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151.
The hydrolysis/precipitation behaviors of Al3+, Al13 and Al30 under conditions typical for flocculation in water treatment were investigated by studying the particulates' size development, charge characteristics, chemical species and speciation transformation of coagulant hydrolysis precipitates. The optimal pH conditions for hydrolysis precipitates formation for AlCl3, PACAl13 and PACAl30 were 6.5–7.5, 8.5–9.5, and 7.5–9.5, respectively. The precipitates' formation rate increased with the increase in dosage, and the relative rates were AlCl3 ? PACAl30 > PACAl13. The precipitates' size increased when the dosage increased from 50 μM to 200 μM, but it decreased when the dosage increased to 800 μM. The Zeta potential of coagulant hydrolysis precipitates decreased with the increase in pH for the three coagulants. The iso-electric points of the freshly formed precipitates for AlCl3, PACAl13 and PACAl30 were 7.3, 9.6 and 9.2, respectively. The Zeta potentials of AlCl3 hydrolysis precipitates were lower than those of PACAl13 and PACAl30 when pH > 5.0. The Zeta potential of PACAl30 hydrolysis precipitates was higher than that of PACAl13 at the acidic side, but lower at the alkaline side. The dosage had no obvious effect on the Zeta potential of hydrolysis precipitates under fixed pH conditions. The increase in Zeta potential with the increase in dosage under uncontrolled pH conditions was due to the pH depression caused by coagulant addition. Al–Ferron research indicated that the hydrolysis precipitates of AlCl3 were composed of amorphous Al(OH)3 precipitates, but those of PACAl13 and PACAl30 were composed of aggregates of Al13 and Al30, respectively. Al3+ was the most un-stable species in coagulants, and its hydrolysis was remarkably influenced by solution pH. Al13 and Al30 species were very stable, and solution pH and aging had little effect on the chemical species of their hydrolysis products. The research method involving coagulant hydrolysis precipitates based on Al–Ferron reaction kinetics was studied in detail. The Al species classification based on complex reaction kinetic of hydrolysis precipitates and Ferron reagent was different from that measured in a conventional coagulant assay using the Al–Ferron method. The chemical composition of Ala, Alb and Alc depended on coagulant and solution pH. The Alb measured in the current case was different from Keggin Al13, and the high Alb content in the AlCl3 hydrolysis precipitates could not used as testimony that most of the Al3+ was converted to highly charged Al13 species during AlCl3 coagulation. 相似文献
152.
Chunxu Wu Lanfeng Li Hao Zhou Jing Ai Hongtao Zhang Jialin Tao Dongsheng Wang Weijun Zhang 《环境科学学报(英文版)》2021,33(2):340-352
This study aimed to explore the adsorption performance of sludge-based activated carbon (SBC) towards dissolved organic matters (DOMs) removal from sewage, and investigated the modification effect of different types of chemicals on the structure of synthesized SBC. Waste activated sludge (WAS) was used as a carbon source, and HCl, HNO3, and NaOH were used as different types of chemicals to modify the SBC. With the aid of chemical activation, the modified SBC showed higher adsorption performances on DOMs removal with maximum adsorption of 29.05 mg/g and second-order constant (k) of 0.1367 (L/mol/sec) due to the surface elution of ash and minerals by chemicals. The surface elemental composition of MSBC suggested that the content of C-C and C-O functional groups on the surface of modified sludge-based activated carbon (MSBC) played an important role on the adsorption capacities of MSBC towards DOMs removal in sewage. Additionally, the residual molecular weight of DOMs in sewage was investigated using a 3-dimension fluorescence excitation-emission matrix (3D-EEM) and high-performance size exclusion chromatography (HP-SEC). Results showed that the chemical modification significantly improved the adsorption capacity of MSBC on humic acids (HA) and aromatic proteins (APN), and both of NaOH-MSBC and HCl-MSBC were effective for a wide range of different AMW DOMs removal from sewage, while the HNO3-MSBC exhibited poorly on AMW organics of 2,617 Da and 409 Da due to the reducing content of macropore. In brief, this study provides reference values for the impact of the chemicals of the activation stage before the SBCs application. 相似文献
153.
钻井废泥浆中重金属化学形态及潜在生态效应评价 总被引:2,自引:0,他引:2
利用化学萃取法对江苏9个油田的不同类型钻井废泥浆的重金属化学形态分布特征进行调查分析,同时选用Hakanson的潜在生态危害指数法对钻井废泥浆中的重金属总量进行生态效应评价。结果表明,钻井废泥浆中Cu、Pb、Zn、Cd、Cr主要以残渣态和有机结合态为主,活性形态含量较低;采用Hakanson的潜在生态危害指数进行评价,发现Cu、Pb、Zn、Cd都属于轻微生态危害水平,而Cr多属于中等水平,产生潜在生态危害的重金属主要为Cr。 相似文献
154.
Variations in the chemical properties of landfill leachate 总被引:4,自引:0,他引:4
Landfill leachates were collected and their chemical properties analyzed once every two months over a ten-month period from
the Gin Drinkers' Bay (GDB) and Junk Bay (JB) landfills. The contents of solids, and inorganic and organic components fluctuated
considerably with time. In general, the chemical properties of the two leachates correlated negatively (P<0.05) with the amounts of rainfall prior to the sampling periods. However, magnesium and pH of the leachates remained relatively
constant with respect to sampling time. The JB leachate contained higher average contents of solids and inorganic and organic
matter than those of GDB with the exception of trace metals. Trace metals were present in the two leachates in trace quantities
(<1.0 mg/liter). The concentrations of average ammoniacal nitrogen were 1040 and 549 mg/liter, while chemical oxygen demand
(COD) values were 767 and 695 mg/liter for JB and GDB leachates, respectively. These results suggest that the leachates need
further treatment before they can be discharged to the coastal waters. 相似文献
155.
Characteristics of MnO2 catalytic ozonation of sulfosalicylic acid and propionic acid in water 总被引:9,自引:0,他引:9
The characteristics of different types of MnO2 catalytic ozonation of sulfosalicylic acid (SSal) and propionic acid (PPA) have been investigated in this paper. The experimental results show the dependence of catalytic activity of MnO2 on organic compounds and the pH of solutions, but it is independent on the type of MnO2. For example, three types of MnO2 have not any catalytic activity when ozonation of PPA under the condition of this experiment. All MnO2 catalytic ozonation of SSal at pH=1.0 have a greater total organic carbon removal than ozonation alone has, however, at pH=6.8 and 8.5, catalytic efficiency is not observed. Furthermore, the batch experimental results indicate that there are no direct relationship between the activity of metal oxide catalytic decomposition of ozone and that of its catalytic degradation of organic compounds. 相似文献
156.
Burkhard O. Wagner 《Umweltwissenschaften und Schadstoff-Forschung》1998,10(4):245-253
Zusammenfassung UNEP International Register of Potentially Toxic Chemicals (IRPTC) wurde von der ersten VN-Umweltkonferenz 1972 geschaffen.
Sein Einfu? und Zusammenwirken in den 80ziger Jahren mit anderen internationalen Programmen der WHO, FAO, OECD und EG in der
Chemikalienkontrolle wird beschrieben. Nach dem Erdgipfel von Rio 1992 werden im VN-Rahmen drei neue Gremien gebildet, die
das Fachprogramm des Kapitels 19 der Agenda 21 (umweltfreundliches Chemikalienmanagement) umsetzen sollen: die United nations
Commission of Sustainable Development, das Intergovernmental Forum on Chemical Safety und das Interorganization Programme
for the Sound Management of Chemicals. Der Erdgipfel brachte auch für IRPTC eine Neuorientierung. Seit 1996 hat UNEP Chemicals,
wie sich IRPTC nunmehr nennt, drei Aufgaben in sein Arbeitsprogramm aufgenommen, die beschrieben werden: das internationale
übereinkommen zum Prior Informed Consent, das internationale übereinkommen zur Kontrolle der Persistent Organic Pollutants,
und schlie?lich sein traditionelles Arbeitsgebiet des Informations-austausches über Stoffe wird weitergeführt.
Die Aussagen dieses Beitrages sind die Meinung des Autors. Sie müssen nicht mit der Auffassung des Umweitbundesamtes oder von UNEP Chemicals übereinstimmen. 相似文献
Die Aussagen dieses Beitrages sind die Meinung des Autors. Sie müssen nicht mit der Auffassung des Umweitbundesamtes oder von UNEP Chemicals übereinstimmen. 相似文献
157.
The timing of chemical signaling with urine in dominance fights of male lobsters (Homarus americanus) 总被引:2,自引:0,他引:2
Chemicals carried in the urine are a rich source of information about the identity, sex, aggressive motivation, and other
attributes of an animal. In agonistic interactions, animals should be careful about disclosing such information, since it
can be used by receivers to the disadvantage of the sender. By adjusting the timing of urine release, the signaler may still
influence the behavior of the receiver to its own benefit. Here we investigate the urine signaling of American lobsters (Homarus americanus), necessary for the maintenance of dominance, using a catheter technique with high temporal resolution. We hypothesize that
urine release in lobster fights is not continuous but restricted to moments that may elicit a reaction in the receiver beneficial
to the sender. We found that eventual winners signaled more readily in the initial phase of the fight. Eventual losers did
not show such initial urination. This suggests that a confident lobster may use urine signals to influence the behavior of
its opponent into giving up the fight at an early stage. For both winners and losers, urine release is linked to offensive
behavior and increases as the intensity of agonistic behavior increases. The coupling of urine release to offensive behaviors
appears to improve both the reliability and efficacy of the chemical signal. Releasing urine under the increasing risk of
inflicting injury during the fight provides a handicap that may ensure reliability of the threat signal. Furthermore, the
immediate coupling of urine components to offensive behavior may help to consolidate the receiver"s memory of the signaler"s
individual scent and thus facilitate future recognition of the dominant animal.
Received: 6 October 1999 / Accepted 28 August 2000 相似文献
158.
Summary. Many secondary plant compounds are involved in defense against both insect herbivores and pathogens. Two secondary plant
compounds of Plantago lanceolata, the iridoid glycosides catalpol and its precursor aucubin, are well known for their deterrent effects on generalist and
non-adapted specialist insect herbivores. We tested the effects of these compounds on the in-vitro growth of a specialist
and generalist fungal pathogen of this host species. Two chemical forms of these iridoids were tested. The glycosides and
their aglycones, the products of enzymatic conversion by specific $/Beta$-glucosidase enzymes. The glycosides enhanced growth
of both the specialist fungus Diaporthe adunca and the generalist fungus Fusarium moniliforme var. subglutinans. The positive effect of these glycosides on the generalist fungus is in sharp contrast with the generally negative effects
of these glysosides on generalist insect herbivores. The aglycones of aucubin and catalpol reduced the growth of the specialist
fungus D. adunca, but, contrary to expectation, enhanced the growth of the generalist fungus F. moniliforme var. subglutinans. Effects of aucubin on D. adunca were stronger than effects of catalpol. This was true both for the growth stimulating effects of the glycosides and for the
fungitoxic effects of the aglycones. We therefore expect that the effects of these iridoids in P. lanceolata on the specialist fungus will strongly depend on the ratio between catalpol and its precursor aucubin and the chemical form
(glycoside or aglycone) in which these compounds are encountered by the fungus during growth. Our results suggest that iridoid
glycosides in P. lanceolata can be used as defense against both herbivores and pathogens, but that their effects are highly specific with respect to
the natural enemy species that is encountered.
Received 11 April 2002; accepted 9 August 2002 相似文献
159.
Rapha?l?JeansonEmail author Jean-Louis?Deneubourg Anne?Grimal Guy?Theraulaz 《Behavioral ecology and sociobiology》2004,55(4):388-394
Insect societies are often confronted with choices among several options such as food sources of different richness or potential nest sites with different qualities. The mechanisms by which a colony as a whole evaluates these situations and takes the appropriate decision are of crucial importance for its survival. Here we studied how collective decisions arise from individual behaviors when a group of workers of the ant Messor barbarus is given a choice between two aggregation sites. Two hundred ants were introduced into an arena and given a choice between two tubes connected to the arena. The tubes had different physical properties: dry and transparent (termed as dry), humid and transparent (termed as humid), or dry and dark (termed as dark). After 30 min, most ants were found to be aggregated in a humid tube when paired with a dry tube, or in a dark tube when paired with a humid one. When two humid tubes were in competition, ants aggregate more in one of the sites. The choice of ants was consistent throughout experiments. An analysis of individual behaviors shows that the probability of an ant recruiting and the intensity of its trail-laying behavior strongly depend on the quality of the tubes. Our study suggests that the selection of an aggregation site does not require that individual ants directly compare sites, but rather relies on the synergy between amplification processes involving recruitment by chemical trails, and a modulation of the individual resting time in a site as a function of its population.Communicated by L. Sundström 相似文献
160.
Bahman AbdolhamidzadehTasneem Abbasi D. RashtchianS.A. Abbasi 《Journal of Loss Prevention in the Process Industries》2011,24(5):575-593
The paper presents an inventory, perhaps the most comprehensive till date, of the major process-industry accidents involving ‘domino effect’. The inventory includes, among other relevant information, the sequence of accidents that had occurred in each domino episode. The information has been analyzed to identify several patterns which may be useful in further work on understanding domino effect and reducing the probability of its occurrence in future. A concept of ‘local domino effect’ has been introduced. 相似文献