瑞平塘河氟化物污染状况调查及溯源研究

以2016—2020年地表水常规监测结果为依据,发现瑞平塘河自2017年起出现氟化物质量浓度升高现象,2020年其中1个断面氟化物质量浓度平均值达到1.25 mg/L,比2016年高出145%。为此于2021年3—6月,对瑞平塘河流域的氟化物污染状况进行实地调查并开展溯源研究。研究结果显示,2021年氟化物质量浓度超过1.0 mg/L的点位占59.34%,其中超过1.5 mg/L的点位占42.86%,表明大部分河道氟化物质量浓度已经超过水体功能区要求,对生态环境安全构成较大潜在风险。溯源调查结果表明,排除了农业源及矿山源污染的可能,乳胶制品企业排放的废水为瑞平塘河氟化物的污染来源。针对目前该行业的排放标准和环境影响评价均未提及氟化物污染,企业废水处理设施也无除氟工艺单元,缺乏有效的污染防治措施与监管要求等问题。提出,应及时组织开展该区域乳胶制品行业整治提升,增加氟化物处理工艺单元,提升出水水质,确定氟化物排放浓度限值,并对该行业排放标准做进一步研究和完善等建议。     

Inherent thermal runaway hazard evaluation method of chemical process based on fire and explosion index

Thermal runaway hazard assessment provides the basis for comparing the hazard levels of different chemical processes. To make an overall evaluation, hazard of materials and reactions should be considered. However, most existing methods didn't take the both into account simultaneously, which may lead the assessment to a deviation from the actual hazard. Therefore, an integrated approach called Inherent Thermal-runaway Hazard Index (ITHI) was developed in this paper. Similar to Dow Fire and Explosion Index(F&EI) function, thermal runaway hazard of chemical process in ITHI was the product of material factor (MF) and risk index (RI) of reaction. MF was an indicator of material thermal hazards, which can be determined by initial reaction temperature and maximum power density. RI, which was the product of probability and severity, indicated the risk of thermal runaway during the reaction stage. Time to maximum rate under adiabatic conditions and criticality classes of scenario were used to indicate the runaway probability of the chemical process. Adiabatic temperature rise and heat of the desired reaction and secondary reaction were used to determine the severity of runaway reaction. Finally, predefined hazard classification criteria was used to classify and interpret the results obtained by this method. Moreover, the method was validated by case studies.     

Systematic review on the implementation methodologies of inherent safety in chemical process

The accomplishments of inherent safety in the field of loss prevention thus far are impressive due to its scientific philosophy: reducing risks at source rather than adding engineered and procedural protections. Generally, the implementation of inherent safety can be done through a cohesive set of fourteen principles elucidated by Kletz and Amyotte. This work, guided by the fourteen principles, presents a systematic review on the implementation methodologies of inherent safety. Firstly, PRISMA procedure was adopted to select eligible literatures according to inclusive and exclusive criteria. After obtaining the selected literatures, the preference, level of application, and gaps in using these principles were critically analyzed. Of the fourteen principles, intensification, substitution, attenuation, simplification, limitation of effects, and avoidance of knock-on effects are preferable to implementing inherent safety in chemical process. Although the remaining principles are also potentially useful, they are not commonly used due to their costs and complexities of implementation. Overall, this work presents a complete spectrum to look across the implementation methodologies of inherent safety and concludes with some holistic and inclusive approaches as future research recommendations.     

Hierarchical pre-positioning of emergency resources for a chemical industrial parks concentrated area

Accidents in chemical industrial parks always cause fateful damage which can be reduced greatly by providing emergency resources sufficiently and timely. One effective way to enhance the emergency response capacity and agility is by pre-positioning of emergency resources for the potential accidents. The Yangtze River Delta of China is a large region where a large number of chemical industrial parks are concentrated. According to the distributing characteristics of demand points in this region, a mathematical model of hierarchical pre-positioning of emergency resources is proposed to ensure that accidents in all chemical industrial parks in this region can be responded timely and effectively. Considering accident domino effect and minimizing the total cost, the model gives optimal decisions of pre-positioning emergency resources, including the location and inventory of depots. The innovative hierarchical pre-positioning method greatly reduces the total cost in the premise of sufficient preparation for supplying emergency resources. Finally, in a visual graph of the Yangtze River Delta, the model is applied and the result shows its applicability.     

Location selection of emergency supplies repositories for emergency logistics management: A variable weighted algorithm

With the development of the city, the number of establishments that are proposed or under construction is increasing year by year, and if they are industries that handle flammable, explosive, toxic, harmful, and dangerous substances, the public safety will face great threats, which will bring great challenges to emergency rescue work. Therefore, providing reasonable solutions to the problem of location selection of emergency supplies repositories are necessary for improving the emergency response efficiency in chemical industrial parks. A mathematical model for location selection of emergency supplies repositories in emergency logistics management are presented considering more actual factors. The optimization objectives of the model are to minimize total transport length and cost. And then a Variable Weighted Algorithm is designed to solve the model, where an auxiliary function was constructed with different methods of building weighting factors based on the theory and method of solving multi-objective optimization problems in operational research. Simulation results show the effectiveness and feasibility of the models and algorithms presented in this paper.     

废铅酸蓄电池污染防治技术及相关政策分析

废铅酸蓄电池具有一定的回收价值,但生产过程和回收过程都容易造成污染。为了引导企业对废旧电池进行正确处理,也为了防止环境被破坏,必须采取科学合理的技术和工艺,并遵循国家相关政策,本文就对此进行了分析,希望能给相关工作提供借鉴。     

研究冷却塔噪声环境影响评价及污染防治措施

随着我国社会经济的发展速度不断加快,城市化建设层次越来越高,大量中央空调设备的冷却塔噪声影响到了人们的日常生活质量。基于此,本文重点针对冷却塔噪声环境的影响进行了分析和研究,提出了相关的有效防治策略,以此有效提高人们的生活质量和舒适度。     

机动车尾气污染及防治对策研究

汽车是当今社会中人们最重要的代步工具,在人们的日常生活中占据着不可替代的位置。随着我国经济快速发展,城市机动车数量不断增加,导致尾气污染问题也日益严重,这不仅对大气质量造成了不良影响,同时也严重危害到了人们的身体健康。因此,机动车尾气污染问题必须得到有关部门高度重视,并且结合造成污染加剧的主要原因,找到机动车尾气污染防治的有效对策。本文将针对机动车尾气污染危害及防治对策进行分析。     

呼和浩特城区冬季近地面挥发性有机物污染特征初步研究

挥发性有机物(VOCs)是环境空气监测的主要目标污染物。本文运用罐采样-三级冷阱预浓缩-中心切割-气相色谱(FID)/气质联用法对人群主要活动的近地面不同高度、不同时间段及不同区域的呼和浩特冬季大气环境中挥发性有机物进行定性定量分析。发现典型天气情况下,呼和浩特城区冬季近地面挥发性有机物组分中烷烃和芳香烃占比较高,城区西侧所监测点位挥发性有机物总量(TVOCs)浓度高于其他区域,且其浓度在高度和时段上存在明显差异。     

绿色化工环保技术与环境治理的关系

我国化工产业的不断发展,带动了我国经济的飞速发展,给人们的生活带来了许多便利条件,但是与此同时也对我国的环境造成了严重的破坏,化工生产用到许多化学材料,在生产过程中会产生大量的化学废弃物,对环境的污染造成很严重的影响。我国对化工生产给环境保护造成的影响高度重视,随着绿色化工环保技术的出现,有效解决了化工产业造成的环境污染问题,对我国的环境问题进行了有效的改善,对我国工业的发展具有重要意义。本文针对绿色化工环保技术进行分析,探讨绿色化工环保技术在环境治理中的有效应用。