全文获取类型
收费全文 | 318篇 |
免费 | 18篇 |
国内免费 | 116篇 |
专业分类
安全科学 | 20篇 |
废物处理 | 2篇 |
环保管理 | 38篇 |
综合类 | 203篇 |
基础理论 | 106篇 |
污染及防治 | 30篇 |
评价与监测 | 3篇 |
社会与环境 | 34篇 |
灾害及防治 | 16篇 |
出版年
2024年 | 2篇 |
2023年 | 5篇 |
2022年 | 7篇 |
2021年 | 10篇 |
2020年 | 16篇 |
2019年 | 17篇 |
2018年 | 9篇 |
2017年 | 10篇 |
2016年 | 21篇 |
2015年 | 19篇 |
2014年 | 17篇 |
2013年 | 24篇 |
2012年 | 19篇 |
2011年 | 30篇 |
2010年 | 19篇 |
2009年 | 28篇 |
2008年 | 16篇 |
2007年 | 22篇 |
2006年 | 13篇 |
2005年 | 18篇 |
2004年 | 16篇 |
2003年 | 15篇 |
2002年 | 13篇 |
2001年 | 15篇 |
2000年 | 13篇 |
1999年 | 9篇 |
1998年 | 8篇 |
1997年 | 15篇 |
1996年 | 7篇 |
1995年 | 6篇 |
1994年 | 1篇 |
1993年 | 5篇 |
1991年 | 5篇 |
1990年 | 1篇 |
1984年 | 1篇 |
排序方式: 共有452条查询结果,搜索用时 31 毫秒
41.
There is increasing concern that agricultural intensification in China has greatly increased N2O emissions due to rapidly increased fertilizer use. By linking a spatial database of precipitation, synthetic fertilizer N input, cropping rotation and area via GIS, a precipitation-rectified emission factor of N2O for upland croplands and water regime-specific emission factors for irrigated rice paddies were adopted to estimate annual synthetic fertilizer N-induced direct N2O emissions (FIE-N2O) from Chinese croplands during 1980-2000. Annual FIE-N2O was estimated to be 115.7 Gg N2O-N year−1 in the 1980s and 210.5 Gg N2O-N year−1 in the 1990s, with an annual increasing rate of 9.14 Gg N2O-N year−1 over the period 1980-2000. Upland croplands contributed most to the national total of FIE-N2O, accounting for 79% in 1980 and 92% in 2000. Approximately 65% of the FIE-N2O emitted in eastern and southern central China. 相似文献
42.
The Quick Easy Cheap Effective Rugged and Safe multiresidue method (QuEChERS) has been validated for the extraction of 15 organochlorine pesticides (OCPs) in completely different matrices of traditional Chinese medicine (TCM). The method employed a rapid, simple and cost-effective procedure. The spiking levels for the recovery experiments were 0.1, 0.5 and 2.0 mg kg−1. Mean recoveries mostly ranged between 76.0% and 114.0% (96.0% on average), and relative standard deviations (RSD) were generally below 10% (4.72% on average). Based on these results, the methodology has been proven to be highly efficient and robust and thus suitable for monitoring the MRL compliance of a wide range of commodity. The contamination status of 15 OCPs on 80 different TCMs marketed in China, and a total of 400 samples were also performed using a previously validated method. 15 OCPs were benzene hexachloride (BHC, including α-BHC, β-BHC, γ-BHC, δ-BHC), hexachlorobenzene, heptachlor, heptachlor epoxide, aldrin, p, p′-DDE, p, p′-DDD, o, p′-DDT, p, p′-DDT, mirex, endrin, dieldrin. This study indicates that the proposed method is useful for analyzing OCPs in TCM. 相似文献
43.
Due to the wide occurrence of endocrine disrupting chemicals in the environment, it is much of importance to develop high throughput screening method for the analysis of this kind of pollutants. Using anion-exchange membrane chromatography, vitellogenin (VTG) from the plasma of 17β-estradiol (E2) treated Chinese rare minnow was rapidly purified within 15 min. Both polyclonal antibody (PcAb) and monoclonal antibody (McAb) against rare minnow VTG (R-VTG) were prepared in rabbit and Balb/c mice, respectively. The competitive enzyme-linked immunosorbent assays (ELISA) based on either PcAb or McAb were developed to identify and quantify R-VTG in the plasma, and these two methods showed similar characteristics. The detection limits of both assays were lower than 3 ng mL−1 with the working ranges covering three magnitudes. The recovery efficiencies of PcAb and McAb based ELISA were 104.2% and 102.6%, respectively; and the intra-assay and inter-assay of these two assays were 6.2% and 9.2%, 8.6% and 12.8%, respectively. These results indicated that the described competitive ELISA methods were sensitive and valuable tools for quantifying vitellogenin in rare minnow plasma. These methods were then applied to measure R-VTG concentrations in plasma of male fish exposed to a series of E2 concentrations. When E2 levels were less than 10 ng L−1, R-VTG levels in plasma were comparable to that in solvent control, while R-VTG levels significantly increased 15-folds and 350-folds, respectively when E2 exposure concentrations were controlled at 10 and 50 ng L−1. The high sensitivity of Chinese rare minnow to E2 was demonstrated, making it a valuable model species to study environmental estrogens. 相似文献
44.
K. M. S. Sundaram S. Y. Szeto 《Journal of environmental science and health. Part. B》2013,48(5):579-599
Abstract An oil‐based formulation of carbaryl (1‐naphthyl N‐methyl‐carbamate) (Sevin‐2‐Oil) was applied twice by a fixed‐wing aircraft at a dosage rate of 280 g of A.I./ha/application to a coniferous forest near Allardville, New Brunswick. The highest concentrations of the chemical in fir foliage, litter and forest soil 1 h after application were respectively 4.20, 1.21 and 0.59 ppm (fresh weight). The residues dissipated rapidly and the DT50 values obtained from the depletion curves were 2.3 d for foliage and 1.5 d for litter and soil samples. Very low levels (<0.1 ppm) of carbaryl persisted in foliage and litter beyond the 10 d sampling period. The maximum residue level found in stream water was 0.314 ppm and more than 50% of it had dissipated within 1 h. Low but detectable levels (0.001 ppm) of the chemical persisted in water until the end of the 10 d sampling period. Sediment samples contained a maximum level of 0.04 ppm, which dissipated below the detection limit within 5 h. Brook trout and slimy sculpins captured in the stream 1 d after the spray contained on average about 0.04 ppm of carbaryl and none of it was found in 3 d postspray samples. 相似文献
45.
K.M.S. Sundaram A. Sundaram 《Journal of environmental science and health. Part. B》2013,48(4):757-783
Abstract Dimilin® WP‐25, a wettable powder formulation of diflubenzuron (DFB) [1‐(4‐chlorophenyl)‐3‐(2,6‐difluorobenzoyl) urea], was formulated in four different carrier liquids, viz., water; a light petroleum paraffinic oil, ID 585; a heavy paraffinic oil, Sunspray® 7N; and a 1:2 mixture of a light petroleum aromatic solvent (Cyclosol® 63) and canola oil; to provide four end‐use mixtures, Dim‐W, Dim‐585, Dim‐7N and Dim‐Cy‐C respectively, each containing 28 g of DFB per litre. Balsam fir branch tips clipped from greenhouse‐grown seedlings, and sugar maple branch tips clipped from field‐grown young trees, were exposed to uniform‐sized droplets (ranging in diameters from 135 to 190 μm) of the four end‐use mixtures which were atomized using a monodispersed droplet generator. Droplets were collected on the fir and maple branch tips and the initial residue per g fresh weight of foliage was determined by high‐performance liquid chromatography (HPLC). The branch tips were exposed to cumulative rainfall of 3, 6 and 10 mm at an intensity of 5 mm/h and at time intervals of 1, 12, 36 and 72 h after DFB treatment, to test the influence of ‘ageing’ of foliar residues on rainfastness. Foliar samples were collected for residue determination just before the onset of rainfall, and at 0.5 h post‐rain. DFB was quantified by the HPLC method. In the case of fir foliage, the Dim‐W formulation was the most susceptible to rain‐washing and the rainfastness did not increase with the ageing period of foliar deposits. In contrast, the three oil‐based mixtures showed greater rainfastness depending upon the carrier liquid and the ageing period. Rainfastness decreased in the order of Dim‐Cy‐C > Dim‐7N > Dim‐585 > Dim‐W. In contrast, the data on maple foliage indicated that the ageing of deposits increased the rainfastness of all the 4 end‐use mixtures. Dim‐585 was the most susceptible to rain washing, and rainfastness decreased in the order of Dim‐W > Dim‐Cy‐C > Dim‐7N > Dim‐585. 相似文献
46.
综合利用中药资源,开展中药生产中的废料综合利用工作,是保证中药资源永续利用的重要措施和手段。本文概述了中药生产中的综合利用及研究情况,探讨了中药生产中废料资源化技术的开发。 相似文献
47.
四川中药资源的开发利用与发展方向 总被引:2,自引:0,他引:2
本文探讨了四川中药资源的开发利用和发展方向;(1)以资源化优势为依托,大力发展创泡中草药;(2)以地道药材为优势,建立稳定的药材基地(3)以综合利用为途径,提高资源利用的数量和质量;(4)以资源保护为前景,保证资源的永续利用。本文 相似文献
48.
Gerald F. Gifford William Humphries Richard A. Jaynes 《Journal of the American Water Resources Association》1984,20(2):181-186
ABSTRACT: Heat pulse velocity techniques were developed for effective monitoring of water movement in aspen (Populus tremuloides), subalpine fir (Abies lasiocarpa), and Englemann spruce (Picea engelmannif). Water loss was monitored in replicated trees of each species for one year. These data were used to modify the plant activity index (a reflection of the ability of plants to transpire water at various times during a year) and the crop coefficient (a reflection of differences in consumptive use rates of water by different vegetation types when all other factors are held constant) for each species within the model ASPCON, a deterministic, lumped-parameter model describing the hydrology of aspen to conifer succession. Results of the modeling in dicate 18.6 cm net loss of moisture available for streamflow when spruce replaced aspen, and a loss of 7.2 cm when fir forests replaced aspen. The aspen to conifer successional trend appears, therefore, to be significantly reducing water yields in the western United States. 相似文献
49.
50.
构造运动与中国沿岸平原的地质灾害 总被引:3,自引:1,他引:3
中国海岸穿过构造沉降带和隆起带,沉降带及隆起带断陷盆地的持续下降吸引了源远流长的大河在此人海,而隆起带内入海的河流多为近源小河,从而引起河流泥沙沿岸分配的不均和海岸沉积物的差异。沉降带内每公里海岸线接受的沉积物是隆起带的数十倍,且以砂质沉积物为主.隆起带河流泥沙来量少.而且砂质沉积物占了压倒的优势.河流泥沙沿岸分配的不均决定了中国沙质和淤泥质海岸的基本类型和分布格局、沉降带和隆起带松散沉积层的厚度和结构,山此产生了中国沿岸与第四纪沉积层有关的灾害和环境问题的有规律的分布。地面沉降主要分布于沉降带内,而地下海水入侵多出现在依赖地下水的隆起带内,底辟构造、浅层天然气往往在大河三角洲构成灾害和潜在的地质灾害.沉降带和隆起带断陷盆地内的海岸低地通常是海平面上升的主要脆弱地区.此外,丰富的河流泥沙使中国海岸对全球海平面上升的响应也不相同,如海岸湿地的再生和海岸侵蚀原因的复杂性等. 相似文献