燃煤工业锅炉大气二氧化硫污染及应用工业固硫型煤控制

本文研究我国燃煤工业锅炉大气ＳＯ２的污染状况及发展趋势，以及应用工业固硫型煤控制燃煤工业锅炉大气ＳＯ２的污染。燃煤工业锅炉燃烧工业固硫型煤时，可明显地降低ＳＯ２和烟尘的排放量，并节约煤炭。推广和发展工业固硫型煤，是防治燃煤工业锅炉大气ＳＯ２污染的一条投资少、见效快、简便易行的实用措施，其经济效益及环境效益相当可观。     

论乡镇工业排污收费

本文介绍了乡镇工业排污费的征收现状及特点；根据１９８９年全国乡镇工业污染源调查数据对乡镇工业排污费应征值作了测算，并从对乡镇工业、社会、财政收入和农村环境保护的影响以及征收可行性等方面进行了论证；在此基础上，对乡镇工业排污费实征率低的原因作了分析，提出了乡镇工业排污费征收、管理和使用的有关建议。     

炼油厂汽提废水预处理工业试验

炼油厂汽提废水含较高浓度的酚 ,会对污水处理场产生冲击。采用上流式曝气生物滤池对废水进行预处理工业试验 ,取得了满意的试验结果 :出水酚浓度低于 9.0mg/L ,酚降解率 >90 % ,完全可以消除它对污水处理场的冲击。并通过工业试验为工艺设计和工业运行确定了有关参数和运行条件。     

超滤膜处理油田采出水用于回注的试验研究

试验采用截留分子量为100 ku的PVDF(聚偏氟乙烯)超滤膜组件对大庆油田采出水进行了处理,处理水用于油田回注以减少清水的消耗和降低环境污染,同时确定了最佳操作条件和膜清洗方法并考察了超滤出水水质的影响.结果表明最佳的操作条件为:跨膜压差0.30～0.35 MPa,膜面流速3.0～3.5 m/s,温度35～40 ℃.超滤出水中的悬浮物、含油量均低于1.00 mg/L,粒径中值和SRB不能检出,超滤出水水质完全满足油田回注水标准.     

Direct-push geochemical profiling for assessment of inorganic chemical heterogeneity in aquifers

Discrete-depth sampling of inorganic groundwater chemistry is essential for a variety of site characterization activities. Although the mobility and rapid sampling capabilities of direct-push techniques have led to their widespread use for evaluating the distribution of organic contaminants, complementary methods for the characterization of spatial variations in geochemical conditions have not been developed. In this study, a direct-push-based approach for high-resolution inorganic chemical profiling was developed at a site where sharp chemical contrasts and iron-reducing conditions had previously been observed. Existing multilevel samplers (MLSs) that span a fining-upward alluvial sequence were used for comparison with the direct-push profiling. Chemical profiles obtained with a conventional direct-push exposed-screen sampler differed from those obtained with an adjacent MLS because of sampler reactivity and mixing with water from previous sampling levels. The sampler was modified by replacing steel sampling components with stainless-steel and heat-treated parts, and adding an adapter that prevents mixing. Profiles obtained with the modified approach were in excellent agreement with those obtained from an adjacent MLS for all constituents and parameters monitored (Cl, NO(3), Fe, Mn, DO, ORP, specific conductance and pH). Interpretations of site redox conditions based on field-measured parameters were supported by laboratory analysis of dissolved Fe. The discrete-depth capability of this approach allows inorganic chemical variations to be described at a level of detail that has rarely been possible. When combined with the mobility afforded by direct-push rigs and on-site methods of chemical analysis, the new approach is well suited for a variety of interactive site-characterization endeavors.     

森林降水化学的变化特征和机理

研究并比较了湖南酸雨区韶山小集水区林内降水的化学特征，结果表明，与大气降水相比，穿冠水和地表穿透水中的富集的离子浓度除了NO3^-和Na^ 外均明显增加，到达地表的降水离子增加倍数最高达34．3倍；离子总量最高倍数为8．1倍，乔木树冠层的离子富集作用大于灌木层。韶山的大气降水、穿冠水和地表穿透水的年均pH分别为4．61、5．54和5．85。持续大量的降水对森林上空的污染物有较高的清除效果。     

Characteristics of MnO2 catalytic ozonation of sulfosalicylic acid and propionic acid in water

The characteristics of different types of MnO₂ catalytic ozonation of sulfosalicylic acid (SSal) and propionic acid (PPA) have been investigated in this paper. The experimental results show the dependence of catalytic activity of MnO₂ on organic compounds and the pH of solutions, but it is independent on the type of MnO₂. For example, three types of MnO₂ have not any catalytic activity when ozonation of PPA under the condition of this experiment. All MnO₂ catalytic ozonation of SSal at pH=1.0 have a greater total organic carbon removal than ozonation alone has, however, at pH=6.8 and 8.5, catalytic efficiency is not observed. Furthermore, the batch experimental results indicate that there are no direct relationship between the activity of metal oxide catalytic decomposition of ozone and that of its catalytic degradation of organic compounds.     

膜生物反应器中膜分离单元运行参数优化试验

用生活杂排水对膜生物反应器中膜分离单元的运行参数进行了优化试验研究，膜分离单元采用中空纤维超滤膜，试验表明，在适宜的反冲洗和化学清洗条件下，膜的透水率可及时、有效地恢复，使膜生物反应器能长期稳定地运行。     

Das neue Chemikalienprogramm von UNEP Chemicals

Zusammenfassung  UNEP International Register of Potentially Toxic Chemicals (IRPTC) wurde von der ersten VN-Umweltkonferenz 1972 geschaffen. Sein Einfu? und Zusammenwirken in den 80ziger Jahren mit anderen internationalen Programmen der WHO, FAO, OECD und EG in der Chemikalienkontrolle wird beschrieben. Nach dem Erdgipfel von Rio 1992 werden im VN-Rahmen drei neue Gremien gebildet, die das Fachprogramm des Kapitels 19 der Agenda 21 (umweltfreundliches Chemikalienmanagement) umsetzen sollen: die United nations Commission of Sustainable Development, das Intergovernmental Forum on Chemical Safety und das Interorganization Programme for the Sound Management of Chemicals. Der Erdgipfel brachte auch für IRPTC eine Neuorientierung. Seit 1996 hat UNEP Chemicals, wie sich IRPTC nunmehr nennt, drei Aufgaben in sein Arbeitsprogramm aufgenommen, die beschrieben werden: das internationale übereinkommen zum Prior Informed Consent, das internationale übereinkommen zur Kontrolle der Persistent Organic Pollutants, und schlie?lich sein traditionelles Arbeitsgebiet des Informations-austausches über Stoffe wird weitergeführt.

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Die Aussagen dieses Beitrages sind die Meinung des Autors. Sie müssen nicht mit der Auffassung des Umweitbundesamtes oder von UNEP Chemicals übereinstimmen.     

化工制药工艺残渣燃烧过程固氯研究

采用管式固定床反应器对化工制药工艺残渣的燃烧分解进行了实验研究,进一步通过加入氧化钙/碳酸钙来防止燃烧过程残渣中氯的释放.实验结果表明,残渣在燃烧时氯主要以氯化氢形式排出,加入固氯剂后能有效地抑制氯化氢的生成,且固氯效果随着钙化物投加量的增加而明显提高.当氧化钙/残渣比(质量比)达到0.8时,固氯率可达97%以上;当碳酸钙/残渣比(质量比)提高到2.0时,固氯率为76%.与此对应的Ca/Cl摩尔比分别为30和40.继续增加钙投加量,固氯效果基本不变.同时发现添加一定量的木屑在助燃的同时有助于提高固氯效果.