重大突发事件下应急冷链供应链协同化评价模型及策略研究*

为有效规避冷链供应链受突发事件带来的不利影响,并强化其应急体系协同化发展,提出基于层次分析法和序参量法的应急冷链供应链协同化水平评价模型。模型以供应链协同化理论为基础,从协同化目标入手构建影响其协同化水平的测度指标体系;利用层次分析法确定评价指标的综合权重,最后运用序参量法评估冷链供应链各应急环节的协同度。结果表明:评价模型能有效评估应急冷链供应链协同化水平,可为冷链供应链应对突发事件提供参考。     

Paternity covaries with laying and hatching order in the collared flycatcher Ficedula albicollis

Females in most bird species engage in extra-pair copulations. Although this behaviour is widespread, benefits for females of doing so are less understood. The most widely accepted hypothesis is that they improve their previous choice of social partner and gain genetic benefits for their offspring. Some evidence for this comes from studies that find that extra-pair young (EPY) have greater fitness than their half-sibs. However, this might be also caused by maternal, non-genetic effect, a possibility that remains largely untested. Here we test whether EPY are laid in larger eggs or eggs laid early in the laying sequence in the collared flycatcher (Ficedula albicollis). The size of eggs bearing EPY and within-pair young (WPY) did not differ, however, EPY were laid in early eggs and consequently hatched earlier than WPY. As hatching asynchrony is a strong determinant of offspring size and survival in many species, including collared flycatcher, our results suggest that a caution is needed when paternal genetic effects are to be inferred from comparison of naturally occurring half-sibs.     

提高地电阻率观测精度研究

随着国民经济的快速发展,地电阻率的观测环境受到各种干扰,其中采用直流牵引技术的城市轨道交通干扰尤为严重,致使一些地电阻率观测台站的观测数据无法满足规范要求,部分台站因此被迫搬迁。进一步改善观测系统测量模式,提高其观测精度势在必行。通过多种方法实验,提出了一些抗干扰措施,达到了提高观测精度的目的,为进一步提升地电阻率观测质量做了技术铺垫。     

舰船设备振动试验方法的探讨

目的探讨舰船设备振动试验中的几个问题并提出解决方法。方法分析GJB 150.16A,GJB4.7—83和MIL-STD-167-1A等振动试验标准,找出其中存在的缺点。阐述实验室模拟与实际环境的差异,提出改进建议。结果 GJB 150.16A中没有明确说明随机部分和正弦部分是单独试验还是叠加试验,GJB 4.7—83和MIL-STD-167-1A中没有给出随机振动的条件,只有正弦振动部分。结论对于标准中存在的缺点,在每个轴向,首先进行一半的功能试验,再进行随机叠加正弦/随机振动,最后进行另一半功能试验。对于实验室模拟与实际环境存在差异的问题,通过采用力谱控制、采用模拟舰船结构的夹具、规定安装方式、对环境条件进行反复迭代等方法改进。     

火灾事故致因的多因素灰色关联分析

运用灰色关联分析方法,以河南省6年的火灾事故统计数据为例,通过计算和分析纵火、电气、违反操作规程等多因素与火灾事故间的灰色关联度及灰色关联序;确定出影响火灾事故的主要相关因素;得出火灾多因素与火灾事故间关系的定量化分析结果。该研究为确定火灾因素间的关系提供了一种较为科学的定量评价方法,对分析事故主要原因、掌握火灾事故发生规律提供支撑,对提出有效对策有重要的理论意义和实用价值;同时,有利于减少火灾事故的发生,促进社会的安全与稳定。     

Kinetics of endosulfan sorption on to wood charcoal

Abstract

A part of the research work conducted to evaluate the efficiency of a locally available low cost wood charcoal in removing endosulfan, an organochlorine insecticide, has been presented here in this paper. In the batch experiments conducted at 1 mg/I initial concentration of endosulfan, it was found that wood charcoal could remove endosulfan from water up to 95%. Kinetic profiles were developed for various conditions and they followed second order kinetic reactions. Adsorption equilibrium time was determined by two different approaches namely rough estimate and 2% slope criteria. The equilibrium time was found to be 5 hrs. Forward, reverse, and overall reaction rate constants were determined by approximating the kinetic data to the first order reversible kinetic model. Rate constants increased with increasing initial concentration of endosulfan. Rate limiting process was determined by using kinetics data and further confirmed by the multiple interruption test. Pore and film diffusion coefficients were determined from the half time equations. Film diffusion appeared to be the rate limiting which was further supported by the multiple interruption test.     

A generalized differential method to calculate lumped kinetic triplet of the nth order model for the global one-step heterogeneous reaction using TG data

Computing kinetic triplet is of importance for the process safety of combustion/gasification industries to establish the chemical reaction scheme and to assess the hazardous risk. Few approaches have been capable of calculating lumped kinetic triplet at one time efficiently, which might be attributed to the fact that the analytical solution for the nonlinear ordinary differential equation (NNODE) for the n^th order reaction model has not been found yet. This paper presents an analytical solution of NNODE to compute kinetic triplet. Results showed that the proposed method (mass fraction curve-fitting error ϕ = 1.49%–2.07%) is more efficient to compute kinetic triplet of the n^th order reaction model, comparing to genetic algorithm (GA) optimization (ϕ = 1.43%–1.81%), Coats-Redfern (ϕ = 2.36%–3.16%), peak-shape, and isoconversional methods. A compensation effect between lnA and E_a is observed due to heating rates. Effects of exported data quality and smooth processing on computation of kinetic triplet are discussed. It is the first time that an analytical solution of NNODE (n^th order model) for global one-step heterogeneous reaction is derived for computing kinetic triplet. This work may help to search for analytical solutions of power-law and Avrami-Erofeev models in the future to efficiently calculate kinetic triplet for accelerating and sigmoidal reaction systems.     

泥炭和腐植酸类物质在环境保护中的应用

本文叙述了泥炭的形成、组成、结构、泥炭及腐植酸类物质在环境保护中的广泛应用：用泥炭净化被放射性污染的废水；用泥炭除去废水中的重金属离子；用泥炭净化工业和城市污水；泥炭对水中石油及其产品的吸附；泥炭对大气中有害气体的清除．因此，泥炭和腐植酸类物质是净化生物圈的宝贵资源．     

Effect of goethite coating and humic acid on the transport of bacteriophage PRD1 in columns of saturated sand

The transport of bacteriophage PRD1, a model virus, was studied in columns containing sediment mixtures of quartz sand with goethite-coated sand and using various solutions consisting of monovalent and divalent salts and humic acid (HA). Without HA and in the absence of sand, the inactivation rate of PRD1 was found to be as low as 0.014 day(-1) (at 5+/-3 degrees C), but in the presence of HA it was much lower (0.0009 day(-1)), indicating that HA helps PRD1 to survive. When the fraction of goethite in the sediment was increased, the removal of PRD1 also increased. However, in the presence of HA, C/C0 values of PRD1 increased by as much as 5 log units, thereby almost completely eliminating the effect of addition of goethite. The sticking efficiency was not linearly dependent on the amount of goethite added to the quartz sand; this is apparently due to surface charge heterogeneity of PRD1. Our results imply that, in the presence of dissolved organic matter (DOM), viruses can be transported for long distances thanks to two effects: attachment is poor because DOM has occupied favourable sites for attachment and inactivation of virus may have decreased. This conclusion justifies making conservative assumptions about the attachment of viruses when calculating protection zones for groundwater wells.     

The impact of seasonal variations in DOC arising from a moorland peat catchment on coagulation with iron and aluminium salts

Natural organic matter (NOM) is one of the main sources of environmental pollution to drinking water supplies in much of the UK and the US. Whilst traditional treatment with trivalent coagulants has proven a successful strategy in the past, operational problems are now being reported during periods of elevated organic levels in the water. Characterisation of the pollutants in terms of polarity, molecular weight and charge, provides a method to understand the impact of the observed temporal and spatial variations in terms of a mechanistic parameter relevant to the treatment processes. Results from this study demonstrate that it is not simply the increased organic concentration, but also the change in NOM composition and character, which influences the impact on the treatment processes. Consequently, monitoring of these parameters provides an insight into how to manage the impact caused by environmental changes to the catchments.