64(11):1862-1869
A field experiment was conducted on a Calcaric Cambisol soil to study the consequences of the penetration depth and properties of pesticides on the risk of subsequent leaching. Three pesticides with different mobility characteristics and bromide were injected at 30 cm (where soil organic matter (OM) was 2%) and 80 cm (soil OM 0.5%) on irrigated plots without a crop. The migration of injected solutes was assessed for two years by sampling the soil solution using six porous cups installed at 50 and 150 cm depth and by relating solute contents to drainage water flux estimated by the STICS model (Simulateur mulTIdisciplinaire pour les Cultures Standard). Pesticides injected at 30 cm were strongly retained so that no metolachlor or diuron was detected at 50 and 150 cm. The ratio of atrazine peak concentration in the soil solution to concentration in the injected solution (C/C0) was 1 × 10−3 and 0.2 × 10−3, respectively, at 50 and 150 cm. When injected at 80 cm, (C/C0) of atrazine, metolachlor and diuron were 10 × 10−3, 1 × 10−3 and 0.3 × 10−3 at 150 cm, respectively; 1/(C/C0) was correlated with Koc values reported from databases. The ratio of drainage volume to the amount of water at field capacity in the soil layer between the injection point at 30 cm and the water sampling level (V/V0) at 50 and 150 cm was 0.6 and 0.9, respectively, for bromide and 1.6 and 1.0 for atrazine. V/V0 of the injected solutes at 80 cm was for bromide, atrazine, metolachlor and diuron 0.6, 0.9, 1.2 and 1.7, respectively; pesticide V/V0 was correlated with Koc. The retardation factor was a good indicator of migration risk, but tended to overestimate retardation of molecules with high Koc. Atrazine desorption represented an additional leaching risk as a source of prolonged low contamination. The large variability in soil solution of bromide and pesticide concentrations in the horizontal plane was attributed to flow paths and clods in the tilled soil layer. This heterogeneity was assumed to channel water fluxes into restricted areas and thereby increase the risk of groundwater contamination. The methodology used in the field proves to provide consistent results.  相似文献   
43.
The flash point temperature of Tri-n-butyl phosphate(TBP) and Tri-iso-amyl phosphate(TiAP) in n-dodecane binary mixture has been measured for the entire concentration range using the continuously closed cup flash point apparatus based on the ASTM D6450 method. The flash point was predicted using the UNIFAC group contribution model. The measured flash point was also compared with the prediction from the NRTL, UNIQUAC and Ideal solution models. The UNIFAC model is able to predict the flash point fairly well for the TBP–dodecane mixture and for TiAP–dodecane mixture no improvements is obtained over the ideal solution assumption. The flash point shows positive deviation from ideal solution behavior for both the binary mixture.  相似文献   
44.
Research on the micro- and macrocharacteristics of different metamorphic degrees of coal helps improve the control and protection techniques used during spontaneous combustion. Nine coals with different properties were thoroughly investigated in this study. Fourier transform infrared spectroscopy and a self-designed temperature-programmed oil bath experimental system were adopted to analyze the molecular structure and macrocharacteristic parameters of the spontaneous combustion of coal. Additionally, the influence of particle size on spontaneous combustion was considered. Various functional groups were employed as microcharacteristic parameters to capture the principal active groups in oxidation. The gas production rate, oxygen consumption rate, gas concentration, heat energy release rate, and characteristic temperatures were evaluated as macrocharacteristic parameters to investigate the changes in coal during oxidation. The results establish that the microcharacteristics of coal molecules determine the degree of spontaneous combustion based on intrinsic properties and that changes in the macrocharacteristics of the spontaneous combustion of coal reflect the microstructural changes. The contents of the hydroxyl groups, carbonyl groups, alkyl ether and aryl ether in the coal molecules gradually decrease with the metamorphic increase. Oxygen-containing functional groups have higher reactivities and easily react with oxygen, causing the macroparameters, such as the oxygen consumption rate, the gas generation rate and the heat energy release rate, to consistently decrease with the increase of the metamorphic degree. Small-particle-size coal molecules have more active aliphatic hydrocarbons, oxygen-containing functional groups and a larger specific surface area, increasing the chances of adsorbing the oxygen of active groups and promoting the reaction between coal and oxygen. The experimental results indicate that coal samples with higher metamorphic degrees or larger sizes exhibit lower tendencies toward spontaneous combustion. Evaluation of the spontaneous combustion of coal based on a temperature-programmed oil bath experimental system is of great practical importance for preventing the spontaneous combustion of coal during storage, processing and utilization and can serve as a convenient reference for production safety in mining applications.  相似文献   
45.
万群 《环境导报》2000,(5):19-20
“W型低NOx环保燃烧器”采用先进的复合多级混合式雾化技术,强化喷射、混合和扩散,燃烧充分从而控制NOx生成。  相似文献   
46.
事故致因模型是用于事故原因分析和预防的重要理论依据,模型的可操作性是决定事故预防效果的重要影响因素。对目前国内研究较为持续和系统的事故致因"2-4"模型进行了深入研究,以增强其在事故分析时的可操作性。首先,研究了事故致因"2-4"模型中组织内、外部原因的各个阶段原因因素的划分情况;其次,根据得到的各阶段原因因素划分结果,对应用事故致因"2-4"模型分析事故原因的因素进行了编码;最后,以一起重大瓦斯爆炸事故为例,对事故致因"2-4"模型原因因素编码系统的有效性进行了实证研究。划分了事故致因"2-4"模型中的各原因模块中的原因因素,并得到了不安全动作和物态、习惯性不安全行为、安全管理体系、安全文化、外部因素等5个层级原因,确定了基于事故致因"2-4"模型的30个原因因素。对事故原因因素进行系统编码,提高了应用事故致因"2-4"模型进行事故原因分析和事故预防的可操作性,增强了其应用实践性。  相似文献   
47.
我国北方有众多中小城镇 ,其环境质量大都有一定特点。本文根据多年的环境监测资料 ,以沈阳郊区新城子区年 ,季间的环境质量变化 ,研究其污染特性和特点 ,分析不同时空变化的环境质量。争取中小城镇的环境综合治理提供技术依据。大气污染主要集中在冬季 ,燃煤污染仍然是主要污染来源 ;水环境污染以城镇生活污水为主 ,而且环境水的缺少又给环境带来了巨大的压力  相似文献   
48.
扑救森林火灾安全准则   总被引:2,自引:0,他引:2  
从分析火场特征、危险条件出发,详细阐述了扑火队员在扑火过程中的行为准则和应注意的安全事项以及避险的方式方法。  相似文献   
49.
市政污泥热解过程中重金属迁移特性及环境效应评估   总被引:3,自引:3,他引:0  
姜媛媛  王彦  段文焱  左宁  陈芳媛 《环境科学》2021,42(6):2966-2974
以昆明某市政污泥为原料,研究生物炭制备过程中重金属Fe、Zn、Mn和Ni的迁移特性,并基于其潜在环境风险确定污泥基生物炭制备的最佳热解温度.本实验选择总量较高的4种重金属Fe、Zn、Mn和Ni,采用BCR提取法测定不同热解温度下4种重金属的形态和含量变化,得到各金属的形态分布变化规律和迁移路径,利用潜在生态风险指数(PERI)和风险评估代码(RAC)对污泥基生物炭进行环境风险评估.结果表明,4种金属的易挥发程度排序为Zn > Mn > Fe > Ni,4种金属形态分布情况和变化规律各不相同,但迁移路径具有共通性.在低温热解阶段,不稳定形态向稳定形态转化;随着温度的升高,可氧化态和残渣态逐步分解破碎,部分逸散到大气中,部分形成可还原态.在环境风险评估方面,高温条件(>500℃)下制备的生物炭环境风险较低,500℃制备的生物炭经济性最好.  相似文献   
50.
典型山区燃煤型电厂周边土壤重金属形态特征及污染评价   总被引:3,自引:0,他引:3  
为了揭示毕节金沙电厂周边土壤重金属(Hg、As、Cd、Cr、Cu、Pb和Zn)污染状况,在电厂周围采集了32个土壤表层样品,采用改进的BCR连续提取法进行形态分析,并以Hakanson潜在生态危害指数法、改性灰色聚类法及风险评估编码法(RAC)进行生态风险评估.结果表明:重金属含量变化具有一定的空间变异结构和空间分布特征,除了Cd和Cr的含量平均值低于贵州省土壤平均背景值外,其余重金属含量的平均值均大于该背景值.土壤中的大部分重金属主要以残渣态形式存在,而Cd主要以酸可提取态和可还原态存在,具有很强的环境危害.相关性分析结果显示,Hg与As、Cd表现为极显著相关,而Zn与其余重金属元素相关性都较弱.生态风险评价得出7种重金属的生态风险大小顺序为Cd > Hg > As > Cu > Pb > Zn > Cr,综合潜在生态风险指数(RI)平均值为129.72,处于中等生态风险.通过改性灰色聚类法对土壤重金属污染进行分析评价,表明电厂西面污染明显高于东面,且Hg和Cd为主要污染物;由风险评估编码法得出元素Cd有效态占18.17%,对环境构成中等风险等级,元素Cr和Zn对环境的危害处于低风险状态,元素Hg、Pb、As和Cu处于无风险状态.综合以上研究结果,金沙电厂土壤受到不同程度的重金属污染,应特别重视Hg和Cd这两种重金属污染的治理.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号